Preparation of Carbon-Coated TiO2-CeO2 Fibers for the Photocatalytic Degradation of Ciprofloxacin

doi:10.3724/SP.J.1095.2013.30019

Chinese Journal of Applied Chemistry

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Preparation of Carbon-Coated TiO₂-CeO₂ Fibers for the Photocatalytic Degradation of Ciprofloxacin

ZHENG Xi^*, CHEN Siying, CHEN Zhen, CHEN Riyao, CHEN Xiao

(College of Environmental Science and Engineering，Fujian Normal University，Fuzhou 350007，China)

Received:2013-01-08 Revised:2013-03-15 Published:2013-11-10 Online:2013-11-10
Contact: Zheng Xi

Abstract

Abstract: The CeO2-TiO2 sol-gel was prepared by the sol-gel method using polyvinylpyrrolidone(PVP) sol/titaniumn-butyloxide(Ti(OC4H9)4) as the precursor and Ce(NO3)3·6H2O as the doping agent, and the CeO2-doped TiO2 nanofiber was prepared by the electrospinning technique. Finally, a layer of carbon membrane was deposited on the surface of the CeO2-TiO2 composite nanofibers using chemical vapor deposition(CVD). The structure and properties of the carbon-coated nanofibers were studied using SEM, FTIR, TEM, XRD, and its photocatalytic activity toward the degradation of ciprofloxacin hydrochloride was investigated under UV-light irradiation. The experimental results show that carbon-coated TiO2 composite nanofibers exhibit higher photocatalytic performance. When the irradiation time is 40 min, the degradation rate of ciprofloxacin hydrochloride is up to 85.8%.

Key words: electrospinning, TiO2, CeO2, carbon-coated, photocatalysis

CLC Number:

O643

ZHENG Xi*, CHEN Siying, CHEN Zhen, CHEN Riyao, CHEN Xiao. Preparation of Carbon-Coated TiO₂-CeO₂ Fibers for the Photocatalytic Degradation of Ciprofloxacin[J]. Chinese Journal of Applied Chemistry, DOI: 10.3724/SP.J.1095.2013.30019.

References

[1] Li D,Xia Y. Electrospinning of Nanofibers:Reinventing the Wheel?[J]. Adv Mater,2004,16(14):1151-1170.

[2] Zhang C,Wu F B,Zhang Y Y,et al. A Novel Combination of Immunoreaction and ICP-MS as a Hyphenated Technique for the Determination of Thyroid-Stimulating Hormone(TSH) in Human Serum[J]. J Anal At Spectrom,2001,16:1393-1396.

[3] Wang X,Li Y D. Selected-Control Hydrothermal Synthesis of α- and β-MnO2 Single Crystal Nanowires[J]. J Am Chem Soc,2002,124(12):2880-2881.

[4] Wu Y Y,Fan R,Yang P D. Block-by-Block Growth of Single-Crystalline Si/SiGe Superlattice Nanowires[J]. Nano Lett,2002,2(2):83-86.

[5] Gudiksen M S,Lauhon L J,Wang J,et al. Growth of Nanowire Superlattice Structures for Nanoscale Photonics and Electronics[J]. Nature,2002,415(7):617-620.

[6] CHEN Yingsheng,CHEN Zhen,CHEN Riyao,et al. Preparation and Photocatalytic Properties of NiO-TiO2 Coaxial Nanofibers[J]. Acta Mater Compos Sin,2011,28(2):36-41(in Chinese).

陈影声,陈震,陈日耀,等. NiO-TiO2同轴纳米纤维的制备及光催化[J]. 复合材料学报,2011,28(2):36-41.

[7] Chang G Q,Zheng X,Chen R Y,et al. Sliver Nanoparticles Filling in TiO2 Hollow Nanofibers by Coaxial Electrospinning[J]. Acta Phys-Chim Sin,2008,24(100):1790-1796.

[8] CHEN Yingsheng,CHEN Zhen,LU Caiying,et al. TiO2 Nanoparticles Loaded on Carbon Nanofibers[J]. Chinese J Appl Chem,2010,27(10):1188-1191(in Chinese).

陈影声,陈震,卢才英,等. 纳米碳纤维固载TiO2[J]. 应用化学,2010,27(10):1188-1191.

[9] Lindberg R H,Wennberg P,Johansson M I,et al. Screening of Human Antibiotic Substances and Determination of Weekly Mass Flows in Five Sewage Treatment Plants in Sweden[J]. Environ Sci Technol,2005,39(10):3421-3429.

[10] CHEN Zhangliu,YANG Guixiang,SUN Yongxue,et al. Advance of Toxicities and Ecotoxicology of Veterinary Drug Residues[J]. J South China Univ Trop Agric,2001,22(1):88-91(in Chinese).

陈杖榴,杨桂香,孙永学. 兽药残留的毒性与生态毒理研究进展[J]. 华南农业大学学报,2001,22(1):88-91.

[11] Sorensen B H,Nielsen S N,Lanzky P F,et al. Occurrence, Fate and Effects of Pharmaceutical Substances in the Environment-A Review[J]. Chemosphere,1998,36(2):357-393.

[12] Ying G G,Kookana R S,Ru Y J. Occurrence and Fate of Hormone Steroids in the Environment[J]. Environ Int,2002,28(6):545-551.

[13] Warman P R. The Effect of Amprolium and Aureomycin on the Nitrification of Poultry Manure-Amended Soil[J]. Soil Sci Soc Am J,1980,44(6):1333-1334.

[14] Dijck P V,Van H. Sensitivity of Environmental Microorganisms to Antimicrobial Agents[J]. Appl Environ Microbiol,1976,31(3):332-336.

[15] Jacobsen A M,Halling-Sorensen B,Ingerslev F. Simultaneous Extraction of Tetracycline, Macrolide and Sulfonamide Antibiotics from Agricultural Soils Using Pressurised Liquid Extraction, Followed by Solid-Phase Extraction and Liquid Chromatography-Tandem Mass Spectrometry[J]. J Chromatography A,2004,1038(1/2):157-170.

[16] Yang S,Carlson K. Routine Monitoring of Antibiotics in Water and Wastewater with a Radioimmunoassay Technique[J]. Water Res,2004,38(14/15):3155-3166.

[17] Elmolla E S,Chaudhuri M. Degradation of Amoxicillin, Ampicillin and Cloxacillin Antibiotics in Aqueous Solution by the UV/ZnO Photocatalytic Process[J]. J Hazard Mater,2010,173(1/3):445-449.

[18] Matthews R W. Photooxidation of Organic Impurities in Water Using Thin Films of Titanium Dioxide[J]. J Phys Chem,1987,91(12):3328-3333.

[19] GE Linke,CHEN Jingwen,ZHANG Siyu,et al. Photodegration of Fluoroquinolone Antibiotic Gatifloxacin in Aqueous Solutions[J]. Chinese Sci Bull,2010,55(15):1495-1500(in Chinese).

葛林科,陈景文,张思玉,等. 水中氟喹诺酮类抗生素加替沙星的光降解[J]. 科学通报,2010,55(11):996-1001.

[20] Herrmann J W,Disdier J,Pichat P,et al. TiO2-Based Solar Photocatalytic Detoxification of Water Containing Organic Pollutants:Case Studies of 2,4-Dichlorophenoxyaceticacid(2,4-D) and of Benzofuran[J]. Appl Catal B,1998,17(1/2):15-23.

[21] LIN Huiliang,ZHOU Guowei,MENG Qinghai. Progress of Preparation of Ordered Mesoporous TiO2-SiO2 and Its Application in Papermaking[J]. Trans China Pulp Paper,2006,21(1):99-102(in Chinese).

林会亮,周国伟,孟庆海. 有序介孔TiO2-SiO2复合材料的制备及在造纸上的应用研究进展[J]. 中国造纸学报,2006,21(1):99-102.

[22] LI Wei,LIU Lifen,YANG Fenglin,et al. Preparation of N Doped TiO2 by Using ACF as Template and Its Photocatalytic Application in Removing Nitrogen from Water[J]. Photogr Sci Photochem,2005,23(5):374-381(in Chinese).

李威,柳丽芬,杨凤林,等. 以ACF为模板制备掺氮TiO2及其光催化脱氨氮研究[J]. 感光科学与光化学,2005,23(5):374-381.

[23] Hu Y,Rakhmawaty D,Matsuoka M,et al. Synthesis,Characterization and Photocatalytic Reactivity of Ti-Containing Micro- and Mesoporous Materials[J]. J Porous Mater,2006,13(3/4):335-340.

[24] Machida M,Norimoto K,Watanabe T,et al. The Effect of SiO2 Addition in Super-Hydrophilic Property of TiO2 Photocatalyst[J]. J Mater Sci,1999,34(11):2569-2574.

[25] ZHAO Binxia,ZHANG Xiaoli,LI Hongya,et al. Catalytic Activities of MnOx-CeO2 Catalysts in Wet Air Oxidation of Pesticide Wastewater[J]. Chem J Chinese Univ,2009,30(5):965-970(in Chinese).

赵彬侠,张小里,李红亚,等. 湿式氧化吡虫啉农药生产废水的MnOx-CeO2催化剂性能研究[J]. 高等学校化学学报,2009,30(5):965-970.

[26] Liu B S,Zhao X J,Zhang N Z,et al. Photocatalytic Mechanism of TiO2-CeO2 Films Prepared by Magnetron Sputtering Under UV and Visible Light[J]. Surf Sci,2005,595(1/3):203-211.

[27] Yang H M,Zhang K,Shi R R,et al. Sol-Gel Synthesis and Photocatalytic Activity of CeO2/TiO2 Nanocomposites[J]. J Am Ceram Soc,2007,90(5):1370-1374.

[28] Matos J,Laine J,Herrmann J M,et al. Influence of Activated Carbon Upon Titania on Aqueous Photocatalytic Consecutive Runs of Phenol Photodegradation[J]. Appl Catal B,2007,70(1/4):461-469.

[29] Nakajima A,Horie K,Hara M,et al. Preparation of Solid Acid Carbon Coating on the Surface of TiO2 by Photo-CVD of Gaseous Aromatic Hydrocarbons[J]. Catal Commun,2009,10(13):1670-1673.

[30] Matos J,Laine J,Herrmann J M,et al. Influence of Activated Carbon Upon Titaniaon Aqueons Photocatalytic Consecutive Runs in Phenol Photodegradation[J]. Appl Catal B,2007,70(1/4):461-469.

[31] TANG Weizhong. Principle of Film Materials, Technologies and Applications[M]. Beijing:Metallurgical Industry Press,2005:73(in Chinese).

唐伟忠. 薄膜材料制备原理、技术及应用[M]. 北京:冶金工业出版社,2005:73.

[32] LI Congju,ZHAI Guojun,FU Zhongyu,et al. Fabrication and Photocatalytic Property of TiO2 Nanofibers[J]. Chinese J Inorg Chem,2006,22(11):2061-2064(in Chinese).

李从举,翟国钧,付中玉,等. TiO2纳米纤维无纺布的制备及光催化性能研究[J]. 无机化学学报,2006,22(11):2061-2064.

[33] DONG Guoli,WANG Jianguo,GAO Yinben,et al. Preparation and Characterization of CeO2-TiO2 Mixed Oxides[J]. J Inorg Mater,1999,14(6):873-880(in Chinese).

董国利,王建国,高荫本,等. CeO2-TiO2复合氧化物的制备及其表征[J]. 无机材料学报,1999,14(6):873-880.

[34] Music S,Gotic M,Lvanda M,et al. Chemical and Microstructural Properties of TiO2 Synthesized by Sol-Gel Procedure[J]. Mater Sci Eng B,1997,47(1):33-40.

[35] Bickley R I,Gonzalez-carreno T ,Lees J S,et al. A Structural Investigation of Titanium Dioxide Photocatalysts[J]. J Solid State Chem,1991,92(1):178-190.

[36] XU Kaqiu,GAO Xiahong. Surface Organic Modification of TiO2 Pigment[J]. Chem Ind Eng Prog,2003,22(11):1200-1202(in Chinese).

徐卡秋,高夏红. 二氧化钛颜料的表面有机改性研究[J]. 化工进展,2003,22(11):1200-1202.

[37] Zhang L W,Fu H B,Zhu Y F. Efficient TiO2 Photocatalysts from Surface Hybridization TiO2 Particles with Graphite-like Carbon[J]. Adv Funct Mater,2008,18:2180-2189.

Preparation of Carbon-Coated TiO₂-CeO₂ Fibers for the Photocatalytic Degradation of Ciprofloxacin

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