中华医学超声杂志

应用化学 ›› 1992, Vol. 0 ›› Issue (6): 52-56.

• 研究论文 • 上一篇    下一篇

含氮杂环三烃基锡衍生物的合成及其生物活性

谢筱娟1, 陈传峰1, 谢庆兰2, 徐效华2   

  1. 1. 安徽师范大学化学系, 芜湖;
    2. 南开大学元素有机化学国家实验室, 天津 30007l
  • 收稿日期:1992-01-03 修回日期:1992-05-14 出版日期:1992-12-10 发布日期:1992-12-10
  • 基金资助:
    天津市科学基金

SYNTHESIS AND BIOLOGICAL ACTIⅥTIES OF TRIALKYLTIN DERIVATIVES CONTAINING AZOTIC HETEROCYCLIC COMPOUNDS

Xie Xiaojuan1, Chen Chuanfeng1, Xie Qinglan2, Xu Xiaohua2   

  1. 1. Department of Chemistry, Anhui Normal University, Wuhu;
    2. National Laboratory of Elemento-organic Chemistry, Nankai University, Tianjin 300071
  • Received:1992-01-03 Revised:1992-05-14 Published:1992-12-10 Online:1992-12-10

PDF

407

被引次数

49 | 14

摘要： 本文合成了14个含氮杂环三烃基锡衍生物,红外光谱,核磁共振谱和质谱的研究表明三烃基锡-1,2,4-三氮唑为以氮原子作桥联的五配位聚合结构化合物,化合物的生物活性和生物选择性主要取决于锡原子上的三烃基。

关键词: 有机锡化合物, 氮杂环化合物, 生物活性, 合成, 杀螨剂, 杀虫剂

Abstract: Fourteen trialkyltin derivatives containing azotic heterocyelie compounds were synthesized. The IR, 1H, 119Sn and 29Si NMR, MS and elemental analysis were carried out. The results showed that trialkyltin-1,2,4-triazole is an organotin polymer containing fivecoordinated tin atom with bridging nitrogen atoms. The bioassay results showed that the biological effects of the compounds are mainly determined by the trialkyl groups linked with the tin atoms.

Key words: organo-tin compound, azotic heterocyclic compound, biological activity, synthesis, acaricide, pesticide

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