中华医学超声杂志

应用化学 ›› 2011, Vol. 28 ›› Issue (08): 864-868.DOI: 10.3724/SP.J.1095.2011.00600

• 研究论文 • 上一篇    下一篇

高热稳定性聚膦腈亚微米球的室温快速合成

付建伟,王明环,王旭哲,袁金苹,许群*   

  1. (郑州大学材料科学与工程学院 郑州 450001)
  • 收稿日期:2010-10-11 修回日期:2011-01-07 出版日期:2011-08-10 发布日期:2011-08-10
  • 通讯作者: 许群，教授; Tel/Fax:0371-67767827; E-mail:qunxu@zzu.edu.cn; 研究方向：环境友好技术与新材料制备
  • 基金资助:
    国家自然科学基金（51003098,20974102,20804040）国家博士后科学基金(20100480055)资助项目

Rapid Room Temperature Synthesis of Polyphosphazene Sub-micrometer Spheres with High Thermal Stability

FU Jianwei, WANG Minghuan, WANG Xuzhe, YUAN Jinping, XU Qun*   

  1. (School of Materials Science and Engineering,Zhengzhou University,Zhengzhou 450001)
  • Received:2010-10-11 Revised:2011-01-07 Published:2011-08-10 Online:2011-08-10

PDF

1798

被引次数

7 | 1

摘要：

以六氯环三膦腈（HCCP）和4,4′-二羟基二苯砜（BPS）为共缩聚单体，乙腈为溶剂，三乙胺为缚酸剂，在室温条件下，采用沉淀聚合的方法快速合成了一种聚膦腈亚微米球。 红外光谱、元素分析及X射线能谱分析(EDX)测试表明，该聚膦腈亚微米球具有高度交联的化学结构；扫描电子显微镜和透射电子显微镜测试表明，该聚膦腈亚微米球粒径分布在410 nm附近，而且具有光滑的表面和实心的结构；热重分析(TGA)测试表明，该聚膦腈亚微米球的热分解温度达到531 ℃。 并推测了该聚膦腈亚微米球的形成机理。

关键词: 沉淀聚合, 聚膦腈, 微球, 合成

Abstract:

Polyphosphazene(PPZ) sub-micrometer spheres were prepared rapidly under room temperature via precipitation polymerization of hexachlorocyclotriphosphazene(HCCP) with 4,4′-sulfonyldiphenol(BPS), using acetonitrile as the solvent and triethylamine(TEA) as the acid-acceptor. The PPZ sub-micrometer spheres were characterized by FT-IR, elemental analysis and EDX, and their highly cross-linked structures were identified. SEM and TEM results indicated that the PPZ sub-micrometer spheres had diameter of about 410 nm, solid structure and smooth surface. TGA result showed that the thermal decomposition temperature of the PPZ sub-micrometer spheres was about 531 ℃. In addition, the formation mechanism of the PPZ sub-micrometer spheres was proposed.

Key words: precipitation polymerization, polyphosphazene, microspheres, synthesis

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