Catalytic Decolorization Performance of Azo Dyes by Doped Nano-Nickel with Three-Dimensional Network Porous Structure

doi:10.19894/j.issn.1000-0518.230276

Chinese Journal of Applied Chemistry ›› 2024, Vol. 41 ›› Issue (4): 557-567.DOI: 10.19894/j.issn.1000-0518.230276

• Full Papers • Previous Articles Next Articles

Catalytic Decolorization Performance of Azo Dyes by Doped Nano-Nickel with Three-Dimensional Network Porous Structure

Xiu-Ying PENG¹, Xiao-Yan GAO², Song-Bai WANG³(), Fu LIU⁴()

^1.Department of Environment and Safety Engineering，Taiyuan Institute of Technology，Taiyuan 030008，China
^2.New Energy Design and Research Institute，Coal Industry Taiyuan Design and Research Institute Group Co. Ltd. ，Taiyuan 030001，China
^3.School of Chemistry and Chemical Engineering，Shanxi University，Taiyuan 030006，China
^4.Shanxi Biological Research Institute Co. Ltd. ，Taiyuan 030006，China

Received:2023-09-13 Accepted:2024-01-29 Published:2024-04-01 Online:2024-04-28
Contact: Song-Bai WANG,Fu LIU
About author:liufutt@163.com；
wsb9696@sxu.edu.cn
Supported by:
the Basic Research Project of Shanxi Provincial(202103021223351);the Talents of Taiyuan Institute of Technology(2022KJ019);Shanxi Scholarship Council of China(2021-011)

1. Catalytic Decolorization Performance of Azo Dyes by Doped Nano-Nickel with Three-Dimensional Network Porous Structure.pdf(502KB)

Abstract

Abstract:

Azo dyes are the main pollutants in textile printing and dyeing industrial wastewater， and their large discharge will seriously endanger the health of organisms. To develop effective catalysts for the decolorization of azo dyes in wastewater， Fe， Co dual-doped Ni ternary metal nanocrystalline is synthesized by a simple hydrothermal method with a three-dimensional network porous structure， named as Fe-Co-Ni NPs. The results show that the prepared ternary alloy nanomaterials have a three-dimensional network structure， and a small amount of Fe and Co doping could obtain higher saturation magnetic susceptibility without changing the polycrystalline structure of nickel. In the presence of sodium borohydride， Fe-Co-Ni NPs have prominent catalytic activity for Congo red reduction due to the synergistic effect of various metal elements. Congo red can be completely decolorized by Fe-Co-Ni NPs in 2 min with an apparent rate constant of 1.24 min^-1， significantly better than binary Fe-Ni （1.00 min^-1）， Co-Ni （0.96 min^-1） and single metal Ni （0.83 min^-1） nanocrystals. Fe-Co-Ni NPs also show good catalytic performances for the reductive degradation of other azo dyes （such as methyl orange and direct red 80） and nitrophenols. This ternary metal catalyst is very suitable for early decolorization treatment of industrial azo wastewater due to ease of synthesis， low cost， good decolorization effect on azo dyes， high stability and reusability.

Key words: Ternary nickel-based catalyst, Catalytic reduction, Azo dye, Sodium borohydride, Congo red

CLC Number:

O643

Xiu-Ying PENG, Xiao-Yan GAO, Song-Bai WANG, Fu LIU. Catalytic Decolorization Performance of Azo Dyes by Doped Nano-Nickel with Three-Dimensional Network Porous Structure[J]. Chinese Journal of Applied Chemistry, 2024, 41(4): 557-567.

Figures/Tables 9

Fig.1 （A） SEM，（B） TEM，（C） SAED and （D） HRTEM images of as-prepared Fe-Co-Ni NPs

Fig.2 Characterizations of structures and properties of as-prepared Ni-based nanoparticles：（A） XRD pattern；（B） Hysteresis loop

Fig.3 XPS spectrum of Fe-Co-Ni NPs：（A） Survey scan；（B） Ni2p

Fig.4 UV spectra of catalytic reduction of various Ni-based catalysts towards CR， the inner inset is the corresponding normalized concentration versus time curves at 497 nm

Fig.5 Catalytic reduction kinetic performances of various Ni-based catalysts towards CR

Table 1 Comparison of catalytic reduction performances of various metal catalysts towards CR

Catalysts	Dyes	k_app	Ref.
Ag/Ni-P（NMA-Maa）	CR	0.486 min^-1	［19］
Pd-Ni （Mesoporous silica）	CR	1.9±0.2×10^-2 s^-1 （（1.14±0.12） min^-1）	［18］
SPION@LT-Cu⁰	CR	0.200 min^-1	［22］
Au Nps	CR	2.43×10^-3 s^-1 （0.146 min^-1）	［23］
Cu-Ni/GP	CR	3.8×10^-3 s^-1 （0.228 min^-1）	［24］
Co _x Ni_1-_x Fe₂O₄	CR	0.025 9 min^-1	［25］
Fe-Co-Ni NPs	CR	1.24 min^-1	In this work

Fig.6 The cycle catalytic stability of Fe-Co-Ni NPs catalyst for congo red reduction reaction

Fig.7 UV spectrum of catalytic reduction of various Fe-Co-Ni NPs catalysts towards different organic pollutants， and the inner insets are the corresponding normalized concentration versus time curves

Fig.8 Schematic of catalytic reduction of organic pollutants by NaBH4 over Fe-Co-Ni NPs

References 31

1	MAENO K， PATEL B R， ENDO T， et al. Angle-sensitive photonic crystals for simultaneous detection and photocatalytic degradation of hazardous diazo compounds［J］. Micromachines， 2020， 11（1）： 93.
2	DIHOM H R， AL-SHAIBANI M M， MOHAMED R M S R， et al. Photocatalytic degradation of disperse azo dyes in textile wastewater using green zinc oxide nanoparticles synthesized in plant extract： a critical review［J］. J Water Proc Eng， 2022， 47： 102705.
3	LIN S H， PENG C F. Continuous treatment of textile wastewater by combined coagulation， electrochemical oxidation and activated sludge［J］. Water Res， 1996， 30（3）： 587-592.
4	PAŹDZIOR K， BILIŃSKA L， LEDAKOWICZ S. A review of the existing and emerging technologies in the combination of AOPs and biological processes in industrial textile wastewater treatment［J］. Chem Eng J， 2019， 376： 120597.
5	WU J， WANG T. Ozonation of aqueous azo dye in a semi-batch reactor［J］. Water Res， 2001， 35（4）： 1093-1099.
6	RATHI B S， KUMAR P S. Sustainable approach on the biodegradation of azo dyes： a short review［J］. Curr Opin Green Sustainable Chem， 2022， 33： 100578.
7	NDLOVU L N， MALATJIE K I， DONGA C， et al. Catalytic degradation of methyl orange using beta cyclodextrin modified polyvinylidene fluoride mixed matrix membranes imbedded with in-situ generated palladium nanoparticles［J］. J Appl Polym Sci， 2023， 140（1）： e53270.
8	于宗龙，贾春晓，路鑫，等. 离子液体@TiO₂纳米复合材料的制备及其光催化性能［J］. 应用化学， 2016， 33（4）： 459-465.
	YU Z L， JIA C X， LU X， et al. Synthesis of ionic liquid@TiO₂ nanocomposites and their photocatalytic performance［J］. Chin J Appl Chem， 2016， 33（4）： 459-465.
9	李文进，姚威龙，徐嘉鑫，等. Ho³⁺掺杂铁酸铋的制备及光催化性［J］. 应用化学， 2019， 36（1）： 91-96.
	LI W J， YAO W L， XU J X， et al. Preparation and photocatalytic properties of Ho³⁺ doping BiFeO₃［J］. Chin J Appl Chem， 2019， 36（1）： 91-96.
10	SUN L， MO Y， ZHANG L. A mini review on bio-electrochemical systems for the treatment of azo dye wastewater： state-of-the-art and future prospects［J］. Chemosphere， 2022， 294： 133801.
11	NAZ M， RAFIQ A， IKRAM M， et al. Elimination of dyes by catalytic reduction in the absence of light： a review［J］. J Mater Sci， 2021， 56： 15572-15608.
12	ZHU Y， WANG W， NI J， et al. Cultivation of granules containing anaerobic decolorization and aerobic degradation cultures for the complete mineralization of azo dyes in wastewater［J］. Chemosphere， 2020， 246： 125753.
13	ZHENG L Q， YU X D， XU J J， et al. Reversible catalysis for the reaction between methyl orange and NaBH₄ by silver nanoparticles［J］. Chem Commun， 2015， 51（6）： 1050-1053.
14	MEI S， PAN M， GAO S， et al. Organic-inorganic bimetallic hybrid particles with controllable morphology for the catalytic degradation of organic dyes［J］. New J Chem， 2020， 44（20）： 8366-8378.
15	SHAH S A， AHMAD Z， KHAN S A， et al. Biomass impregnated zero-valent Ag and Cu supported-catalyst： evaluation in the reduction of nitrophenol and discoloration of dyes in aqueous medium［J］. J Organomet Chem， 2021， 938： 121756.
16	KHAN N， SHAHIDA B， KHAN S A， et al. Anchoring Zero-Valent Cu and Ni nanoparticles on carboxymethyl cellulose-polystyrene-block polyisoprene-block polystyrene composite films for nitrophenol reduction and dyes degradation［J］. J Polym Environ， 2023， 31（2）： 608-620.
17	HABAS S E， LEE H， RADMILOVIC V， et al. Shaping binary metal nanocrystals through epitaxial seeded growth［J］. Nat Mater， 2007， 6（9）： 692-697.
18	PANDEY P C， MITRA M D， TIWARI A K， et al. Synthetic incorporation of palladium-nickel bimetallic nanoparticles within mesoporous silica/silica nanoparticles as efficient and cheaper catalyst for both cationic and anionic dyes degradation［J］. J Environ Sci Health， Part A， 2021， 56（4）： 460-472.
19	ARIF M. Catalytic degradation of azo dyes by bimetallic nanoparticles loaded in smart polymer microgels［J］. RSC Adv， 2023， 13（5）： 3008-3019.
20	GONG Z， MA T， LIANG F. Syntheses of magnetic blackberry-like Ni@Cu@Pd nanoparticles for efficient catalytic reduction of organic pollutants［J］. J Alloys Compd， 2021， 873： 159802.
21	ALSHEHRI A A， MALIK M A. Facile one-pot biogenic synthesis of Cu-Co-Ni trimetallic nanoparticles for enhanced photocatalytic dye degradation［J］. Catalysts， 2020， 10（10）： 1138.
22	AHMAD I， MANZOOR K， AALAM G， et al. Facile synthesis of L-tryptophan functionalized magnetic nanophotocatalyst supported by copper nanoparticles for selective reduction of organic pollutants and degradation of azo dyes［J］. Catal Lett， 2022： 1-20.
23	DEOKAR G K， INGALE A G. Exploring effective catalytic degradation of organic pollutant dyes using environment benign， green engineered gold nanoparticles［J］. Inorg Chem Commun， 2023， 151： 110649.
24	ISMAIL M， KHAN M I， KHAN S B， et al. Green synthesis of plant supported Cu single bond Ag and Cu single bond Ni bimetallic nanoparticles in the reduction of nitrophenols and organic dyes for water treatment［J］. J Mol Liq， 2018， 260： 78-91.
25	CHEN R， WANG W， ZHAO X， et al. Rapid hydrothermal synthesis of magnetic CoxNi_1- xFe₂O₄ nanoparticles and their application on removal of Congo red［J］. Chem Eng J， 2014， 242： 226-233.
26	ADITYA T， PAL A， PAL T. Nitroarene reduction： a trusted model reaction to test nanoparticle catalysts［J］. Chem Commun， 2015， 51（46）： 9410-9431.
27	AMIR M， KURTAN U， BAYKAL A. Rapid color degradation of organic dyes by Fe₃O₄@His@Ag recyclable magnetic nanocatalyst［J］. J Ind Eng Chem， 2015， 27： 347-353.
28	VIDHU V K， PHILIP D. Catalytic degradation of organic dyes using biosynthesized silver nanoparticles［J］. Micron， 2014， 56： 54-62.
29	LUO S， QIN P， SHAO J， et al. Synthesis of reactive nanoscale zero valent iron using rectorite supports and its application for orange II removal［J］. Chem Eng J， 2013， 223： 1-7.
30	YANG Y， ZHANG H， HUANG H， et al. Iron-loaded carbon nanotube-microfibrous composite for catalytic wet peroxide oxidation of m-cresol in a fixed bed reactor［J］. Environ Sci Pollut Res， 2020， 27： 6338-6351.
31	BHOL P， MOHANTY P S. Smart microgel-metal hybrid particles of PNIPAM-co-PAA@AgAu： synthesis， characterizations and modulated catalytic activity［J］. J Phys： Condens Mat， 2020， 33（8）： 084002.

[1]	Fan WU, He-Yuan TIAN, Peng LIU, Li-Wei SUN, Yi-Bo ZHANG, Xiang-Guang YANG. Spinel Mangane-Based Catalysts with High Oxygen Vacancy Used for NH₃-SCR Reaction at Low Temperature [J]. Chinese Journal of Applied Chemistry, 2023, 40(5): 697-707.
[2]	SUI Li-Li, JIANG Hui-Ye, WANG Di, HUANG Wei-Wei, SUI Wei-Wei, SHEN Shu-Chang, WANG Ping, ZHANG Wen-Zhi, WANG Wen-Bo, ZHAO Bing, LIU Yong-Zhi. Construction of Hierarchical NiO Microspheres and the Adsorption Capacity to Congo Red Azo-dye [J]. Chinese Journal of Applied Chemistry, 2021, 38(4): 447-456.
[3]	ZHAO Shiduo, LI Fang, LI Qiming, LIANG Zhihua. Preparation of USY Zeolite Supported Cobalt Boride Amorphous Alloy Catalysts and Its Application in Catalytic Hydrogen Production via Hydrolysis of Sodium Borohydride [J]. Chinese Journal of Applied Chemistry, 2016, 33(6): 655-660.
[4]	SUN Qian, YANG Yingchun*, YE Zhixiang, ZHANG Lin. Resonance Rayleigh Scattering and Resonance nonlinear Scattering Spectra of Hg(Ⅱ)-phen-CR Systems and Their Analytical Application [J]. Chinese Journal of Applied Chemistry, 2013, 30(04): 474-480.
[5]	ZHU Chuangao*, WANG Fengwu. Preparation of LiBH4 by Electrocatalytic Reduction of LiBO2 at a Nano-PbO/Ti Electrode [J]. Chinese Journal of Applied Chemistry, 2012, 29(10): 1194-1198.
[6]	Hu Jianli, Li Xuanrong, Liao Xianxin. NEW MALEIC MONOAMIDE DYES FOR PET/COTTON BLENDS [J]. Chinese Journal of Applied Chemistry, 1992, 0(6): 117-119.
[7]	Li Xuanrong, Zhu Weiqun, Liao Xianxin. NEW MALEIC MONOAMIDE DYES FOR PET/COTTON BLENDS [J]. Chinese Journal of Applied Chemistry, 1989, 0(2): 86-88.

Catalytic Decolorization Performance of Azo Dyes by Doped Nano-Nickel with Three-Dimensional Network Porous Structure

RichHTML

PDF

Supplement

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 9

References 31

Related Articles 7

Recommended Articles

Metrics

Comments