Research and Application Progress on Porous Organic Polymers for Adsorption and Separation of Organic Pollutants in Water System

doi:10.11944/j.issn.1000-0518.2018.09.180184

Chinese Journal of Applied Chemistry ›› 2018, Vol. 35 ›› Issue (9): 1019-1025.DOI: 10.11944/j.issn.1000-0518.2018.09.180184

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Research and Application Progress on Porous Organic Polymers for Adsorption and Separation of Organic Pollutants in Water System

AN Liancai^a,HAN Jiufang^a,ZHANG Yinghui^a^*(),BU Xianhe^a^b^*()

^aSchool of Materials Science and Engineering,Nankai University,Tianjin 300350,China
^bCollege of Chemistry,Nankai University,Tianjin 300071,China

Received:2018-05-21 Accepted:2018-05-23 Published:2018-09-01 Online:2018-08-06
Contact: ZHANG Yinghui,BU Xianhe
Supported by:
Supported by the National Natural Science Foundation of China(No.21531005), Tianjin Natural Science Foundation(No.16JCZDJC36900)

Abstract

Abstract:

Organic pollutants in water system are widely viewed as a serious threat to ecologic safety and human health, and it has become a global issue to develop effect technology to control and reduce organic pollutants in water system. Adsorption treatment, based on various porous materials, is believed to be a promising solution to this question. Porous organic polymers(POPs), characterized with high specific surface area, high physical and chemical stability, and easy functionalization, exhibit great potential application in tackling organic pollution of water. In this article, the recent advances were briefly reviewed on the application of POPs in adsorbing organic pollutants such as common organic solvents, pesticides and insecticides, organic dyes in water system.

Key words: porous organic polymers, organic pollutants, water system, adsorption

AN Liancai, HAN Jiufang, ZHANG Yinghui, BU Xianhe. Research and Application Progress on Porous Organic Polymers for Adsorption and Separation of Organic Pollutants in Water System[J]. Chinese Journal of Applied Chemistry, 2018, 35(9): 1019-1025.

References

[1]	HUANG Zhihui,LI Yuzhen,ZHANG Ning,et al. Research Progress of Inorganic, Organic and Composite Materials Handing Organic Pollutants[J]. Chem Res Appl,2016,28(6):770-776(in Chinese). 黄志慧,李育珍,张宁,等. 无机、有机及复合吸附材料处理有机污染物的研究[J]. 化学研究与应用,2016,28(6):770-776.
[2]	Davankov V A,Rogozhin S V,Tsyurupa M P.Macrocrosslinked Polystyrenes:US Patent,Appl[P]. 1971,3729,457.
[3]	McKeown N B,Makhseed S,Budd P M. Phthalocyanine-based Nanoporous Network Polymers[J]. Chem Commun,2002,23:2780-2781.
[4]	Liu X,Xu Y,Jiang D.Conjugated Microporous Polymers as Molecular Sensing Devices:Microporous Architecture Enables Rapid Response and Enhances Sensitivity in Fluorescence-On and Fluorescence-Off Sensing[J]. J Am Chem Soc,2012,134(21):8738-8741.
[5]	Cote A P,Benin A I,Ockwig N W,et al. Porous, Crystalline, Covalent Organic Frameworks[J]. Science,2005,310(5751):1166-1170.
[6]	Ben T,Ren H,Ma S,et al. Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area[J]. Angew Chem Int Ed,2009,121(50):9621-9624.
[7]	Han J,Fan X,Zhuang Z Z,et al. A Triphenylene-based Conjugated Microporous Polymer:Construction, Gas Adsorption, and Fluorescence Detection Properties[J]. RSC Adv,2015,5(20):15350-15353.
[8]	Song W C,Xu X K,Chen Q,et al. Nitrogen-rich Diaminotriazine-based Porous Organic Polymers for Small Gas Storage and Selective Uptake[J]. Polym Chem,2013,4(17):4690-4696.
[9]	Chang Z,Zhang D S,Chen Q,et al. Microporous Organic Polymers for Gas Storage and Separation Applications[J]. Phys Chem Chem Phys,2013,15(15):5430-5442
[10]	Dalapati S,Jin E,Addicoat M,et al. Highly Emissive Covalent Organic Frameworks[J]. J Am Chem Soc,2016,138(18):5797-5800.
[11]	Ding S Y,Dong M,Wang Y W,et al. Thioether-Based Fluorescent Covalent Organic Framework for Selective Detection and Facile Removal of Mercury(Ⅱ)[J]. J Am Chem Soc,2016,138(9):3031-3037.
[12]	Weng J Y,Xu Y L,Song W C,et al. Tuning the Adsorption and Fluorescence Properties of Aminal-Linked Porous Organic Polymers Through N-Heterocyclic Group Decoration[J]. J Polym Sci Polym Chem,2016,54(12):1724-1730.
[13]	Ding S Y,Gao J,Wang Q,et al. Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki-Miyaura Coupling Reaction[J]. J Am Chem Soc,2011,133(49):19816-19822.
[14]	Fang Q,Wang J,Gu S,et al. 3D Porous Crystalline Polyimide Covalent Organic Frameworks for Drug Delivery[J]. J Am Chem Soc,2015,137(26):8352-8355.
[15]	Tian D,Zhang H Z,Zhang D S,et al. Li-Ion Storage and Gas Adsorption Properties of Porous Polyimides(PIs)[J]. RSC Adv,2014,4(15):7506-7510.
[16]	Yang D H,Yao Z Q,Wu D H,et al. Structure-modulated Crystalline Covalent Organic Frameworks as High-rate Cathodes for Li-Ion Batteries[J]. J Mater Chem A,2016,4(47):18621-18627.
[17]	LIN Yijun,ZHU Yunlong,KUANG Guichao,et al. Application of Porous Organic Polymers in the Radioactive Iodine Adsorption[J]. Prog Chem,2017,29(7):766-775(in Chinese). 林益军,朱云龙,旷桂超,等. 用于放射性碘吸附的多孔有机聚合物[J]. 化学进展,2017,29(7):766-775.
[18]	CHEN Dongyang,LIU Cheng,WANG Jinyan,et al. Research Progress on the Electrochemical Application of Nanoporous Organic Polymers[J]. Acta Polym Sin,2018,5:559-570(in Chinese). 陈东洋,刘程,王锦艳,等. 纳米多孔有机聚合物电化学应用研究[J]. 高分子学报,2018,5:559-570.
[19]	Muhammad S,Mazen K N,Ihsanullaha,et al. Removal of Heavy Metals and Organic Pollutants from Water Using Dendritic Polymers Based Adsorbents:A Critical Review[J]. Sep Purif Technol,2018,191:400-423.
[20]	Li A,Sun H X,Tan D Z,et al. Superhydrophobic Conjugated Microporous Polymers for Separation and Adsorption[J]. Energy Environ Sci,2011,4(6):2062-2065.
[21]	Zhong M,Su P K,Lai J Y,et al. Organic Solvent-resistant and Thermally Stable Polymeric Microfiltration Membranes Based on Crosslinked Polybenzoxazine for Size-selective Particle Separation and Gravity-driven Separation on Oil-Water Emulsions[J]. J Membr Sci,2018,550:18-25.
[22]	Xue Y M,Dai P C,Jiang X F,et al. Template-free Synthesis of Boron Nitride Foam-like Porous Monoliths and Their High-end Applications in Water Purification[J]. J Mater Chem A,2016,4(4):1469-1478.
[23]	Wan X Z,Umair A,Wang Y K,et al. Highly Porous and Chemical Resistive P(TFEMA-DVB) Monolith with Tunable Morphology for Rapid Oil/Water Separation[J]. RSC Adv,2018,8(15):8355-8364.
[24]	Zhu H G,Yang S,Chen D Y,et al. A Robust Absorbent Material Based on Light-Responsive Superhydrophobic Melamine Sponge for Oil Recovery[J]. Adv Mater Interfaces,2016,3(5):1500683.
[25]	Xiao Z Y,Zhang M H,Fan W D,et al. Highly Efficient Oil/Water Separation and Trace Organic Contaminants Removal Based on Superhydrophobic Conjugated Microporous Polymer Coated Devices[J]. Chem Eng J,2017,326:640-646.
[26]	Yu L H,Hao G Z,Xiao L,et al. Robust Magnetic Polystyrene Foam for High Efficiency and Removal Oil from Water Surface[J]. Sep Purif Technol,2017,173:121-128.
[27]	Du R,Zhang N,Xu H,et al. CMP Aerogels: Ultrahigh-Surface-Area Carbon-Based Monolithic Materials with Superb Sorption Performance[J]. Adv Mater,2014,26(47):8053-8058.
[28]	Du R,Zheng Z,Mao N N,et al. Fluorosurfactants-Directed Preparation of Homogeneous and Hierarchical-Porosity CMP Aerogels for Gas Sorption and Oil Cleanup[J]. Adv Sci,2015,2(10):1570040.
[29]	Rao K V,Sudip M,Tapas K M,et al. Guest-Responsive Reversible Swelling and Enhanced Fluorescence in a Super-Absorbent, Dynamic Microporous Polymer[J]. Chem Eur J,2012,18(15):4505-4509
[30]	Ji W H,Su R H,Geng Y L,et al. Rapid, Low Temperature Synthesis of Molecularly Imprinted Covalent Organic Frameworks for the Highly Selective Extraction of Cyano Pyrethroids from Plant Samples[J]. Anal Chim Acta,2018,1001:179-188.
[31]	Lu Q Y,Ma Y C,Li H,et al. Postsynthetic Functionalization of Three-Dimensional Covalent Organic Frameworks for Selective Extraction of Lanthanide Ions[J]. Angew Chem Int Ed,2018,57(21):1-7.
[32]	Salonen L M,Pinela S R,Fernandes S P S,et al. Adsorption of Marine Phycotoxin Okadaic Acid on a Covalent Organic Framework[J]. J Chromatogr A,2017,1525:17-22.
[33]	Zheng C L,Du M M,Rong Y Z. Fast AdsorptIon of ErythromycIn on the Conjugated Microporous Polymers[J]. Adv Mater Res,2015,1073/1076:32-38.
[34]	Zheng C L,Du M M,Li F,et al. Selective Adsorption of Metronidazole on Conjugated Microporous Polymers[J]. Sci China Chem,2015,58(7):1227-1234.
[35]	Zheng C L,Feng S S,Wang Q R,et al. Adsorption Thermodynamics of Metronidazole on the Conjugated Microporous Polymers[J]. J Residuals Sci Technol,13(S1):101-105.
[36]	Wang Z H,Zhang P B,Hu F,et al. A Crosslinked β-Cyclodextrin Polymer Used for Rapid Removal of a Broadspectrum of Organic Micropollutants from Water[J]. Carbohydr Polym,2017,177:224-231.
[37]	Luo Q,Zhao C,Liu G,et al. A Porous AromaticFramework Constructed from Benzene Rings Has a High Adsorption Capacity for Perfluorooctane Sulfonate[J]. Sci Rep,2016,6:20311.
[38]	Hou Y X,Zhang X M,Wang C M,et al. Novel Imine-linked Porphyrin Covalent Organic Frameworks with Good Adsorption Removing Property of RhB[J]. New J Chem,2017,41(14):6145-6151.
[39]	Zhu X,An S H,Liu Y,et al. Efficient Removal of Organic Dye Pollutants Using Covalent Organic Frameworks[J]. AIChE J,2017,63(8):3470-3478.
[40]	Huang N,Wang P,Addicoat M A.Ionic Covalent Organic Frameworks:Design of a Charged Interface Aligned on 1D Channel Walls and Its Unusual Electrostatic Functions[J]. Angew Chem Int Ed,2017,56(18):4982-4986.
[41]	Yu S,Lyu H,Tian J,et al. A Polycationic Covalent Organic Framework:A Robust Adsorbent for Anionic Dye Pollutants[J]. Polym Chem,2016,7(20):3392-3397.
[42]	Li Z,Li H,Guan X.Three-Dimensional Ionic Covalent Organic Frameworks for Rapid, Reversible, and Selective Ion Exchange[J]. J Am Chem Soc,2017,139(49):17771-17774.
[43]	Bekir S,Budd P M.Selective Dye Adsorption by Chemically-modified and Thermally-treated Polymers of Intrinsic Microporosity[J]. J Colloid Interface Sci,2017,492:81-91.
[44]	Zhang H J,Wang J H,Zhang Y H,et al. Hollow Porous Organic Polymer:High-Performance Adsorption for Organic Dye in Aqueous Solution[J]. J Polym Sci Polym Chem,2017,55(8):1329-1337.
[45]	Wang J H,Zhang Y,An L C,et al. Sulfonated Hollow Covalent Organic Polymer:Highly-Selective Adsorption Toward Cationic Organic Dyes over Anionic Ones in Aqueous Solution[J]. Chinese J Chem,https://doi.org/10.1002/cjoc.201800142.
[46]	Ning G H,Chen Z,Gao Q,et al. Salicylideneanilines-Based Covalent Organic Frameworks as Chemoselective Molecular Sieves[J]. J Am Chem Soc,2017,139(26):8897-8904.
[47]	Wang B,Xie Z,Li Y,et al. Dual-Functional Conjugated Nanoporous Polymers for Efficient Organic Pollutants Treatment in Water:A Synergistic Strategy of Adsorption and Photocatalysis[J]. Macromolecules,2018,51(9):3443-3449.
[48]	He S J,Rong Q F,Niu H Y,et al. Construction of a Superior Visible-light-driven Photocatalyst Based on a C3N4 Active Centrephotoelectron Shift Platform-electron Withdrawing Unit Triadic Structure Covalent Organic Framework[J]. Chem Commun,2017,53(69):9636-9639.

Research and Application Progress on Porous Organic Polymers for Adsorption and Separation of Organic Pollutants in Water System

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