Recent Advances in Direct Oxidation of Methane to Methanol

doi:10.19894/j.issn.1000-0518.210461

Chinese Journal of Applied Chemistry ›› 2022, Vol. 39 ›› Issue (4): 540-558.DOI: 10.19894/j.issn.1000-0518.210461

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Recent Advances in Direct Oxidation of Methane to Methanol

Ke WANG, Xiao WANG(), Shu-Yan SONG

State Key Laboratory of Rare Earth Resource Utilization，Changchun Institute of Applied Chemistry，Chinese Academy of Sciences，Changchun 130022，China

Received:2021-09-10 Accepted:2021-12-10 Published:2022-04-01 Online:2022-04-19
Contact: Xiao WANG
About author:skybyyn@ciac.ac.cn
Supported by:
the National Natural Science Foundation of China(21771173);the National Key Research and Development Program of China(2016YFA0203200)

Abstract

Abstract:

The methods for synthesizing methanol from methane include indirect method and direct catalytic oxidation method， but the indirect method requires high equipment， and the methane conversion rate and methanol selectivity are not ideal. Direct catalytic oxidation method （DMTM） can produce methanol with high selectivity through a one-step reaction， and has huge application potential. For DMTM， the homogeneous catalytic system usually requires a special reaction medium combined with a precious metal catalyst. Although the reaction efficiency is high， it is corrosive to the reaction equipment， the product is not easy to separate， and the application prospect is poor. Liquid phase-heterogeneous catalysis generally uses H₂O₂ as the oxidant， Au， Pd， Fe， Cu and other metal elements as the main active component of the catalyst， and·OH is the main oxidation active substance， which can be used at low temperature to realize the activation and oxidation of methane. Therefore， heterogeneous catalytic systems are currently the mainstream of research. Gas phase-heterogeneous catalysis mainly uses O₂ and N₂O as oxidants. The former is more active， and the latter is more selective for products. In addition， H₂O in anaerobic systems can also be directly used as oxygen donors， commonly Cu， Fe， Rh， etc. elements are used as catalysts. Zeolite molecular sieves are the most widely used support， and metal oxides， metal organic frameworks （MOFs） and graphene are also involved. Multi-metal synergistic catalysis has achieved good results. This article mainly summarizes the research on the direct catalytic oxidation of thermally catalyzed methane to methanol in recent years， and prospects for future research directions.

Key words: Homogeneous catalysis, Heterogeneous catalysis, Gas phase-heterogeneous catalysis, Liquid phase-heterogeneous catalysis, CH₄ oxidation

CLC Number:

O643

Ke WANG, Xiao WANG, Shu-Yan SONG. Recent Advances in Direct Oxidation of Methane to Methanol[J]. Chinese Journal of Applied Chemistry, 2022, 39(4): 540-558.

Figures/Tables 18

Fig.1 Mechanism of Pt electrophilic catalysis of CH4 oxidation in acetic acid system［9］

Fig.2 Mechanism of Hg catalyzed CH4 oxidation in concentrated sulfuric acid system［11］

Fig.3 Mechanism of Pt catalytic oxidation of CH4 in fuming sulfuric acid system［12］

Fig.4 Mechanism of I catalytic oxidation of CH4 in fuming sulfuric acid system［15］

Fig.5 Model of Cu trimer active center［17］

Fig.6 Three reaction mechanisms of H2O2 oxidation of CH4 on Fe/ZSM-5 molecular sieve［21］

Fig.7 Mechanism of Fe dimer catalyzed oxidation of CH4 to CH3OH［22］

Fig.8 The reaction mechanism of oxidation of CH4 to CH3OH catalyzed by oxidant K2S2O8 and ZV Cu［24］

Fig.9 The reaction mechanism of CH4 oxidation in the presence of H2O2 and O2 molecules［32］

Fig.10 Energy network diagram of Fe2O3 （0001） surface activation of CH4［45］Yellow O： lattice O； red O： iron-based O； brown arrows： CH4 decomposition； yellow and blue arrows represent the oxidative decomposition of CH4 in lattice O and iron-based O， respectively； green dotted arrows represent the formation of CO2 and H2O； The purple arrow indicates the regeneration of the active site； the curved arrow indicates the adsorption/desorption of gas phase species

Fig.11 Mechanism of N2O as the oxidant and Fe2O3 nanoclusters catalyzing the activation and oxidation of CH4 to methanol［46］

Fig.12 Mechanism of dimer Cu-zeolite catalyzing CH4 to CH3OH［54］

Fig.13 Energy calculation diagram for the anaerobic catalysis of dimer Cu-zeolite from CH4 to CH3OH（kJ/mol）［55］

Fig.14 The possible formation mechanism of Cu species during the activation of N2O and O2 （OF is the O atom in the zeolite framework）［7］

Table 1 Synthesis of CH3OH by Cu?zeolite catalyst activated CH4 in recent years

催化剂

Catalyst

组成

Composition

氧化剂

Oxidant

反应条件

Reaction conditions

选择性

Selective

转化率

Conversion

产量/h

Yields

参考文献

Ref.

Cu?MAZ

n（Si）/n（Al）=4∶3

4.4%（mass fraction）Cu

O₂

723 K，O₂；473 K，

$p C H 4$ =0.1 MPa，3 MPa

150 μmol/g_cat、

200 μmol/g

TON=0.48

［63］

Cu?MAZ

（棒状）

（rod）

n（Si）/n（Al）=4.32

4.64%（mass fraction）Cu

O₂

723 K，O₂；473 K，

p C H 4

=0.6 MPa

197 μmol/g

［64］

Table 1 Synthesis of CH3OH by Cu?zeolite catalyst activated CH4 in recent years

催化剂

Catalyst

组成

Composition

氧化剂

Oxidant

反应条件

Reaction conditions

选择性

Selective

转化率

Conversion

产量/h

Yields

参考文献

Ref.

Cu?MAZ

n（Si）/n（Al）=4∶3

4.4%（mass fraction）Cu

O₂

723 K，O₂；473 K，

$p C H 4$ =0.1 MPa，3 MPa

150 μmol/g_cat、

200 μmol/g

TON=0.48

［63］

Cu?MAZ

（棒状）

（rod）

n（Si）/n（Al）=4.32

4.64%（mass fraction）Cu

O₂

723 K，O₂；473 K，

p C H 4

=0.6 MPa

197 μmol/g

［64］

Fig.15 Side view of GOPL calculation geometry［79］

Fig.16 The effect of water on the catalyst catalyzing the product selectivity improvement of CH4 to CH3OH （a） CeO2/Cu2O/Cu（111） catalyst，SAC=0.4［81］；（b）Ni/CeO2（111） catalyst，SAC=0.15［83］（T=450 K，pCH4=0.1 MPa，pO2=0.05 MPa）

Fig.17 The catalytic effect and structure information of Ru x Ir1-x /CuO catalyst （a） CH3OH and by-product yield；（b） selectivity；（c） charge analysis structure model［85］

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Recent Advances in Direct Oxidation of Methane to Methanol

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