Chinese Journal of Applied Chemistry ›› 1991, Vol. 0 ›› Issue (2): 78-81.

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PROPERTIES OF COPU/PMMA AB CROSSLINKED POLYMERS

Du Ying, Liu Wenzhong, Han Xiaozu   

  1. Changchun Institute of Applied Chemistry, Academia Sintca, Changchun 130022
  • Received:1989-12-29 Revised:1990-05-28 Published:1991-04-10 Online:1991-04-10

Abstract: The effects of composition, crosslink density of COPU/PMMA AB crosslinked polymerson their mechanical, dynamic mechanical properties, compatibility an d morphology werestudied.The results show that increasing the content of hard segment and decreasing cros-slink density make the compatibility of the polymer worse.TEM shows that the COPU/PMMA AB crosslinked polymer systems transform from apparent compatible to semi-compatibleone with the increase of hard segment content,and the phase inversion occurs when PMMA content reaches to 50%.The damping value is controlled mainly by the crosslink density,whereas the Tg value by the component.

Key words: AB crosslinked polymer, castor oil, MMA, toluene disocyanate, mechanical property