Chinese Journal of Applied Chemistry ›› 1998, Vol. 0 ›› Issue (3): 116-117.

• Full Papers • Previous Articles    

Synthesis of 1,1-Dimethyl-3-butenyl Cyclopenta-dienyl Lanthanide Chloride Complexes

Lin Jin, Zhang Ping, Wang Zhaoyu   

  1. Department of Chemistry, Hebei Normal University, Shijiazhuang 050016
  • Received:1997-08-06 Revised:1997-12-05 Published:1998-06-10 Online:1998-06-10

Abstract: Five title complexes were synthesized. The characterization results obtained from elemental analysis, MS, 1H NMR and thermogravimetric analysis revealed that the complexes have a general formula [C5H4C(CH3) 2CH2CH=CH2]·LnCl2·MgCl2·THF, where Ln=La, Nd, Sm, Gd and Lu.

Key words: vinyl cyclopentadienyl, lanthanide dichloride, complex, synthesis