TRANSPORT OF Ag (Ⅰ)THROUGH LIQUID MEMBRANE CONTAINING AN OLIGOMER OF EPITHIOPROPYL BUTYL ETHER

Chinese Journal of Applied Chemistry ›› 1993, Vol. 0 ›› Issue (2): 13-16.

• Full Papers • Previous Articles Next Articles

TRANSPORT OF Ag (Ⅰ)THROUGH LIQUID MEMBRANE CONTAINING AN OLIGOMER OF EPITHIOPROPYL BUTYL ETHER

Xu Yuwu, Wang Ying, Dong Shihua

Department of Chemistry, Wuhan University, 430072 Wuhan

Received:1992-02-28 Revised:1992-07-28 Published:1993-04-10 Online:1993-04-10

Abstract

Abstract: The oligomer of epithiopropyl butyl ether (PSB) with M_n=1600 was synthesized and its transport properties as a mobile carrier for Ag (Ⅰ) in bulk liquid membrane system were studied. It was found that the presence of the oligomer carrier in liquid membrane is necessary for transport of Ag (Ⅱ) and the transportion rate of Ag (Ⅰ) is dependent on the carrier concentration in liquid membrane, the thickness of liquid membrane,the acidity and the concentration of Ag(Ⅰ) in source phase and the additives in receiving phase. In the system AgNO₃ (aq)/PSB-ClCH₂CH₂Cl/NH₃·H₂O(aq),Ag(Ⅰ) can be transported from source phase to receiving phase completely under the appropriate conditions and only the Ag(Ⅰ) can be transported to receiving phase selectively from Ag(Ⅰ)-K(Ⅰ)-Cu (Ⅱ)-Zn (Ⅱ) mixtrue. The carrier can be used repeatedly without marked lose of its activity and selectivity.

Key words: liquid membrane separation, silver, oligomer, epithiopropy1 buty1 ether

Xu Yuwu, Wang Ying, Dong Shihua. TRANSPORT OF Ag (Ⅰ)THROUGH LIQUID MEMBRANE CONTAINING AN OLIGOMER OF EPITHIOPROPYL BUTYL ETHER[J]. Chinese Journal of Applied Chemistry, 1993, 0(2): 13-16.

[1]	Zhi-Peng DU, Yang ZHOU, San-Gen ZHAO. Synthesis， Crystal Structure and Birefringence Properties of Silver Cluster Compound Ag₃B₆O₁₀I [J]. Chinese Journal of Applied Chemistry, 2023, 40(2): 229-235.
[2]	Feng LI, Shi-Yu LU, Yu ZHANG, Li-Jun GUO, Xue ZHAI, Cui-Qin LI. Catalytic Properties of Silylated⁃Salicylaldimine Transition Metal Complexes Functionalized Nano⁃silica Catalysts in Ethylene Oligomerization [J]. Chinese Journal of Applied Chemistry, 2022, 39(6): 949-959.
[3]	Jing TANG, Na ZHANG, Dong-Xu SHI, Fang-Hui ZHANG, Jian-Jie TANG. Synthesis of UiO-66-NH₂Grafted Pyridineimine Cobalt Catalyst and Its Catalytic Performance in Ethylene Oligomerization [J]. Chinese Journal of Applied Chemistry, 2022, 39(02): 258-265.
[4]	WEI Xue-Ying, WU Wei, NAI Yong-Ning, JIANG Meng-Yuan, TIAN Shi-Wei, MAO Guo-Liang. Research Progress on the Selective Oligomerization of Ethylene Catalyzed by Phosphoramine Chromium and Diphosphinoamine Chromium [J]. Chinese Journal of Applied Chemistry, 2021, 38(2): 136-156.
[5]	GUO Yong-Yan, TIAN Yan-Fei, DANG Ming-Ming, YANG Ping, LONG Yun-Fei. Preparation of Thiourea Coordinated Chromium Black T Stabilized Silver Nanoclusters under Alkaline Environment [J]. Chinese Journal of Applied Chemistry, 2021, 38(2): 195-201.
[6]	GUO Shao-Bo, LIANG Yan-Li, LIU Zhi-Feng, ZHANG Qiang, MA Jian-Qi. Synergistic Antibacterial Activity of Tetracycline Combined with Silver Nanoparticles [J]. Chinese Journal of Applied Chemistry, 2021, 38(11): 1462-1468.
[7]	XING Yayan, SHI Yuzhe, DENG Shixian, ZHAO Baihan, LIU Zhiguo. Preparation and Application of Catechin-Silver Nanocomposites [J]. Chinese Journal of Applied Chemistry, 2020, 37(9): 1062-1068.
[8]	GAO Siheng, YANG Yu, WU Jinling, QIN Lixia, KANG Shizhao, LI Xiangqing. Preparation and Photoelectric Performance of Graphene Oxide/Ultrafine Silver Composite [J]. Chinese Journal of Applied Chemistry, 2020, 37(8): 923-929.
[9]	CAI Zhifeng, CHEN Siying, PANG Shulin, SONG Shuang, JIA Kang, MAO Yujin, TIAN Fang, ZHANG Caifeng. Synthesis of 2-Mercaptobenzimidazole-Functionalized Water-Soluble Copper Nanoclusters and Their Application to the Determination of Ag⁺ [J]. Chinese Journal of Applied Chemistry, 2020, 37(5): 587-594.
[10]	GUO Yongyan, ZENG Weiwei, YANG Ping, TIAN Yanfei, LONG Yunfei. Synthesis of Silver Nanoclusters Stabilized by pH-Regulated Chromotropic Acid 2R [J]. Chinese Journal of Applied Chemistry, 2020, 37(1): 54-60.
[11]	WANG Jun,LIU Jinyi,CHEN Liduo,LAN Tianyu,WANG Libo. Synthesis and Ethylene Oligomerization Behavior of Hyperbranched Bispyridineimine Chromium Catalyst [J]. Chinese Journal of Applied Chemistry, 2019, 36(7): 773-781.
[12]	CHEN Fan, GUO Zhiqian, ZHU Weihong. Synthesis and Characterization of pH and Temperature Sensitive Polymeric Fluorescent Probe [J]. Chinese Journal of Applied Chemistry, 2018, 35(4): 401-409.
[13]	Xiaoqin ZHANG, Jiang WU, Jiantai WANG, Chi YAN, Yingying FU, Zhiyuan XIE. Silver Nanowire Composite Transparent Electrode Based Flexible Polymer Solar Cells [J]. Chinese Journal of Applied Chemistry, 2018, 35(1): 109-115.
[14]	SHI Yun, LI Mengsheng, WEI Xiaolin. Synthesis of N,N-Isoquinoline Dipoles via Intramolecular Cyclization of o-Alkynylbenzaldehyde Hydrazones [J]. Chinese Journal of Applied Chemistry, 2017, 34(7): 795-800.
[15]	MENG Xianwen, SONG Xiao, LIU Suqin, LIANG Ying. Synthesis of Silver Vanadium Tetraoxide/Graphene Oxide Composite and Its Visible-light Photocatalytic Performance [J]. Chinese Journal of Applied Chemistry, 2016, 33(12): 1441-1447.

TRANSPORT OF Ag (Ⅰ)THROUGH LIQUID MEMBRANE CONTAINING AN OLIGOMER OF EPITHIOPROPYL BUTYL ETHER

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments