Research Progress of Metal Sulfides in Rechargeable Batteries

doi:10.11944/j.issn.1000-0518.2020.12.200190

Chinese Journal of Applied Chemistry ›› 2020, Vol. 37 ›› Issue (12): 1384-1402.DOI: 10.11944/j.issn.1000-0518.2020.12.200190

• Review • Previous Articles Next Articles

Research Progress of Metal Sulfides in Rechargeable Batteries

HUI Kanglong^a,b, FU Jipeng^b, GAO Tian^a*, TANG Mingxue^b*

^aDepartment of Physics,Shanghai University of Electric Power,Shanghai 200090,China;
^bCenter for High Pressure Science & Technology Advanced Research,Beijing 100094,China

Received:2020-06-17 Revised:2020-07-06 Accepted:2020-08-18 Published:2020-12-01 Online:2020-12-07
Contact: TANG Mingxue, professor; Tel:0431-85454658; E-mail:mingxue.tang@hpstar.ac.cn; Research interests:metal ion battery materials synthesis and cycling mechanism
Co-corresponding author:GAO Tian, professor; Tel:021-61655165; E-mail:gaotian@shiep.edu.cn; Research interests:new energy materials and devices
Supported by:
National Natural Science Foundation of China (No.2197040727)

Abstract

Abstract: Lithium/sodium ion batteries with low cost, long life, high safety, high performance and easy massive fabrication have become very effective secondary energy storage devices. For lithium/sodium batteries, the electrode materials have crucial influence on their performance and cycling life. Metal sulfides are regarded as potential anode materials for lithium/sodium ion batteries because of their high specific capacity and low potential. Metal sulfides show drawbacks, such as shuttle effect and volume change, resulting in structural deformation, together with decayed capacity and reduced stability. This review summarizes the research progress on the modification and properties of metal sulphide anode materials. Designing controlled complex structure and composite anodes enhances electronic conductivity and minimizes the effect caused by volume change, and thereby further to achieve better electrochemical performance. The structure-function relationship of metal sulphide materials is discussed and their positive prospects are proposed.

Key words: metal sulphide, lithium ion battery, sodium ion battery, electrochemical performance, structure-function relationship

CLC Number:

O613

HUI Kanglong, FU Jipeng, GAO Tian, TANG Mingxue. Research Progress of Metal Sulfides in Rechargeable Batteries[J]. Chinese Journal of Applied Chemistry, 2020, 37(12): 1384-1402.

References

[1] Zheng X,Li J,et al. A Review of Research on Hematite as Anode Material for Lithium-Ion Batteries[J]. Ionics,2014,20(12):1651-1663.
[2] HE Donghua,TANG Anping,SHEN Jie,et al. Progress in Lithium Vanadyl Phosphate as Electrode Materials for Lithium-Ion Batteries[J]. Chinese J Appl Chem,2014,31(10):1115-1122(in Chinese).
贺冬华,唐安平,申洁,等. 锂离子电池电极材料磷酸氧钒锂的研究进展[J]. 应用化学,2014,31(10):1115-1122.
[3] Tian L,Zou H L,Fu J X,et al. Topotactic Conversion Route to Mesoporous Quasi-Single-Crystalline Co₃O₄ Nanobelts with Optimizable Electrochemical Performance[J]. Adv Funct Mater,2010,20:617-623.
[4] Xu X,Ji S,Gu M,et al. In Situ Synthesis of MnS Hollow Microspheres on Reduced Graphene Oxide Sheets as High-Capacity and Long-Life Anodes for Li- and Na-Ion Batteries[J]. ACS Appl Mater Interfaces,2015,7(37):20957.
[5] ZUO Zicheng,LI Liangyu. Applications of Graphdiyne in Li⁺/Na⁺ Battery Anodes[J]. Chinese J Appl Chem,2018,35(9):1057-1066(in Chinese).
左自成,李玉良. 石墨炔在锂/钠离子电池负极中的应用[J]. 应用化学,2018,35(9):1057-1066.
[6] Xiao Y,Lee S H,Sun Y K,et al. The Application of Metal Sulfides in Sodium-Ion Batteries[J]. Adv Energy Mater,2017,7:1601329-1601349.
[7] LI Zongfeng,DONG Guixia,KANG Jingrui,et al. Research Progress of Transition Metal Sulfides in Lithium-Ion Batteries[J]. Chinese J Power Sources,2019,43(6):1042-1046(in Chinese).
李宗峰,董桂霞,亢静锐,等. 过渡金属硫化物在锂离子电池中的研究进展[J]. 电源技术,2019,43(6):1042-1046.
[8] MA Yanmei. Research Progress of Sulphide Anode Materials for Sodium-Ion Batteries[J]. Energy Storage Sci Technol,2019,8(3):52-58(in Chinese).
马艳梅. 钠离子电池硫化物负极材料的研究进展[J]. 储能科学与技术,2019,8(3):52-58.
[9] WEI Keyi,LI Xue. Research Status of Metal Sulfides in Lithium-Ion Batteries[J]. Electron Mass,2020,(3):4-7(in Chinese).
韦克毅,李雪. 金属硫化物在锂离子电池中的研究现状[J]. 电子质量,2020,(3):4-7.
[10] Luo B,Fang Y,Wang B,et al. Two Dimensional Graphene-SnS₂ Hybrids with Superior Rate Capability for Lithium-Ion Storage[J]. Energy Environ Sci,2012,5(1):5226-5230.
[11] Yang S,Zhang Y,Wang S,et al. Rational Construction of MoS₂/Mo₂N/C Hierarchical Porous Tubular Nanostructures for Enhanced Lithium Storage[J]. J Mater Chem A,2019,7:23886-23894.
[12] Hu X,Li Y,Zeng G,et al. Three-Dimensional Network Architecture with Hybrid Nanocarbon Composites Supporting Few-Layer MoS₂ for Lithium and Sodium Storage[J]. ACS Nano,2018,12(2):1592-1602.
[13] Lim Y V,Wang Y,Guo L,et al. Cubic-shaped WS₂ Nanopetals on Prussian Blue Derived Nitrogen-Doped Carbon Nanoporous Framework for High Performance Sodium-ion Batteries[J]. J Mater Chem A,2017,5:10406-10415.
[14] Zhang X,Zhao R F,Wu Q H,et al. Ultrathin WS₂ Nanosheets Vertically Embedded in Hollow Mesoporous Carbon Framework-A Triple-Shelled Structure with Enhanced Lithium Storage and Electrocatalytic Properties[J]. J Mater Chem A,2018,6:19004-19012.
[15] Yu X Y,Yu L,Lou X W,et al. Metal Sulfide Hollow Nanostructures for Electrochemical Energy Storage[J]. Adv Energy Mater,2016,6(3):1501333.
[16] Wang J G,Sun H H,Liu H Y,et al. Edge-Oriented SnS₂ Nanosheet Arrays on Carbon Paper as Advanced Binder-Free Anodes for Li-Ion and Na-Ion Batteries[J]. J Mater Chem A,2017,5:23115-23122.
[17] Chen M,Zhang Z,Si L,et al. Engineering of Yolk-Double Shell Cube-like SnS@N-S Codoped Carbon as a High-Performance Anode for Li- and Na-Ion Batteries[J]. ACS Appl Mater Interfaces,2019,11(38):35050-35059.
[18] Wang L,Li X,Jin Z,et al. Spatially Controlled Synthesis of Superlattice-like SnS/Nitrogen-Doped Graphene Hybrid Nanobelts as High-Rate and Durable Anode Materials for Sodium-Ion Batteries[J]. J Mater Chem A,2019,7:27475-27483.
[19] Zhang Q,Bock D C,Takeuchi K J,et al. Probing Titanium Disulfide-Sulfur Composite Materials for Li-S Batteries via In Situ X-Ray Diffraction (XRD)[J]. J Electrochem Soc,2017,4(164):A897-A901.
[20] Chaturvedi A,Edison E,Arun N,et al. Two Dimensional TiS₂ as a Promising Insertion Anode for Na-Ion Battery[J]. Chem Select,2018,3(2):524-528.
[21] Vega-Mayoral V,Tian R,Kelly A,et al. Solvent-Exfoliation Stabilizes TiS₂ Nanosheets Against Oxidation, Facilitating Lithium Storage Applications[J]. Nanoscale,2019,11:6206-6216.
[22] Tao H W,Zhou M,Wang R X,et al. TiS₂ as an Advanced Conversion Electrode for Sodium-Ion Batteries with Ultra-high Capacity and Long-Cycle Life[J]. Adv Sci,2018,11:1801021.
[23] Lu J,Lian F,Guan L,et al. Adapting FeS₂ Micron Particles as an Electrode Material for Lithium-Ion Batteries via Simultaneous Construction of CNT Internal Networks and External Cages[J]. J Mater Chem A,2019,7:991-997.
[24] Xie X,Hu Y,Fang G,et al. Towards a Durable High Performance Anode Material for Lithium Storage:Stabilizing N-Doped Carbon Encapsulated FeS Nanosheets with Amorphous TiO₂[J]. J Mater Chem A,2019,7:16541-16552.
[25] Xiao F P,Yang X M,Yu Y W,et al. Metal-Organic Framework Derived CoS₂ Wrapped with Nitrogen-Doped Carbon for Enhanced Lithium/Sodium Storage Performance[J]. ACS Appl Mater Interfaces,2020,3(6):217-226.
[26] Pan Y L,Cheng X D,Gong L L,et al. Double-morphology CoS₂ Anchored on N-Doped Multichannel Carbon Nanofibers as High-Performance Anode Materials for Na-Ion Batteries[J]. ACS Appl Mater Interfaces,2018,10(37):31441-31451.
[27] Yang Z G,Wu Z G,Liu J,et al. Platelet-Like CuS Pregnated with Twin Crystal for High Performance Sodium-Ion Storage[J]. J Mater Chem A,2020,8:8049-8057.
[28] Wang Y,Zhang Y,Li H,et al. Realizing High Reversible Capacity:3D Intertwined CNTs Inherently Conductive Network for CuS as an Anode for Lithium-Ion Batteries[J]. Chem Eng J,2017,1(332):49-56.
[29] Kang W P,Wang Y Y,Xu J,et al. Recent Progress in Layered Metal Dichalcogenide Nanostructures as Electrodes for High-Performance Sodium-Ion batteries[J]. J Mater Chem A,2017,5:7667-7690.
[30] Hao J,Zhang J,Xia G L,et al. Heterostructure Manipulation via in Situ Localized Phase Transformation for High-Rate and Highly Durable Lithium Ion Storage[J]. ACS Nano,2018,12(10):10430-10438.
[31] Han L,Wu S,Hu Z,et al. Hierarchically Porous MoS₂-Carbon Hollow Rhomboids for Superior Performance of the Anode of Sodium-Ion Batteries[J]. ACS Appl Mater Interfaces,2020,12(9):10402-10409.
[32] Zeng X,Ding Z,Ma C,et al. Hierarchical Nanocomposite of Hollow N-Doped Carbon Spheres Decorated with Ultrathin WS₂ Nanosheets for High-Performance Lithium-Ion Battery Anode[J]. ACS Appl Mater Interfaces,2016,8(29):18841-18848.
[33] Li T,Guo R,Luo Y,et al. Improved Lithium and Sodium Ion Storage Properties of WS₂ Anode with Three-layer Shell Structure[J]. Electrochim Acta,2020,1(331):135424.
[34] Hu Z,Zhu Z,Cheng F,et al. Pyrite FeS₂ for High-rate and Long-life Rechargeable Sodium Batteries[J]. Energy Environ Sci,2015,8(4):1309-1316.
[35] Man Z,Li P,Zhou D,et al. Two Birds with One Stone:FeS₂@C Yolk-Shell Composite for High-Performance Sodium-Ion Energy Storage and Electromagnetic Wave Absorption[J]. Nano Lett,2020,5(20):3769-3777.
[36] Bi R,Zeng C,Huang H,et al. Metal-Organic Frameworks Derived Hollow NiS₂ Spheres Encased in Graphene Layers for Enhanced Sodium-Ion Storage[J]. J Mater Chem A,2018,6:14077-14082.
[37] Kim H,Cho G B,Kim K W,et al. Fabrication of Superelastic NiS/TiNi Electrode/Current Collector Materials[J]. Phys Scr,2007,(T129):85.
[38] Nam T H,Ahn H J,Kim K W,et al. Hybrid Superelastic Metal-Metal Sulfide Materials for Current Collector and Anode of Battery:US, 20080066832.X[P]. 2005-12-29.
[39] Xie H Q,Chen M,Wu L M,et al. Hierarchical Nanostructured NiS/MoS₂/C Composite Hollow Spheres for High Performance Sodium-Ion Storage Performance[J]. ACS Appl Mater Interfaces,2019,11:41222-41228.
[40] Li B,Wang R,Chen Z,et al. Embedding Heterostructured MnS/Co_1-xS Nanoparticles in Porous Carbon/Graphene for Superior Lithium Storage[J]. J Mater Chem A,2019,7:1260-1266.
[41] Hou B T,Wang X L,Wang J X,et al. In situ Synthesis of Homogeneous Ce₂S₃/MoS₂ Composites and Their Electrochemical Performance for Lithium Ion Batteries[J]. RSC Adv,2017,7:6309-6314.
[42] Zhang Y,Lu F,Pan L,et al. Improved Cycling Stability of NiS₂ Cathode Through Designing “Kiwano” Hollow Structure[J]. J Mater Chem A,2018,6:11978-11984.
[43] Li Q,Li L,Wu P,et al. Silica Restricting the Sulfur Volatilization of Nickel Sulfide for High-Performance Lithium-Ion Batteries[J]. Adv Energy Mater,2019,20:1901153.
[44] Kim H H,K Sadan M,Kim C,et al. Simple and Scalable Synthesis of CuS as an Ultrafast and Long-Cycling Anode for Sodium-Ion Batteries[J]. J Mater Chem A,2019,7:16239-16248.
[45] SHI Yongchao,TANG Mingxue. NMR/EPR on Rechargeable Batteries[J]. Acta Phys-Chim Sin,2020,36(4):1905004(in Chinese).
史永超,唐明学. 可充电池的磁共振研究[J]. 物理化学学报,2020,36(4):1905004.
[46] Chien P H,Feng X,Tang M,et al. Li Distribution Heterogeneity in Solid Electrolyte Li₁₀GeP₂S₁₂ upon Electrochemical Cycling Probed by ⁷Li MRI[J]. J Phys Chem Lett,2018,9:1990-1998.
[47] Tang M,Sarou-Kanian V,Melin P,et al. Following Lithiation Fronts in Paramagnetic Electrodes with in situ Magnetic Resonance Spectroscopic Imaging[J]. Nat Commun,2016,7:13284.
[48] Tang M,Dalzini A,Li X,et al. Operando EPR for Simultaneous Monitoring of Anionic and Cationic Redox Processes in Li-Rich Metal Oxide Cathodes[J]. J Phys Chem Lett,2017,8(17):4009-4016.
[49] Zheng H,Wang L,Li K,et al. Pressure Induced Polymerization of Acetylide Anions in CaC₂ and 10⁷ Fold Enhancement of Electrical Conductivity[J]. Chem Sci,2016,8:298-304.

Research Progress of Metal Sulfides in Rechargeable Batteries

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Bing-Shuai CHEN, Hai-Tao ZHUO, Shu HUANG, Shao-Jun CHEN. Advances of High-Performance Polymer Binders for Silicon-Based Anodes [J]. Chinese Journal of Applied Chemistry, 2023, 40(5): 625-639.
[2]	Xue-Jian SHI, Wan-Qiang LIU, Chun-Li WANG, Yong CHENG, Li-Min WANG. Research Progress of Sb-based Anode Materials for Potassium Ion Batteries [J]. Chinese Journal of Applied Chemistry, 2023, 40(2): 210-228.
[3]	En-Tong WANG, Lin-Fang YANG. Preparation and Properties of LiNi_0.6Co_0.2Mn_0.2O₂ Cathode Material for High Specific Capacity Lithium Ion Battery [J]. Chinese Journal of Applied Chemistry, 2022, 39(8): 1209-1215.
[4]	Yu MENG, Qing ZHANG, Wen-Hao PENG, Xiao-Fei ZHU, De-Feng ZHOU. Preparation and Electrochemical Performance of Pr_0.8Sr_0.2Fe_0.7Ni_0.3O_3-_δ ⁃Pr_1.2Sr_0.8Ni_0.6Fe_0.4O₄₊_δ Composite Cathode [J]. Chinese Journal of Applied Chemistry, 2022, 39(5): 797-808.
[5]	LIU Xue, MA Hua, XU Heng, JI Haicong, WANG Dong. Lithium Storage Properties of Non-woven Fabric Based Polypyrrole Flexible Electrodes [J]. Chinese Journal of Applied Chemistry, 2020, 37(5): 555-561.
[6]	WANG Jinying, QU Jiangying, LI Jielan, TANG Zhanlei, ZANG Yunhao, WANG Tao, GU Jianfeng, ZHOU Gang, GAO Feng. Two-Step Coating Synthesis of Silicon/Carbon Composite Based on Coal Tar Pitch and Its Lithium Battery Performance [J]. Chinese Journal of Applied Chemistry, 2020, 37(5): 562-569.
[7]	WANG Chunli,SUN Lianshan,ZHONG Ming,WANG Limin,CHENG Yong. Research Progress of Transition Metal and Compounds for Lithium-Sulfur Batteries [J]. Chinese Journal of Applied Chemistry, 2020, 37(4): 387-404.
[8]	CHEN Jiaqi, ZHOU Yan, SUN Jingwen, ZHU Junwu, WANG Xin, FU Yongsheng. Recent Progress of Metal Organic Frameworks-Based Hollow Materials [J]. Chinese Journal of Applied Chemistry, 2020, 37(11): 1221-1235.
[9]	CAI Min, WU Chunyan, XIE Yishun, BAN Gui, LAI Feiyan, HUANG Xiaoying, ZHANG Xiaohui. Effects of Ethyl Orthosilicate on the Electrochemical Performance of High-Voltage Lithium Nickel Manganese Oxide-Based Full-Cell [J]. Chinese Journal of Applied Chemistry, 2020, 37(11): 1301-1308.
[10]	YANG Tao, LIU Wenfeng, MA Mengyue, DONG Hongyu, YANG Shuting. Fade Mechanism of Ternary Lithium Ion Power Battery [J]. Chinese Journal of Applied Chemistry, 2020, 37(10): 1181-1186.
[11]	WU Xiangkun,ZHAN Qiushe,ZHANG Lan,ZHANG Suojiang. Progress on Microstructural Optimization and Controllable Preparation Technology for Lithium Ion Battery Electrodes [J]. Chinese Journal of Applied Chemistry, 2018, 35(9): 1076-1092.
[12]	XU Xiaolong, HAO Zhendong, LI Haoqiang, WANG Hao, LIU Jingbing, YAN Hui. Modification of LiFePO₄ Based on Zeolite Imidazolate Framework-8 [J]. Chinese Journal of Applied Chemistry, 2018, 35(8): 939-945.
[13]	Zhaomin WANG, Zheng YI, Ming ZHONG, Yong CHENG, Limin WANG. Research Progress of Antimony-Based Anode Materials for Lithium Ion Batteries [J]. Chinese Journal of Applied Chemistry, 2018, 35(7): 745-755.
[14]	Ruoxin YUAN, Xingang LIU, Chuhong ZHANG. Preparation of Tin Oxide-Graphene Flexible Electrode and Its Application in Lithium Ion Battery [J]. Chinese Journal of Applied Chemistry, 2018, 35(7): 825-833.
[15]	CHEN Lihui,WU Qiuhan,PAN Pei,SONG Zixuan,WANG Feng,DING Yu. Spinel Lithium Manganese Oxide Octahedral Nanoparticles with Excellent Electrochemical Performance as Cathode Materials for Lithium-Ion Batteries [J]. Chinese Journal of Applied Chemistry, 2018, 35(11): 1384-1390.