CHLORO-PLATINIC ACID(SODIUM)-CROWN ETHER COMPLEXES AND THEIR CATALYTIC PROPERTIES IN HYDROSILYLATION OF UNSATURTAED COMPOUNDS

Chinese Journal of Applied Chemistry ›› 1988, Vol. 0 ›› Issue (2): 96-99.

• Report • Previous Articles

CHLORO-PLATINIC ACID(SODIUM)-CROWN ETHER COMPLEXES AND THEIR CATALYTIC PROPERTIES IN HYDROSILYLATION OF UNSATURTAED COMPOUNDS

Li Caiyun, Yuan Guangpu, Yan Shuyong, Xie Zhengxiao

Lanzhou Institute of Chemical Physics, Academia Sinica

Received:1987-01-15 Revised:1987-06-08 Published:1988-04-10 Online:1988-04-10

Abstract

Abstract: Four novel complexcs were obtained by reaoting H₂PtCl₆·6H₂O or Na₂PtCl₆ with 18 Crown-6 and 1, 7, 10, 16-tetraoxa-4, 13-diazacyclooctadecane in molar ratio of 1:2 and 1:1 respectively. The complexes arc stable and slightsoluble or unsoluble in common organic solvents. In hydrosilylation of unsaturated compounds the complexes show a high catalytic activity at 80℃ and can be recovered and reused for several times. The activity of the complexes are, however, lower than that of H₂PtCl₆ or Na₂PtCl₆ alone when the hydrosilylation is carried out at 40℃ or room temperature.

Key words: Platinic chloride Crownether compounds, Hydrosilylation Unsaturated, compounds

Li Caiyun, Yuan Guangpu, Yan Shuyong, Xie Zhengxiao . CHLORO-PLATINIC ACID(SODIUM)-CROWN ETHER COMPLEXES AND THEIR CATALYTIC PROPERTIES IN HYDROSILYLATION OF UNSATURTAED COMPOUNDS[J]. Chinese Journal of Applied Chemistry, 1988, 0(2): 96-99.

[1]	Fang-Xie SHEN, Xiang WAN, Wei-Chao WANG. Volatile Organic Compounds Degradation at Room Temperature on Mn-mullite YMn₂O₅ Catalyst [J]. Chinese Journal of Applied Chemistry, 2023, 40(6): 888-895.
[2]	Jia-Zheng LI, Shu-Zhong HE. Research Progress of Total Synthesis of Polygalolides [J]. Chinese Journal of Applied Chemistry, 2023, 40(5): 615-624.
[3]	Hong-Li YANG, Qian-Qi WANG, Huan WANG, Han YAN, Peng-Hui LIN, Jin-Qiu SONG, Yang DING, Shan-Hua LI, Fu-Nan LI. Structure Optimization， Synthesis and Anti-hepatocarcinoma Activity of Cinnamamide Compounds [J]. Chinese Journal of Applied Chemistry, 2023, 40(2): 261-267.
[4]	WANG Chunli,SUN Lianshan,ZHONG Ming,WANG Limin,CHENG Yong. Research Progress of Transition Metal and Compounds for Lithium-Sulfur Batteries [J]. Chinese Journal of Applied Chemistry, 2020, 37(4): 387-404.
[5]	MENG Fanfei,WEI Wei,ZHOU Sha,ZHOU Sha,LI Zhengming. Herbicidal Activity of Sulfonylurea Herbicides in Rice Fields [J]. Chinese Journal of Applied Chemistry, 2020, 37(4): 416-423.
[6]	MENG Fanfei, WEI Wei, ZHOU Sha, ZHOU Sha, LI Zhengming. Herbicidal Activity of Sulfonylurea Herbicides in Rice Fields [J]. Chinese Journal of Applied Chemistry, 2020, 37(4): 0-.
[7]	JIN Yuting, ZHI Defu, GUO Yongtai, SUI Yue, SUN Lei, ZWANG Qian, HAO Longxuan, ZHAO Chunhui. Whitening and Antioxidant Activities of Phenolic Derivatives [J]. Chinese Journal of Applied Chemistry, 2019, 36(11): 1257-1265.
[8]	LI Jiaqi, FU Dayou, YUAN Dong, XU Jing. Preparation and Characterization of ZnMgAl Hydrotalcite Supported BiOI [J]. Chinese Journal of Applied Chemistry, 2019, 36(1): 83-90.
[9]	LIU Taihong, FANG Yu. Film-based Fluorescent Gas Sensors [J]. Chinese Journal of Applied Chemistry, 2018, 35(9): 1133-1137.
[10]	SHI Yun, LI Mengsheng, DAN Yanni. Peroxidation of Benzoylimidazole [J]. Chinese Journal of Applied Chemistry, 2018, 35(5): 511-517.
[11]	HE Fagui,GAO Xiang. Application of Oxygen Nucleophiles Hydroxyl and Alkoxide Anions in Derivatization of Fullerenes [J]. Chinese Journal of Applied Chemistry, 2017, 34(5): 489-501.
[12]	DENG Youlin, TANG Shi, YUAN Li, LI Zengzeng, WANG Liangneng, LI Liyang, HUANG Guixiu, LIU Yingying, WU Yiting, FU Li. Copper-catalyzed Cyclization of Benamides and Alkyl Azo Compounds Leading to Isoquinolinediones Bearing α-Substituted Quaternary Carbon [J]. Chinese Journal of Applied Chemistry, 2017, 34(3): 330-337.
[13]	WANG Xuejin, ZHU Xiaping, LAN Lumei. Efficient Removal of Cr(Ⅵ) in Wastewater by Mg/Al Layered Superamolecular Compounds [J]. Chinese Journal of Applied Chemistry, 2017, 34(1): 98-104.
[14]	ZHU Zhaoqiang,DU Weimin,GUO Wei,ZHU Wenjuan. Research Progress of Preparation and Application of Transition Metal Ternary Compounds in Supercapacitors [J]. Chinese Journal of Applied Chemistry, 2016, 33(3): 267-276.
[15]	CHANG Jing, YAO Hong, WU Hongping, WANG Ruiyue, LIN Qi, WEI Taibao, ZHANG Youming. A Novel Dual-channel Chemosensor for Cyanide Ion in Aqueous Medium [J]. Chinese Journal of Applied Chemistry, 2016, 33(1): 108-115.

CHLORO-PLATINIC ACID(SODIUM)-CROWN ETHER COMPLEXES AND THEIR CATALYTIC PROPERTIES IN HYDROSILYLATION OF UNSATURTAED COMPOUNDS

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments