Chinese Journal of Applied Chemistry ›› 1996, Vol. 0 ›› Issue (6): 72-74.

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Preparation,Structure and Catalytic Property of Cobalt Chromium Mixed Oxide Ultrafine Particle

Liu Changkun, Shen Yongcun, Xi Qiang   

  1. Department of Fine Chemistry, Wuhan Institute of Chemical Technology, Wuhan 430073
  • Received:1996-02-16 Revised:1996-07-02 Published:1996-12-10 Online:1996-12-10

Abstract: Cobalt chromium mixed oxide ultrafine particle catalysts were prepared by coprecipitation and sol-gel methods. The catalytic properties of catalysts for catalytic oxidation of 2,3,6-trimethylphenol to trimethyl-p-benzoquinone were investigated.It is shown that the catalyst with Co/Cr=1 prepared by sol-gel method is the best.The structures of catalysts were characterized by TEM,XRD and DTA-TG.The mixed oxide is amorphous under 350℃.The thermal stability of this amorphous catalyst is higher than that of Co3O4 and Cr2O3.

Key words: cobalt chromium mixed oxide, ultrafine particle, catalyst, preparation, structure, catalytic oxidation, trimethylphenol, trimethyl-p-benzoquinone