应用化学 ›› 1989, Vol. 0 ›› Issue (5): 35-38.

• 研究论文 • 上一篇    下一篇

端羟基聚丁二烯预聚物的表征

刘元社1, 安立华1, 单复1, 骆韫珠2   

  1. 1. 国防科技大学五系 长沙;
    2. 深圳大学应用化学系
  • 收稿日期:1988-11-30 修回日期:1989-03-22 出版日期:1989-10-10 发布日期:1989-10-10

CHARACTERIZATION OF HYDROXYLTERMINATED POLY-BUTADIENE(HTPB) PREPOLYMER

Liu Yuanshe1, An Lihua1, Shan Fu1, Luo Yunzhu2   

  1. 1. National Defense University of Science and Technology, Changsha;
    2. Shenzhen University
  • Received:1988-11-30 Revised:1989-03-22 Published:1989-10-10 Online:1989-10-10

摘要: 本文用VPO、IR、GPC、TLC方法表征国产端羟基聚丁二烯(HTPB),其结果是:Mn为3220,Mw/Mn为1.69,fn为2.16,fw为2.27。证明国产HTPB预聚物的数均官能度随分子量增加而增加。探讨了用TLC法研究HTPB官能度分布的可靠性。

关键词: 端羟基聚丁二烯, 官能度分布, 表征, 薄层色谱法

Abstract: The China made hydroxylterminated polybutadiene (HTPB) has been characterized using VPO, IR, GPC and TLC techniques. The polymer was found to have Mn=3220,Mw/Mn=1.69,fn=2.16 and fw=2.27 with its number average functionlity being inereased with molecular weight. The reliability of TLC to determine the functionality distribution of HTPB has been discussed.

Key words: Hydroxylterminated polybutadiene, Functionality distribution, Characterization, Thin layer chromatography