Thermoregulated Phase-Transfer Catalysis System for Hydrogenation of α，β -Unsaturated Ketones at Atmospheric Pressure

doi:10.19894/j.issn.1000-0518.240133

Chinese Journal of Applied Chemistry ›› 2024, Vol. 41 ›› Issue (9): 1350-1356.DOI: 10.19894/j.issn.1000-0518.240133

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Thermoregulated Phase-Transfer Catalysis System for Hydrogenation of α，β -Unsaturated Ketones at Atmospheric Pressure

Bing-Qin LIU, Yan-Hua WANG()

School of Chemistry，Dalian University of Technology，Dalian 116024，China

Received:2024-04-22 Accepted:2024-08-15 Published:2024-09-01 Online:2024-10-09
Contact: Yan-Hua WANG
About author:yhuawang@dlut.edu.cn
Supported by:
the National Natural Science Foundation of China(21173031)

Abstract

Abstract:

A novel thermoregulated phase-transfer （TPT） catalysis system composed of H₂O， 1-hexanol and Ru nanocatalyst （Ru_nano catalyst） was developed and utilized for the selective hydrogenation of chalcone at atmospheric H₂ pressure. Under the optimal circumstances， both the conversion of chalcone and the selectivity for the product of CC double bond hydrogenation from chalcone were above 99%. The Ru_nano catalyst is conveniently separable from product and directly recycled six times with conversion and selectivity remaining unchanged. The turnover frequency （TOF） was higher than that of previously reported Ru_nano catalyst and the leaching of Ru was further reduced. In addition， this novel TPT catalysis system was also extended to the atmospheric hydrogenation of other α，β -unsaturated ketones with ＞99% conversion and selectivity.

Key words: H₂O/1-hexanol biphasic system, Ru nanocatalyst, Selective hydrogenation, α, β-Unsaturated ketones, Atmospheric H₂ pressure

CLC Number:

O622.4

Bing-Qin LIU, Yan-Hua WANG. Thermoregulated Phase-Transfer Catalysis System for Hydrogenation of α，β -Unsaturated Ketones at Atmospheric Pressure[J]. Chinese Journal of Applied Chemistry, 2024, 41(9): 1350-1356.

Figures/Tables 9

References 17

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Entry	Time of addition of Hg/min	n（Hg）/n（Ru）	Total time/min	Conversion/% ^b
1	—	—	30	＞99
2	0	1 000	30	22
3	—	—	15	56
4	15	1 000	30	58

Entry	Time of addition of Hg/min	n（Hg）/n（Ru）	Total time/min	Conversion/% ^b
1	—	—	30	＞99
2	0	1 000	30	22
3	—	—	15	56
4	15	1 000	30	58

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Thermoregulated Phase-Transfer Catalysis System for Hydrogenation of α，β -Unsaturated Ketones at Atmospheric Pressure

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