Synthesis of Phenylenediacyl bis-PMPS and Their Extration Behavior to U(Ⅵ)

Chinese Journal of Applied Chemistry ›› 1994, Vol. 0 ›› Issue (2): 23-26.

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Synthesis of Phenylenediacyl bis-PMPS and Their Extration Behavior to U(Ⅵ)

Dong Xuechang¹, Zhang Shugui²

1. Department of Chemistry, Yunnan Institute of Nationalities, Kunming 650031;
2. Experimental Center, Yunnan University, Kunming

Received:1993-02-23 Revised:1993-06-22 Published:1994-04-10 Online:1994-04-10

Abstract

Abstract: Three new chelating agents of phenylenediacyl bis 1-phenyl-3-methylpyrazol-5-one (PMP) end groups have been synthesized. Their structures have been characterized by elemental analysis,UV,IR,¹H NMR and MS spectra. The extraction of U(Ⅵ) with these compounds have been studied.The values of the pH_1/2, logK_ex and chemical composition of the complexes have been obtained by the slope analysis method.

Key words: phenylmethylpyrazolone, phenylenediacyl compound, chelating agent, synthesis, extraction, U( Ⅵ)

Dong Xuechang, Zhang Shugui. Synthesis of Phenylenediacyl bis-PMPS and Their Extration Behavior to U(Ⅵ)[J]. Chinese Journal of Applied Chemistry, 1994, 0(2): 23-26.

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Synthesis of Phenylenediacyl bis-PMPS and Their Extration Behavior to U(Ⅵ)

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