Oxidative Carbonylation of Aniline by Pd/C Catalyst

Chinese Journal of Applied Chemistry ›› 1997, Vol. 0 ›› Issue (4): 41-45.

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Oxidative Carbonylation of Aniline by Pd/C Catalyst

Xu Pianpian¹, Zhang Fanxian¹, Wang Wenfeng², Pen Yiru³

1. Department of Chemistry, State Key Laboratory of Physical Chemistry of Solid Surface, Institute of Physical Chemistry, Xiamen University, Xiamen 361005;
2. Department of Chemistry, Fuzhou University, Fuzhou;
3. Department of Chemistry , Fujian Normal University, Fuzhou

Received:1996-12-31 Revised:1997-05-05 Published:1997-08-10 Online:1997-08-10

Abstract

Abstract: The effects of the preparation conditions of Pd/C catalyst and the promoters on the catalytic property have been investigated. The influences of partial oxygen pressure and addition of nitrobenzene on the oxidative carbonylation of aniline to ethyl N-phenyl carbamate also have been tested. The Pd/C catalyst was characterized by XPS, TPR and in situ IR techniques. A possible mechanism of the oxidative carbonylation of aniline catalyzed by Pd/C NaI system in alcohol medium has been proposed.

Key words: aniline, oxidative carbonylation, ethyl N-phenyl carbamate, palladium

Xu Pianpian, Zhang Fanxian, Wang Wenfeng, Pen Yiru. Oxidative Carbonylation of Aniline by Pd/C Catalyst[J]. Chinese Journal of Applied Chemistry, 1997, 0(4): 41-45.

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Oxidative Carbonylation of Aniline by Pd/C Catalyst

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