Water-Soluble and Amphiphilic Polymers 18. Amphiphilic Monomers of 2-Acrylamidoalkanesulfonic Acids

Chinese Journal of Applied Chemistry ›› 1996, Vol. 0 ›› Issue (1): 1-5.

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Water-Soluble and Amphiphilic Polymers 18. Amphiphilic Monomers of 2-Acrylamidoalkanesulfonic Acids

Zhang Congyun¹, Fang Tianru¹, Qiu Lingwei¹, Wang Fusong¹, Liu Peiyan²

1. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022;
2. Department of Chemistry, The Northeast Normal University, Changchun

Received:1995-06-07 Revised:1995-08-24 Published:1996-02-10 Online:1996-02-10

Abstract

Abstract: The solubility and colloidal properties of 2-acrylamidoalkanesulfonic acids were found to vary markedly with the alkyl length.Due to the existence of a chiral carbon,the peaks of methylene protons adjacent to it clearly split on the ¹H NMR spectra.The polymerization kinetics and colloidal properties of 2-acrylamidohexadecane sulfonic acid in water/dioxane mixed solvents were investigated.It is found that both the polymerization rate and the relative molecular mass of the resultant polymer have a minimum value when water/dioxane volume ratio is in the range of 1～1/2.The critical micelle concentration increases with the content of dioxane in the mixed solvent, and no apparent micelle formation is observed when water/dioxane volume ratio is 1/2～1/4.

Key words: amphiphilic monomer, acrylamidoalkanesulfonic acid, solubility, critical micelle concentration, NMR, polymerization characteristics

Zhang Congyun, Fang Tianru, Qiu Lingwei, Wang Fusong, Liu Peiyan. Water-Soluble and Amphiphilic Polymers 18. Amphiphilic Monomers of 2-Acrylamidoalkanesulfonic Acids[J]. Chinese Journal of Applied Chemistry, 1996, 0(1): 1-5.

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Water-Soluble and Amphiphilic Polymers 18. Amphiphilic Monomers of 2-Acrylamidoalkanesulfonic Acids

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