Chinese Journal of Applied Chemistry ›› 1993, Vol. 0 ›› Issue (2): 73-74.

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AN ONE-POT SYNTHESIS OF 1-TRIMETHYLSILOXY ALLYLPHOSPHONATES

Li Zhonghua, Zhu Chuanfang, ZhaoYongzhen   

  1. Department of Chemistry, Central China Normal University, 430070 Wuhan
  • Received:1992-03-11 Revised:1992-05-04 Published:1993-04-10 Online:1993-04-10

Abstract: 1-Trimethylsiloxy allylphosphonates (3a-f) were synthesized by reacting phosphites (1), α, β-unsaturated aldehydes (2) and trimethylchlorosilane in one pot. The synthesis was carried out under a very mild conditions and was easy to operate. The structures of the phesphonates obtained were confirmed by IR, 1H, 31P NMR and MS.

Key words: phosphite, phosphonate, synthesis