Luminescence Properties of Eu2+-activated CaO-MgO-SiO2 Long-lasting Phosphorescence Glasses

doi:10.11944/j.issn.1000-0518.2016.01.150169

Chinese Journal of Applied Chemistry ›› 2016, Vol. 33 ›› Issue (1): 63-69.DOI: 10.11944/j.issn.1000-0518.2016.01.150169

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Luminescence Properties of Eu²⁺-activated CaO-MgO-SiO₂ Long-lasting Phosphorescence Glasses

WANG Hongjie^a,MA Tengfei^a,ZHANG Su^b^*(),FENG Jing^b,PANG Ran^b,JIANG Lihong^b,LI Chengyu^b^*()

^aSchool of Materials Science and Engineering,Jilin Jianzhu University,Changchun,China 130118
^bState Key Laboratory of Rare Resource Utilization,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China

Received:2015-05-14 Accepted:2015-10-08 Published:2016-01-05 Online:2016-01-05
Contact: ZHANG Su,LI Chengyu
Supported by:
Supported by the National Natural Science Foundation of China(No.51102229, No.51402288, No.21401184), Program of Science and Technology Development Plan of Jilin Province(No.20140201007GX), the Education Department of Jilin Province “1025” Science and Technology Research Project(2014, 226th)

Abstract

Abstract:

In this article, a new Eu²⁺ ion activated silicate glass was prepared. The glass composition is 2CaO-MgO-3SiO₂-0.015Eu₂O₃(CMSE). The transmitted spectrum, steady-state photoluminescence(PL) spectrum, long-lasting phosphorescence(LLP) and thermal glow were performed to investigate the luminescent properties of the CMSE sample. It was found that the CMSE sample can be excited by ultraviolet(UV) and near UV light to give yellow PL emission and LLP. The emission origins from the d-f transition of Eu²⁺. The results of thermal glow curve indicate that the LLP is originated from the trap level with depth of 0.83 eV in the forbidden band of glass host. This study is beneficial for finding other rare earth ions activated luminescent glasses for white light LEDs.

Key words: Eu2+, long-lasting phosphorescence, glasses, luminescence

WANG Hongjie, MA Tengfei, ZHANG Su, FENG Jing, PANG Ran, JIANG Lihong, LI Chengyu. Luminescence Properties of Eu²⁺-activated CaO-MgO-SiO₂ Long-lasting Phosphorescence Glasses[J]. Chinese Journal of Applied Chemistry, 2016, 33(1): 63-69.

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Luminescence Properties of Eu²⁺-activated CaO-MgO-SiO₂ Long-lasting Phosphorescence Glasses

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