一种2-乙酰基吡嗪-罗丹明B衍生物的合成及其对Ni2+的识别

doi:10.11944/j.issn.1000-0518.2017.12.170294

摘要/Abstract

摘要：

分子光谱法具有灵敏度高、操作简单等优点,发展简便、快捷、对镍离子(Ni²⁺)具有高度选择性的探针具有非常重要的意义。本文以金属离子诱导罗丹明酰胺衍生物反应开环的策略,设计并合成了对Ni²⁺检测具有单一选择性识别的紫外吸收探针。同时,该探针可对水溶液中的Ni²⁺实现“裸眼”识别。此外,该探针对Ni²⁺具有较高的灵敏度,其对水溶液中Ni²⁺的检测限为0.5 μmol/L,表明该探针可用于Ni²⁺的检测分析。

关键词: 分子探针, 罗丹明B, Ni²⁺, “裸眼”识别

Abstract:

Molecular spectroscopy has the advantages of high sensitivity and simple operation. Therefore, it is significant to develop a probe with high selectivity for nickel ions(Ni²⁺). In this paper, a novel molecular probe was designed and synthesized from rhodamine B, hydrazine hydrate and 2-acetylpyrazine for the detection of Ni²⁺ with excellent selectivity in aqueous media. Simultaneously, the probe rhodamine B amide derivative(RWZ) can achieve “naked eye” recognition of Ni²⁺ in aqueous solution. Furthermore, the probe shows high sensitivity to Ni²⁺ with low limit of detection(0.5 μmol/L), indicating that the probe can be used for detection of Ni²⁺ in aqueous solution.

Key words: molecular probe, rhodamine B, nickel ion, “naked-eye&rdquo, identification

黄齐, 宋昊翰, 王晓, 庞兰芳, 周艳梅. 一种2-乙酰基吡嗪-罗丹明B衍生物的合成及其对Ni²⁺的识别[J]. 应用化学, 2017, 34(12): 1468-1473.

HUANG Qi, SONG Haohan, WANG Xiao, PANG Lanfang, ZHOU Yanmei. Synthesis of a New Rhodamine-Based Probe for Selective Detection of Ni²⁺ in Aqueous Solution[J]. Chinese Journal of Applied Chemistry, 2017, 34(12): 1468-1473.

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一种2-乙酰基吡嗪-罗丹明B衍生物的合成及其对Ni²⁺的识别

Synthesis of a New Rhodamine-Based Probe for Selective Detection of Ni²⁺ in Aqueous Solution

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