Synthesis and Characterization of 5,12-diphenyl-7,14-dimethyl-1,4,8,11-tetraazacyclotetradecane-N-acetic Acid and Its Cu(Ⅱ)、Ni(Ⅱ) Complexes

Chinese Journal of Applied Chemistry ›› 1996, Vol. 0 ›› Issue (4): 104-106.

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Synthesis and Characterization of 5,12-diphenyl-7,14-dimethyl-1,4,8,11-tetraazacyclotetradecane-N-acetic Acid and Its Cu(Ⅱ)、Ni(Ⅱ) Complexes

Zhang Youjin¹, He Qun¹, Xie Fuxin², Xu Zhiqiang², Ni Shisheng²

1. Department of Processing and Technology, Hefei Institute of Economics and Technology, Hefei 230052;
2. Department of Chemistry, Anhui University, Hefei

Received:1995-11-26 Revised:1996-04-08 Published:1996-08-10 Online:1996-08-10

Abstract

Abstract: A novel 14 membered N-acetic acid substituted tetraazamacrocyclic ligand, 5,12-diphenyl-7,14-dimethyl-l,4,8,11-tetraazacyclotetradecane-N-acetic acid (HL ) has been synthesized in dry methanol by the interaction of 5,12-diphenyl-7,14-dimethyl-1,4,8,11-tetraazacyclotetradecane with bromoacetic acid. Its Cu (Ⅱ) and Ni(Ⅱ) complexes have also been prepared. The ligand and the complexes have been characterized by elemental analysis.IR,¹H NMR,MS,UV-Vis spectra and conductivity measurements.

Key words: tetraazacyclotetradecane-N-acetic acid, complex, synthesis, characterization

Zhang Youjin, He Qun, Xie Fuxin, Xu Zhiqiang, Ni Shisheng. Synthesis and Characterization of 5,12-diphenyl-7,14-dimethyl-1,4,8,11-tetraazacyclotetradecane-N-acetic Acid and Its Cu(Ⅱ)、Ni(Ⅱ) Complexes[J]. Chinese Journal of Applied Chemistry, 1996, 0(4): 104-106.

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Synthesis and Characterization of 5,12-diphenyl-7,14-dimethyl-1,4,8,11-tetraazacyclotetradecane-N-acetic Acid and Its Cu(Ⅱ)、Ni(Ⅱ) Complexes

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