链状Cs8Mn4Sn4Se16和[Ni(1,2-dap)3]2Cd2Sn2S8 (1,2-dap:1,2-丙二胺)的溶剂热合成与表征

doi:10.11944/j.issn.1000-0518.2018.06.170234

摘要/Abstract

摘要：

采用溶剂热法,在1,4-丁二胺中合成以碱金属为客体阳离子的硫属锡酸盐Cs₈Mn₄Sn₄Se₁₆(1)及1,2-丙二胺(1,2-dap)配位的过渡金属为客体阳离子的硫属锡酸盐[Ni(1,2-dap)₃]₂Cd₂Sn₂S₈(2)。并采用单晶X射线、紫外可见漫反射、热重分析-差示扫描量热分析(TG-DSC)等手段进行表征。结果表明,化合物1为正交晶系,空间群为Fddd;化合物2为正交晶系,空间群为Cmcm;且结构中均包含SnQ₄(Q=S,Se)四面体与TMQ₄(TM=Mn,Cd)四面体通过共边而成的一维(1-D)阴离子链,紫外可见漫反射分析表明,化合物1、2的禁带宽度分别为1.70 和2.21 eV,具有半导体性质。且TG-DSC测试显示化合物1、2在一定温度下具有一定的稳定性。

关键词: 溶剂热合成, 多元硫属锡酸盐, 结构, 表征

Abstract:

The chalcogenidostannate compound Cs₈Mn₄Sn₄Se₁₆(1) and [Ni(1,2-dap)₃]₂Cd₂Sn₂S₈(2) were solvothermally synthesized by using the alkali metal in 1,4-butanediamine, and 1,2-propanediamine(1,2-dap) coordinated transition metal as guest cations, respectively. Single-crystal X-ray, ultraviolet-visible(UV-Vis) diffuse reflectance spectroscopy and thermogravimetric analysis and differential scanning calorimetry(TG-DSC) indicate that the compounds 1 and 2 belong to orthorhombic system Fddd group and Cmcm group. Both 1 and 2 consist of one-dimensional straight anionic chains composed of edge sharing tetrahedron SnQ₄(Q=S, Se) or TMQ₄(TM=Mn, Cd). The UV-visble diffuse reflectance data show that the band gaps of compounds 1 and 2 are 1.70 eV and 2.21 eV, respectively, which implies that compounds 1 and 2 have semiconductor properties. The TG-DSC results indicate good thermal stability of compunds 1 and 2 in some temperature condition.

Key words: solvothermal synthesis, multi-chalcogenidostannates, crystal structure, characterization

韩文静,白音孟和. 链状Cs₈Mn₄Sn₄Se₁₆和[Ni(1,2-dap)₃]₂Cd₂Sn₂S₈ (1,2-dap:1,2-丙二胺)的溶剂热合成与表征[J]. 应用化学, 2018, 35(6): 700-707.

HAN Wenjing,BAIYIN Menghe. Solvothermal Synthesis and Characterization of Cs₈Mn₄Sn₄Se₁₆ and [Ni(1,2-dap)₃]₂Cd₂Sn₂S₈ (1,2-dap:1,2-Propanediamine)Chains[J]. Chinese Journal of Applied Chemistry, 2018, 35(6): 700-707.

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链状Cs₈Mn₄Sn₄Se₁₆和[Ni(1,2-dap)₃]₂Cd₂Sn₂S₈ (1,2-dap:1,2-丙二胺)的溶剂热合成与表征

Solvothermal Synthesis and Characterization of Cs₈Mn₄Sn₄Se₁₆ and [Ni(1,2-dap)₃]₂Cd₂Sn₂S₈ (1,2-dap:1,2-Propanediamine)Chains

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