Dynamic Surface Tensions of Castor Oil Acid Methyl Ester Ethoxylate Aqueous Solutions

doi:10.11944/j.issn.1000-0518.2015.06.140305

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (6): 689-694.DOI: 10.11944/j.issn.1000-0518.2015.06.140305

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Dynamic Surface Tensions of Castor Oil Acid Methyl Ester Ethoxylate Aqueous Solutions

ZHANG Qian^a, SUN Yongqiang^{a, *}, ZHI Lifei^a, ZHANG Yong^a, SUN Jinyuan^a, WU Huaping^a, DI SERIO Martino^b

^aChina Research Institute of Daily Chemical Industry,Taiyuan 030001,China
^bDepartment of Chemical Sciences,University of Naples Federico Ⅱ,M. Napoli 80126,Italy

Received:2014-09-02 Accepted:2015-02-11 Published:2015-06-10 Online:2015-06-10
Contact: Yongqiang SUN
Supported by:
Supported by the National Science and Technology Support Project of International(No.2013DFA42120), International Science and Technology Cooperative Project of Shanxi Province(No.2013081019), Natural Science and Technology Support Project of China(No.2012BAD32B10)

Abstract

Abstract:

The dynamic surface tensions of different average ethylene oxide(EO) adduct number(10, 12, 14, 16, and 20) of ethoxylated castor oil acid methyl esters(ECAME) were measured by maximum bubble pressure method(MBP). The effect of dynamic surface tension at different concentration, temperature and the presence of inorganic electrolyte were investigated. The dynamic surface tension parameters(EO adduct number n, equilibrium time t^*, maximum slope of curve R_1/2) of different concentration were discussed. The results show that dynamic surface tension increases with the average n increasing from 10 to 20, n decreases from 3.02 to 1.05, t^* decreases from 14.45 to 2.29, and R_1/2 increases from 0.43 to 6.44, while the concentration of ECAME ranges from 0.5×10^-5 to 10×10^-5 mol/L. Therefore, the dynamic surface activity increases and the dynamic surface tension decreases. The dynamic surface tension decreases with the temperature increasing from 25 ℃ to 45 ℃. The initial adsorption dynamic surface tension increases with the increasing of inorganic electrolyte concentration and the late adsorption dynamic surface tension decreases with the increasing of inorganic electrolyte concentration. Comparing with conventional fatty acid methyl ester ethoxylate(FMEE), ECAME has an excellent dynamic surface activity. This indicates a new direction for the application of ECAME.

Key words: ethoxylated castor oil acid methyl esters, dynamic surface tension, concentration, temperature, inorganic electrolyte

CLC Number:

ZHANG Qian, SUN Yongqiang, ZHI Lifei, ZHANG Yong, SUN Jinyuan, WU Huaping, DI SERIO Martino. Dynamic Surface Tensions of Castor Oil Acid Methyl Ester Ethoxylate Aqueous Solutions[J]. Chinese Journal of Applied Chemistry, 2015, 32(6): 689-694.

References

[1]	Cox M F,Weerasooriya U. Methyl Ester Ethoxylates[J]. J Am Oil Chem Soc,1997,74(7):847-859.
[2]	Behler A,Syldath A. Fatty Acid Methy Ester Ethoxylates-a New Class of Nonionic Surfactants[A]. Comit Europ en des Agent de Surface et Leurs Interm duaures Organiques. Proceedings of 5th Word Surfactants Congress[C]. Champaign USA:AOCS Press,2000:382-391.
[3]	Hama I,Okamoto T,Nakamura H. Preparation and Properties of Ethoxylated Fatty Methyl Ester Nonionics[J]. J Am Oil Chem Soc,1995,72:781-784.
[4]	Hama I,Okamoto T,Hidai E,et al.Direct Ethoxylation of Fatty Methyl Ester over Al-Mg Composite Oxide Catalyst[J]. J Am Oil Chem Soc,1997,74:19-24.
[5]	Hama I,Sasamoto H,Okamoto T. Influence of Catalyst Structure on Direct Ethoxylation of Fatty Methyl Esters over Al-Mg Composite Oxide Catalyst[J]. J Am Oil Chem Soc,1997,74:817-822.
[6]	Hreczuch W. Comparison of the Kintics and Composition of Ethoxylated Methyl Dodecanoate and Ethoxylated Dodecanol with Narrow and Broad Distribution of Homologs[J]. J Surfact Deterg,1999,2:287-292.
[7]	Alejski K,Bialowas E,Hreczuch W,et al.Oxyethylation of Fatty Acid Methyl Esters. Molar Ratio and Temperature Effects. Pressure Drop Modeling[J]. Ind Eng Chem Res,2003,42:2924-2933.
[8]	Makowska D,Hreczuch W,Zimoch J,et al.Surface Activity of Mixtures of Oxyethylated Methyl Dodecanoate and Sodium Dodecylbenzenesulfonate[J]. J Surfact Deterg,2001,4:121-126.
[9]	SUN Yongqiang,ZHANG Gaoyong,LUO Yi,et al.The Applications of Fatty Acid Methyl Ester Ethoxylate Used in Laundry[J]. China Surfact Deterg Cosmet,2005,35(2):72-74(in Chinese). 孙永强,张高勇,罗毅,等. 脂肪酸甲酯乙氧基化物在洗衣粉中的应用[J]. 日用化学工业,2005,35(2):72-74.
[10]	Zhi L F,Li Q X,Li Y L,et al.Adsorption and Aggregation Properties of Novel Star-shaped Gluconamide-type Cationic Surfactants in Aqueous Solution[J]. Colloid Polym Sci,2014,292(5):1041-1050.
[11]	Gao Y Y,Yang X Q. Equilibrium and Dynamic Surface Properties of Sulfosuccinate Surfactants[J]. J Surfact Deterg,2014,17(6):1117-1123.
[12]	Nahringbauer I. Dynamic Surface Tension of Aqueous Polymer Solutions,I:Ethyl(hydroxyethyl) Cellulose(BERMOCOLL cst-103)[J]. J Colloid Interface Sci,1995,176:318-328.
[13]	Eastoe J,Dalton J S,Rogueda P G,et al.Dynamic Surface Tensions of Nonionic Surfactant Solutions[J]. J Colloid Interface Sci,1997,188:423-430.
[14]	Li G Z,Shen Q,Ma C S. Determination of the Optimum Composition of Middle-Phase Microemulsion Using the Orthogonal-test-design Method[J]. Disp Sci Technol,1999,20(1):559-565.
[15]	CHEN Zhengguo,PAN Shouwei,GAO Qing,et al.The Synthesis and Surace Properties of Different Molecular Weight Polyethylene Shrink Glycerol Phenyl Ether Sulfonate[J]. Chinese J Appl Chem,2007,24(7):810-816(in Chinese). 陈正国,潘守伟,高庆,等. 不同分子量的聚缩水甘油苯基醚磺酸钠的合成及表面性能[J]. 应用化学,2007,24(7):810-816.
[16]	Zhi L F,Li Q X,Li Y L,et al.Adsorption and Aggregation Properties of Novel Star-shaped Gluconamide-type Cationic Surfactants in Aqueous Solution[J]. Colloid Polym Sci,2014,292:1041-1050.
[17]	Rosen M J, Song L D. Dynamic Surface Tension of Aqueous Surfactant Solutions[J]. J Colloid Interface Sci,1996,179:261-268.
[18]	CHEN Zhengguo,WANG Haiping,PAN Shouwei. The Preparation and Dynamic Surface Tension of a Polyether Sulfonate Surfactant[J]. Chinese J Appl Chem,2007,24(2):168-172(in Chinese). 陈正国,汪海平,潘守伟. 一种磺酸聚醚型表面活性剂的制备及动态表面张力[J]. 应用化学,2007,24(2):168-172.
[19]	Popyoshev S U,Pugh R J. Aqueous Solutions of Ethyl(Hydroxyethyl) Cellusose and Hydrophobic Modified Ethyl(Hydroxyethyl) Cellulose Polymer:Dynamic Surface Tension Measurments[J]. J Colloid Interface Sci,1997,193:41-49.
[20]	CHAI Jinling,XU Jun,LI Ganzuo,et al.The Surface Adsorption Equilibrium and Kinetics of Alkyl Poly Glucoside Solution[J]. Chem J Chinese Univ,2002,23(10):1915-1920(in Chinese). 柴金玲,徐军,李干佐,等. 烷基聚葡萄糖苷溶液的表面吸附平衡与动力学[J]. 高等学校化学学报,2002,23(10):1915-1920.

Dynamic Surface Tensions of Castor Oil Acid Methyl Ester Ethoxylate Aqueous Solutions

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