Synthesis of Solid Complexes of Disubstituted Benzo Crown Ethers with Transition Metals

Chinese Journal of Applied Chemistry ›› 1994, Vol. 0 ›› Issue (2): 35-39.

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Synthesis of Solid Complexes of Disubstituted Benzo Crown Ethers with Transition Metals

Lu Airu¹, Zhang Youming¹, Zhang Lianxiang¹, Dai Yujie²

1. Department of Chemistry, Northwest Normal University, Lanzhou 730070;
2. Department of Pharmacy, Hebei Medical Institute, Shijiazhuang

Received:1993-06-26 Revised:1993-12-03 Published:1994-04-10 Online:1994-04-10

Abstract

Abstract: Ninefeen solid complexes of4',5'-diiodobenzo-15-crown-5,4',5'-dibromobenzo-15-crown-5,4'-bromo-5'-nitrobenzo-15-crown-5,and tetrabromodibenzo-18-crown-6 with nitrates,perchlorates,chlorides of Mn(Ⅱ),Co(Ⅱ),Cu(Ⅱ),Zn(Ⅱ),Ag(Ⅰ),and Cd(Ⅱ) have been synthesized Their compositions and properties have been characterized by elemental analysis, thermal analysis, IR spectra,X-ray diffraction analysis and molar conductance measurements.

Key words: transition metal, disubstituted benzo crown ether, solid complex, synthesis, property

Lu Airu, Zhang Youming, Zhang Lianxiang, Dai Yujie. Synthesis of Solid Complexes of Disubstituted Benzo Crown Ethers with Transition Metals[J]. Chinese Journal of Applied Chemistry, 1994, 0(2): 35-39.

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Synthesis of Solid Complexes of Disubstituted Benzo Crown Ethers with Transition Metals

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