STUDIES ON IRON FAMILY ELEMENTS COORDINATION COMPOUNDS WITH CROWN ETHERS Ⅹ.COMPLEXES OF COBALT CHLORIDE AND COBALT NITRATE WITH CROWN ETHERS

Chinese Journal of Applied Chemistry ›› 1992, Vol. 0 ›› Issue (4): 52-57.

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STUDIES ON IRON FAMILY ELEMENTS COORDINATION COMPOUNDS WITH CROWN ETHERS Ⅹ.COMPLEXES OF COBALT CHLORIDE AND COBALT NITRATE WITH CROWN ETHERS

Zhang Youming, Lu Airu, Song Yumin, Zhang Lianxiang

Department of Chemistry, Northwestern Normal University, Lanzhou 730070

Received:1991-10-10 Revised:1992-03-02 Published:1992-08-10 Online:1992-08-10

Abstract

Abstract: This paper reports the syntheses and properties of the coordination compounds of CoCl₂ with dibenzo-24-crown-8, dibcnzo-30-crown-10, 4'-iodobcnzo-15-crown-5 and 4'-bromobenzo-15-crown and the coordination compounds of Co(NO₃)₂ with benzo-15-crown-5,4'-iodobenzo-15-crown-5 and 4'-bromobcnzo-15-crown-5. The complexes have been characterized by elemental analysis, IR, UV, DTA-TG and X-ray powder diffraction analysis as well as the molar conductance measurements.

Key words: cobalt chloride, cobalt nitrate, crown ether, coordination compound, synthesis

Zhang Youming, Lu Airu, Song Yumin, Zhang Lianxiang. STUDIES ON IRON FAMILY ELEMENTS COORDINATION COMPOUNDS WITH CROWN ETHERS Ⅹ.COMPLEXES OF COBALT CHLORIDE AND COBALT NITRATE WITH CROWN ETHERS[J]. Chinese Journal of Applied Chemistry, 1992, 0(4): 52-57.

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STUDIES ON IRON FAMILY ELEMENTS COORDINATION COMPOUNDS WITH CROWN ETHERS Ⅹ.COMPLEXES OF COBALT CHLORIDE AND COBALT NITRATE WITH CROWN ETHERS

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