中华医学超声杂志

应用化学 ›› 1989, Vol. 0 ›› Issue (5): 31-34.

• 研究论文 • 上一篇    下一篇

金和铂的某些冠醚类配合物的合成与性质

龚钰秋, 张培志   

  1. 杭州大学化学系
  • 收稿日期:1988-11-27 修回日期:1989-03-11 出版日期:1989-10-10 发布日期:1989-10-10
  • 基金资助:
    国家自然科学基金

SYNTHESIS AND CHARACTERIZATION OF COMPLEXES OF GOLD(Ⅲ)AND PLATINUM(Ⅳ)WITH SOME CROWN ETHERS

Gong Yuqiu, Zhang Peizhi   

  1. Department of Chemistry, Hangzhow University
  • Received:1988-11-27 Revised:1989-03-11 Published:1989-10-10 Online:1989-10-10

PDF

456

被引次数

2

摘要： 制得5种金和铂的冠醚类配合物,用元素分析、红外和紫外光谱、摩尔电导和1H核磁共振谱等方法研究了配合物的组成及其有关性质。

关键词: 金, 铂, 冠醚配合物

Abstract: Five solid complexes of gold (Ⅲ) or platinum (Ⅳ) with crown ethers have been preparedfirstly. These complexes have been characterized by elemental analysis, IR and UV spectra,molar conductances and 1H NMR measurements. The complexes were found to have following constitution: [K(B15C5)2]AuCl4, [Na(B15C5)2]PtCl6, (K18C6)]AuCl4, [K(DB15C5)]AuCl4and [NH4(DB24C8)]AuCl4, where B=benzo, DB=dibenzo.

Key words: Gold, Platinum, Crown ether complex

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