应用化学 ›› 2011, Vol. 28 ›› Issue (03): 245-253.DOI: 10.3724/SP.J.1095.2011.00268

• 综合评述 • 上一篇    下一篇

单电子转移活性自由基聚合的现状及展望

丁伟*,孙颖,吕崇福,魏继军,于涛   

  1. (东北石油大学化学化工学院 大庆 163318)
  • 收稿日期:2010-05-10 修回日期:2010-07-28 出版日期:2011-03-10 发布日期:2011-03-10
  • 通讯作者: 丁伟,教授; 电话/传真:0459-6504071; E-mail:dingwei40@126.com; 研究方向:高分子化学-活性自由基聚合
  • 基金资助:
    黑龙江省自然科学基金重点项目(ZJG0507),黑龙江省自然科学基金青年基金(QC08C33),黑龙江省研究生创新科研资金(YJSCX2008-044HLJ)和黑龙江省科技厅攻关项目(GZ05A404)资助

Current Situation and Perspectives of Single Electron Transfer Living Radical Polymerization

DING Wei*, SUN Ying, LV Chongfu, WEI Jijun, YU Tao   

  1. (Chemistry and Chemical Engineering College of Northeast Petroleum University,Daqing 163318)
  • Received:2010-05-10 Revised:2010-07-28 Published:2011-03-10 Online:2011-03-10

摘要:

重点介绍了单电子转移活性自由基聚合的机理及适合该聚合体系的催化剂、配体、溶剂种类和单体适用范围,并探讨了单电子转移活性自由基聚合的发展前景。

关键词: 活性聚合, 单电子转移活性自由基聚合, 机理, 外层电子转移, 异裂

Abstract:

In this paper, we mainly discussed the involved mechanism in single electron transfer living radical polymerization. The types of catalysts, ligands, solvents as well as monomers suitable for such kinds of polymerizations have been also addressed in detail. In addition, the perspectives of this single electron transfer living radical polymerization was highlighted.

Key words: living polymerization, single electron transfer living radical polymerization, Mechanism, outer-sphere electron transfer, heterolysis

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