
Chinese Journal of Applied Chemistry ›› 2024, Vol. 41 ›› Issue (8): 1175-1183.DOI: 10.19894/j.issn.1000-0518.240046
• Full Papers • Previous Articles Next Articles
Xiang-Chun ZHANG1(), Heng-Bo MAO2, Zi-Xuan LUO3, Bin WEI3, Jing-Hua WANG4
Received:
2024-02-05
Accepted:
2024-07-02
Published:
2024-08-01
Online:
2024-08-27
Contact:
Xiang-Chun ZHANG
About author:
zxc54875@yeah.netSupported by:
CLC Number:
Xiang-Chun ZHANG, Heng-Bo MAO, Zi-Xuan LUO, Bin WEI, Jing-Hua WANG. Method for the Formation and Determination of Characteristic Parameters of Medium Phase Microemulsion[J]. Chinese Journal of Applied Chemistry, 2024, 41(8): 1175-1183.
Water sample | X | Y | Z | W | N |
---|---|---|---|---|---|
Reagent | Na2CO3, Na2SO4, NaCl | Na2CO3 | Alkyl aryl phosphate (Effective substance concentration 40%, 6 types in total: NηC12-5P、NηC14-5P、NηC16-5P、ηC14-3P、ηC14-5P、ηC14-7P) | Na2CO3, Na2SO4, NaCl, PAM | H2O |
ρ/(mg·L-1) | 4 655.742, 11.316 27, 1 381.249 | — | 103260 | 4 655.742, 11.316 27, 1 381.249, 2 333 | — |
Table 1 Water sample simulation configuration
Water sample | X | Y | Z | W | N |
---|---|---|---|---|---|
Reagent | Na2CO3, Na2SO4, NaCl | Na2CO3 | Alkyl aryl phosphate (Effective substance concentration 40%, 6 types in total: NηC12-5P、NηC14-5P、NηC16-5P、ηC14-3P、ηC14-5P、ηC14-7P) | Na2CO3, Na2SO4, NaCl, PAM | H2O |
ρ/(mg·L-1) | 4 655.742, 11.316 27, 1 381.249 | — | 103260 | 4 655.742, 11.316 27, 1 381.249, 2 333 | — |
Water sample coding | The proportion of basic water samples in the working water volume | ||||
---|---|---|---|---|---|
X | Y | Z | W | N | |
U0D3 | 90 | 0 | 4 | 0 | 6 |
U1D3 | 90 | 0.5 | 4 | 0 | 5.5 |
U2D3 | 90 | 0.9 | 4 | 0 | 5.1 |
U3D3 | 90 | 1.3 | 4 | 0 | 4.7 |
Table 2 Working water sample configuration ratio
Water sample coding | The proportion of basic water samples in the working water volume | ||||
---|---|---|---|---|---|
X | Y | Z | W | N | |
U0D3 | 90 | 0 | 4 | 0 | 6 |
U1D3 | 90 | 0.5 | 4 | 0 | 5.5 |
U2D3 | 90 | 0.9 | 4 | 0 | 5.1 |
U3D3 | 90 | 1.3 | 4 | 0 | 4.7 |
Water sample time/d | Maximum particle size/nm | Accumulation of liquid droplets in mesophase micro lotion/% | ||||||
---|---|---|---|---|---|---|---|---|
U0D3 | U1D3 | U2D3 | U3D3 | U0D3 | U1D3 | U2D3 | U3D3 | |
0 | 58.8 | 73.8 | 246.8 | 235.6 | 97 | 78 | 100 | 100 |
7 | 57.3 | 116.6 | 67.8 | 68.2 | 97 | 76 | 94 | 94 |
14 | 59.8 | 78.8 | 65.7 | 69.6 | 96 | 69 | 93 | 86 |
21 | 61.6 | 81.8 | 62.6 | 73.7 | 96 | 69 | 94 | 94 |
28 | 65.8 | 74.4 | 83.8 | 67.8 | 95 | 83 | 93 | 95 |
35 d | 67..4 | 76.2 | 53.8 | 67.8 | 95 | 89 | 93 | 92 |
49 | 68.8 | 74.4 | 68.5 | 85.8 | 92 | 87 | 92 | 83 |
63 | 68.8 | 73.1 | 67.1 | 77.5 | 90 | 93 | 95 | 94 |
77 | 69.9 | 78.9 | 89.8 | 97.6 | 89 | 91 | 89 | 93 |
91 | 66.3 | 67.8 | 66.4 | 73.1 | 87 | 89 | 93 | 95 |
Table 3 Cumulative distribution and maximum particle size of the first dispersed particle size group
Water sample time/d | Maximum particle size/nm | Accumulation of liquid droplets in mesophase micro lotion/% | ||||||
---|---|---|---|---|---|---|---|---|
U0D3 | U1D3 | U2D3 | U3D3 | U0D3 | U1D3 | U2D3 | U3D3 | |
0 | 58.8 | 73.8 | 246.8 | 235.6 | 97 | 78 | 100 | 100 |
7 | 57.3 | 116.6 | 67.8 | 68.2 | 97 | 76 | 94 | 94 |
14 | 59.8 | 78.8 | 65.7 | 69.6 | 96 | 69 | 93 | 86 |
21 | 61.6 | 81.8 | 62.6 | 73.7 | 96 | 69 | 94 | 94 |
28 | 65.8 | 74.4 | 83.8 | 67.8 | 95 | 83 | 93 | 95 |
35 d | 67..4 | 76.2 | 53.8 | 67.8 | 95 | 89 | 93 | 92 |
49 | 68.8 | 74.4 | 68.5 | 85.8 | 92 | 87 | 92 | 83 |
63 | 68.8 | 73.1 | 67.1 | 77.5 | 90 | 93 | 95 | 94 |
77 | 69.9 | 78.9 | 89.8 | 97.6 | 89 | 91 | 89 | 93 |
91 | 66.3 | 67.8 | 66.4 | 73.1 | 87 | 89 | 93 | 95 |
Related characteristic parameters | NηC12-5P | NηC14-5P | NηC16-5P |
---|---|---|---|
P1/% | 1.1 | 0.9 | 0.8 |
P2/% | 2.1 | 1.8 | 1.6 |
ΔP/% | 1.1 | 0.8 | 0.9 |
P*/% | 1.6 | 1.36 | 1.2 |
VM*/mL | 1.99 | 2.91 | 2.18 |
6.378 | 9.444 | 10.344 |
Table 4 Characteristic parameters of mid-phase microemulsions with different alkyl aryl chain lengths
Related characteristic parameters | NηC12-5P | NηC14-5P | NηC16-5P |
---|---|---|---|
P1/% | 1.1 | 0.9 | 0.8 |
P2/% | 2.1 | 1.8 | 1.6 |
ΔP/% | 1.1 | 0.8 | 0.9 |
P*/% | 1.6 | 1.36 | 1.2 |
VM*/mL | 1.99 | 2.91 | 2.18 |
6.378 | 9.444 | 10.344 |
Related characteristic parameters | ηC14-3P | ηC14-5P | ηC14-7P |
---|---|---|---|
P1/% | 2.1 | 1.6 | 0.6 |
P2/% | 4.6 | 3.6 | 2.5 |
ΔP/% | 2.6 | 2.1 | 2.0 |
P*/% | 3.36 | 2.61 | 1.56 |
VM*/mL | 2.46 | 2.78 | 3.31 |
4.61 | 5.68 | 7.44 |
Table 5 Characteristic parameters of alkyl aryl mid-phase microemulsion with different aryl positions
Related characteristic parameters | ηC14-3P | ηC14-5P | ηC14-7P |
---|---|---|---|
P1/% | 2.1 | 1.6 | 0.6 |
P2/% | 4.6 | 3.6 | 2.5 |
ΔP/% | 2.6 | 2.1 | 2.0 |
P*/% | 3.36 | 2.61 | 1.56 |
VM*/mL | 2.46 | 2.78 | 3.31 |
4.61 | 5.68 | 7.44 |
Related characteristic parameters | 30 ℃ | 40 ℃ | 50 ℃ | 60 ℃ |
---|---|---|---|---|
P1/% | — | 1.51 | 1.61 | 1.71 |
P2/% | — | 3.41 | 3.61 | 4.11 |
ΔP/% | — | 1.81 | 2.11 | 2.51 |
P*/% | — | 2.46 | 2.61 | 2.91 |
VM*/mL | — | 1.93 | 1.78 | 1.63 |
— | 6.197 | 5.681 | 5.177 |
Table 6 Characteristic parameters of mid-phase microemulsion under the influence of different temperatures
Related characteristic parameters | 30 ℃ | 40 ℃ | 50 ℃ | 60 ℃ |
---|---|---|---|---|
P1/% | — | 1.51 | 1.61 | 1.71 |
P2/% | — | 3.41 | 3.61 | 4.11 |
ΔP/% | — | 1.81 | 2.11 | 2.51 |
P*/% | — | 2.46 | 2.61 | 2.91 |
VM*/mL | — | 1.93 | 1.78 | 1.63 |
— | 6.197 | 5.681 | 5.177 |
1 | LU B, LIU N, LI H, et al. Quantitative determination and characteristic wavelength selection of available nitrogen in coco-peat by NIR spectroscopy[J]. Soil Till Res, 2019, 191: 266-274. |
2 | 李世江, 闫淑芳, 陈伟东, 等. 磷酸盐体系正向电压对ZrH_(1.8)表面阻氢陶瓷层的影响[J]. 稀有金属, 2019, 43(8): 831-837. |
LI S J, YAN S F, CHEN W D, et al. ZrH1.8 Surface resistance ceramic layer in phosphate system under different forward voltages[J]. Chin J Rare Met, 2019, 43(8): 831-837. | |
3 | 朱宝伟, 陈红, 刘海燕, 等. 微通道混合器的研制及在微乳液制备中的应用[J]. 化学试剂, 2019, 41(6): 566-571. |
ZHU B W, CHEN H, LIU H Y, et al. Development of microchannel mixer and application in preparation of microemulsion[J]. Chem Reag, 2019, 41(6): 566-571. | |
4 | ZHANG S, ZHANG Y. Characteristic analysis and calculation of frequencies of voltages in out-of-step oscillation power system and a frequency-based out-of-step protection[J]. IEEE Trans Power Syst, 2019, 34(1): 205-214. |
5 | BEHRENSDORF-NICOL H A, EMINA W, URSULA B, et al. In vitro potency determination of botulinum neurotoxin serotype A based on its receptor-binding and proteolytic characteristics[J]. Toxicol In Vitro, 2018, 53: 80-88. |
6 | FERNANDEZ-PUMAREGA A, SUSANA AMÉZQUETA, FUGUET E, et al. Determination of the retention factor of ionizable compounds in microemulsion electrokinetic chromatography[J]. Anal Chim Acta, 2019, 1078: 221-230. |
7 | CHERAGHI M, BAYATI BOOIN M, MAHMOUDIAN ESFAHANI M, et al. Determination of torque-speed characteristic for a two-speed elevator induction machine[J]. IET Electr Power Appl, 2018, 12(2): 239-246. |
8 | 陆玲, 孙志高, 周麟晨, 等. 石蜡/油酸钠/己醇/水微乳液的制备及性能研究[J]. 化学研究与应用, 2019, 31(6): 1220-1224. |
LU L, SUN Z G, ZHOU L C, et al. Preparation and properties of paraffin/sodium oleate/hexanol/water microemulsion[J]. Chem Res Appl, 2019, 31(6): 1220-1224. | |
9 | 罗明良, 司晓冬, 杨宗梅, 等. 连续油管缓蚀用微乳液的制备与性能[J]. 精细化工, 2018, 35(10): 1758-1764. |
LUO M L, SI X D, YANG Z M, et al. Preparation and performance of microemulsion for corrosion inhibition of coiled tubing[J]. Fine Chem, 2018, 35(10): 1758-1764. | |
10 | RUITAO C, YUTENG L, GUO Z, et al. In situ preparation and luminescence properties of CaWO4 and CaWO4∶Ln (Ln=Eu3+, Tb3+ ) nanoparticles and transparent CaWO4∶Ln/PMMA nanocomposites[J]. J Lumin, 2018, 202: 65-70. |
11 | ZHOU L, HE S, ZHAO Y, et al. Single channel identification in a meandering river with compound channels[J]. Oil Geophys Prospect, 2019, 54(1): 175-181. |
12 | HALIM M A, FRANCK B, TRISTAN D, et al. Direct determination of molecular weight distribution of calf-thymus DNAs and study of their fragmentation under ultrasonic and low-energy IR irradiations. a charge detection mass spectrometry investigation[J]. Rapid Commun Mass Spectrom, 2018,33(1): 12-25. |
13 | 张丽芳, 梁善庆, 张龙飞,等. 镁铝水滑石复配三聚氰胺磷酸盐制备阻燃中密度纤维板的工艺[J]. 木材工业, 2018, 32 (171): 11-14. |
ZHANG L F, LIANG S Q, ZHANG L F,et al. Manufacturing parameters for fire-retardant medium density fiberboard with magnesium-aluminum layered double hydroxide and melamine phosphate[J]. China Wood Ind, 2018, 32(171): 11-14. | |
14 | YANG J, JIA X C, WEI X, et al. tectonic characteristics and its hydrocarbon control in the block A, Indus basin[J]. Soil Geophys Prosp, 2019, 54(2): 417-422. |
15 | YANG S, LU J, YANG C. Multi-wave AVO responses in fractured tight sandstone[J]. Oil Geophys Prospect, 2018, 53(4): 798-804. |
[1] | Xue-Yan YANG, Jun-Jie SHI, Yong-Jun ZHOU, Yu-Mei DAI, Hong-Zhou LI. Flame Retardancy of Epoxy Resin Enhanced by Intercalation of Magnesium Aluminum Hydrotalcite with Phosphorous Flame Retardants [J]. Chinese Journal of Applied Chemistry, 2024, 41(8): 1154-1167. |
[2] | Xiao-Jing CHAI, Rui-Rui ZHAO, Yuan ZHANG, Chuan DONG, Shao-Min SHUANG. Colorimetric/Fluorometric Detection of Adenosine-5′-Triphosphate Based on Metal-Organic Framework Cu@Sc-MOF Nanozyme [J]. Chinese Journal of Applied Chemistry, 2024, 41(5): 728-738. |
[3] | Zi-Wei LU, Yong-Fu LIU, Zhao-Hua LUO, Peng SUN, Jun JIANG. Progress on Cr3+-Doped Broadband Near-Infrared Phosphors [J]. Chinese Journal of Applied Chemistry, 2024, 41(3): 328-339. |
[4] | Yue ZHANG, Rui LIANG, Can-Nan ZHAO, Chun-Mei LI. Construction of Graphene Oxide-DNA Nanoprobe for Adenosine 5-Triphosphate Detection and Drug Delivery [J]. Chinese Journal of Applied Chemistry, 2024, 41(1): 118-127. |
[5] | Jun-Jie SHI, Zhe-Hang SHI, Hong-Zhou LI. Preparation of Magnesium Aluminum-Type Hydrotalcite Compounds Intercalated with Phosphorus Flame Retardants and Their Flame Retardant Application in Thermoplastic Polyurethane [J]. Chinese Journal of Applied Chemistry, 2023, 40(9): 1288-1301. |
[6] | Ying-Hua GUO, Shun-Fa ZHOU, Jing LI, Wei-Wei CAI. Research Progress in Regulation Strategy of Transition Metal Phosphate Catalyst for Electrochemical Water Splitting [J]. Chinese Journal of Applied Chemistry, 2023, 40(8): 1094-1108. |
[7] | Wei WANG, Jia-Yuan LI. Research Progress of Cobalt Phosphide Heterojunction Catalysts for Electrolytic Hydrogen Evolution Reaction [J]. Chinese Journal of Applied Chemistry, 2023, 40(8): 1175-1186. |
[8] | Yuan-Hua ZHANG, Sheng-Ran LI, Xi-Fei YU. Fluoride-Functionalized Choline Phosphate Liposomes for Oral Insulin Administration [J]. Chinese Journal of Applied Chemistry, 2023, 40(5): 730-742. |
[9] | Sheng-Jie LIU, Yong-Jie YE, Yin-Yi LIU, Shu-Man LIN, Hao-Yuan XIE, Wen-Ting LIU, Wei-Qin XU. Preparation of Uniformly Loaded Cu3P Nanoparticles in Porous Carbon Based on Copper Foam and Their Photocatalytic Performance for Dye Degradation [J]. Chinese Journal of Applied Chemistry, 2022, 39(7): 1090-1097. |
[10] | LI Chun, YU Yan-Hao. Research Progress on Mechanism and Application of Biomimetic Mineralization [J]. Chinese Journal of Applied Chemistry, 2022, 39(1): 74-85. |
[11] | ZHANG Yanping, XUE Dongfeng. Influence of Sodium and Potassium Ions on Dihydrogen Phosphate Anion Raman Spectra [J]. Chinese Journal of Applied Chemistry, 2020, 37(7): 823-829. |
[12] | ZHAO Bingbing, DENG Dongyang, CHEN Guihua, SONG Qingmei, FU Jianping, ZHANG Sukun, ZHOU Chengyong, JÜ Yongming. Main Influencing Factors and Removal Mechanism of Phosphate Anions by Chitosan-Fe(III) Composite Gel Beads [J]. Chinese Journal of Applied Chemistry, 2020, 37(6): 673-682. |
[13] | CHEN Chen, RUAN Hongli, Lü Le, SONG Zhixi, Lü Chengwei, AN Yue. Synthesis of Pyridazine Derivatives by Base-Catalyzed Three-Component Reaction of Aldehyde, Malononitrile and Phthalhydrazide [J]. Chinese Journal of Applied Chemistry, 2020, 37(5): 502-511. |
[14] | HU Chen,JIN Yi,ZHU Shaoqing,XU Ye,SHUI Jianglan. Methods for Improving Low-Temperature Performance of Lithium Iron Phosphate Based Li-Ion Battery [J]. Chinese Journal of Applied Chemistry, 2020, 37(4): 380-386. |
[15] | DONG Zhiyun, ZHANG Xiaoyu, ZENG Zhengquan, XI Fugui. Anthracene-Benzimidazolium Based Fluorescent Chemosensor for Highly Selective Recogniton of H2PO4- [J]. Chinese Journal of Applied Chemistry, 2020, 37(1): 80-87. |
Viewed | ||||||||||||||||||||||||||||||||||||||||||||||||||
Full text 1181
|
|
|||||||||||||||||||||||||||||||||||||||||||||||||
Abstract 324
|
|
|||||||||||||||||||||||||||||||||||||||||||||||||