Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (9): 1288-1301.DOI: 10.19894/j.issn.1000-0518.230044
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Jun-Jie SHI, Zhe-Hang SHI, Hong-Zhou LI()
Received:
2023-03-01
Accepted:
2023-07-08
Published:
2023-09-01
Online:
2023-09-14
Contact:
Hong-Zhou LI
About author:
lihongzhou@fjnu.edu.cnSupported by:
CLC Number:
Jun-Jie SHI, Zhe-Hang SHI, Hong-Zhou LI. Preparation of Magnesium Aluminum-Type Hydrotalcite Compounds Intercalated with Phosphorus Flame Retardants and Their Flame Retardant Application in Thermoplastic Polyurethane[J]. Chinese Journal of Applied Chemistry, 2023, 40(9): 1288-1301.
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URL: http://yyhx.ciac.jl.cn/EN/10.19894/j.issn.1000-0518.230044
Sample | T5%/℃ | T10%/℃ | Maximum thermal mass loss temperature/℃ | Mass residue ratio/% at 800 ℃ |
---|---|---|---|---|
DOPO | 221.4 | 237.0 | 303.0 | 0 |
MAH | 170.1 | 206.8 | 215.3 | 57.8 |
DOPO5+MAH1 | 176.5 | 207.7 | 214.8 | 47.8 |
DOPO5-MAH1-6h | 191.4 | 209.9 | 203.0 | 55.3 |
Table 1 Thermogravimetric parameters of DOPO5-MAH1 compounds and mixtures
Sample | T5%/℃ | T10%/℃ | Maximum thermal mass loss temperature/℃ | Mass residue ratio/% at 800 ℃ |
---|---|---|---|---|
DOPO | 221.4 | 237.0 | 303.0 | 0 |
MAH | 170.1 | 206.8 | 215.3 | 57.8 |
DOPO5+MAH1 | 176.5 | 207.7 | 214.8 | 47.8 |
DOPO5-MAH1-6h | 191.4 | 209.9 | 203.0 | 55.3 |
Sample | T5%/℃ | T10%/℃ | Maximum thermal mass loss temperature/℃ | Mass residue ratio/% at 800 ℃ |
---|---|---|---|---|
APP | 296.2 | 324.9 | 578.7 | 44.1 |
MAH | 170.1 | 206.8 | 215.3 | 57.8 |
APP5+MAH1 | 176.8 | 209.1 | 349.4 | 56.6 |
APP5-MAH1-6h | 259.3 | 301.8 | 319.3 | 64.6 |
Table 2 Thermogravimetric parameters of APP5-MAH1 compounds and mixtures
Sample | T5%/℃ | T10%/℃ | Maximum thermal mass loss temperature/℃ | Mass residue ratio/% at 800 ℃ |
---|---|---|---|---|
APP | 296.2 | 324.9 | 578.7 | 44.1 |
MAH | 170.1 | 206.8 | 215.3 | 57.8 |
APP5+MAH1 | 176.8 | 209.1 | 349.4 | 56.6 |
APP5-MAH1-6h | 259.3 | 301.8 | 319.3 | 64.6 |
Sample | T5%/℃ | T10%/℃ | Maximum thermal mass loss temperature/℃ | Mass residue ratio/% at 800 ℃ |
---|---|---|---|---|
MPP | 241.2 | 275.4 | 390.5 | 30.2 |
MAH | 171.5 | 206.8 | 215.0 | 57.8 |
MPP5+MAH1 | 110.6 | 232.6 | 299.7 | 35.2 |
MPP5-MAH1-6h | 207.5 | 264.2 | 402.1 | 33.4 |
Table 3 Thermogravimetric parameters of MPP5-MAH1 compounds and mixtures
Sample | T5%/℃ | T10%/℃ | Maximum thermal mass loss temperature/℃ | Mass residue ratio/% at 800 ℃ |
---|---|---|---|---|
MPP | 241.2 | 275.4 | 390.5 | 30.2 |
MAH | 171.5 | 206.8 | 215.0 | 57.8 |
MPP5+MAH1 | 110.6 | 232.6 | 299.7 | 35.2 |
MPP5-MAH1-6h | 207.5 | 264.2 | 402.1 | 33.4 |
Sample | TTI/s | Peak-HRR/(kW·m-2) | THR/(MJ·m-2) | SPR/(m2·s-1) | MLR/(g·s-1) |
---|---|---|---|---|---|
TPU | 22 | 1 236.6 | 105.7 | 0.19 | 0.36 |
MAH/TPU | 35 | 679.7 | 97.0 | 0.11 | 0.23 |
DOPO/TPU | 36 | 1 214.5 | 102.1 | 0.24 | 0.29 |
(DOPO+MAH)/TPU | 40 | 669.3 | 103.4 | 0.13 | 0.22 |
(DOPO-MAH-6h)/TPU | 45 | 573.9 | 98.2 | 0.13 | 0.20 |
Table 4 Cone test data of TPU and DOPO-MAH
Sample | TTI/s | Peak-HRR/(kW·m-2) | THR/(MJ·m-2) | SPR/(m2·s-1) | MLR/(g·s-1) |
---|---|---|---|---|---|
TPU | 22 | 1 236.6 | 105.7 | 0.19 | 0.36 |
MAH/TPU | 35 | 679.7 | 97.0 | 0.11 | 0.23 |
DOPO/TPU | 36 | 1 214.5 | 102.1 | 0.24 | 0.29 |
(DOPO+MAH)/TPU | 40 | 669.3 | 103.4 | 0.13 | 0.22 |
(DOPO-MAH-6h)/TPU | 45 | 573.9 | 98.2 | 0.13 | 0.20 |
Sample | TTI/s | Peak-HRR/(kW·m-2) | THR/(MJ·m-2) | SPR/(m2·s-1) | MLR/(g·s-1) |
---|---|---|---|---|---|
TPU | 22 | 1 236.6 | 105.7 | 0.19 | 0.36 |
MAH/TPU | 35 | 679.7 | 97.0 | 0.11 | 0.23 |
APP/TPU | 32 | 963.0 | 96.7 | 0.16 | 0.31 |
(APP+MAH)/TPU | 33 | 657.7 | 89.1 | 0.12 | 0.25 |
(APP-MAH-6h)/TPU | 36 | 405.9 | 71.2 | 0.09 | 0.14 |
Table 5 Cone test data of TPU and APP-MAH
Sample | TTI/s | Peak-HRR/(kW·m-2) | THR/(MJ·m-2) | SPR/(m2·s-1) | MLR/(g·s-1) |
---|---|---|---|---|---|
TPU | 22 | 1 236.6 | 105.7 | 0.19 | 0.36 |
MAH/TPU | 35 | 679.7 | 97.0 | 0.11 | 0.23 |
APP/TPU | 32 | 963.0 | 96.7 | 0.16 | 0.31 |
(APP+MAH)/TPU | 33 | 657.7 | 89.1 | 0.12 | 0.25 |
(APP-MAH-6h)/TPU | 36 | 405.9 | 71.2 | 0.09 | 0.14 |
Sample | TTI/s | Peak-HRR/(kW·m-2) | THR/(MJ·m-2) | SPR/(m2·s-1) | MLR/(g·s-1) |
---|---|---|---|---|---|
TPU | 22 | 1 236.6 | 105.7 | 0.19 | 0.36 |
MAH/TPU | 35 | 679.7 | 97.0 | 0.11 | 0.23 |
MPP/TPU | 30 | 744.3 | 99.5 | 0.12 | 0.26 |
(MPP+MAH)/TPU | 32 | 513.7 | 94.4 | 0.11 | 0.19 |
(MPP-MAH-6h)/TPU | 40 | 524.0 | 91.3 | 0.10 | 0.18 |
Table 6 Cone test data of TPU and MPP-MAH
Sample | TTI/s | Peak-HRR/(kW·m-2) | THR/(MJ·m-2) | SPR/(m2·s-1) | MLR/(g·s-1) |
---|---|---|---|---|---|
TPU | 22 | 1 236.6 | 105.7 | 0.19 | 0.36 |
MAH/TPU | 35 | 679.7 | 97.0 | 0.11 | 0.23 |
MPP/TPU | 30 | 744.3 | 99.5 | 0.12 | 0.26 |
(MPP+MAH)/TPU | 32 | 513.7 | 94.4 | 0.11 | 0.19 |
(MPP-MAH-6h)/TPU | 40 | 524.0 | 91.3 | 0.10 | 0.18 |
1 | WANG S S, FANG Q, LIU C, et al. Biomass tannic acid intermediated surface functionalization of ammonium polyphosphate for enhancing fire safety and smoke suppression of thermoplastic polyurethane[J]. Eur Polym J, 2023, 187:111897. |
2 | 秦建雨, 赵翰鹏, 姚金雨, 等. 有机磷阻燃剂插层钙基蒙脱土纳米复合物的制备和表征[J]. 材料工程, 2022, 50(9): 78-88. |
QIN J Y, ZHAO H P, YAO J Y, et al. Preparation and characterization of intercalated calcium-based montmorillonite nanocompounds with organophosphorus flame retardants[J]. J Mater Eng, 2022, 50(9): 78-88. | |
3 | 林渊, 陈嘉炼, 李红周. 单宁酸/聚乙烯醇的阻燃性能[J]. 应用化学, 2023, 40(1): 69-78. |
LIN Y, CHEN J L, LI H Z. Flame retardant properties of tannic acid/poly(vinyl alcohol)[J]. Chin J Appl Chem, 2023, 40(1): 69-78. | |
4 | 周伯龙, 张明聪, 史翎. 反应型有机硅阻燃剂研究进展[J]. 应用化学, 2021, 38(12): 1556-1575. |
ZHOU B L, ZHANG M C, SHI L. Research progress on reactive silicone flame retardants[J]. Chin J Appl Chem, 2021, 38(12): 1556-1575. | |
5 | MOLINARI F N, BARRAGAN E, BILBAO E, et al. An electrospun polymer composite with fullerene-multiwalled carbon nanotube exohedral complexes can act as memory device[J]. Polymer, 2020, 184: 122380. |
6 | FARAHANCHI A, MALLOY R A, SOBKOWICZ M J. Extreme shear processing for exfoliating organoclay in nanocomposites with incompatible polymers[J]. Polymer, 2018, 145: 117-126. |
7 | ZHANG J, KONG Q, YANG L, et al. Few layered Co(OH)2 ultrathin nanosheet-based polyurethane nanocomposites with reduced fire hazard: from eco-friendly flame retardance to sustainable recycling[J]. Green Chem, 2016, 18(10): 3066-3074. |
8 | VATTATHURVALAPPIL S H, KUNDURTHI S, DRZAL L T, et al. Thermo-mechanical degradation in ABS-Fe3O4 polymer nanocomposite due to repeated electromagnetic heating[J]. Compos Part B-Eng, 2020, 201: 108374. |
9 | 吉婉丽, 钟少锋, 余雪满. 阻燃超疏水棉纤维的制备及性能[J]. 应用化学, 2020, 37(3): 301-306. |
JI W L, ZHONG S F, YU X M. Preparation and properties of superhydrophobic and flame-retardant cotton fabric[J]. Chin J Appl Chem, 2020, 37(3): 301-306. | |
10 | KILIARIS P, PAPASPYRIDES C D. Polymer/layered silicate(clay) nanocomposites: an overview of flame retardancy[J]. Prog Polym Sci, 2010, 35(7): 902-958. |
11 | KOKLUKAYA O, CAROSIO F, DURAN V L, et al. Layer-by-layer modified low density cellulose fiber networks: a sustainable and fireproof alternative to petroleum based foams[J]. Carbohyd Polym, 2020, 230: 115616. |
12 | HU X, LI M, YANG J, et al. In situ fabrication of melamine hydroxyl ethylidene diphosphonate wrapped montmorillonite for reducing the fire hazards of epoxy resin[J]. Appl Clay Sci, 2021, 201: 105934. |
13 | WANG Q, O′HARE D. Recent advances in the synthesis and application of layered double hydroxide (LDH) nanosheets[J]. Chem Rev, 2012, 112(7): 4124-4155. |
14 | KHAN A I, O′HARE D. Intercalation chemistry of layered double hydroxides: recent developments and applications[J]. J Mater Chem, 2002, 12(11): 3191-3198. |
15 | WEHBI M, MEHDI A, NEGRELL C, et al. Phosphorus-containing fluoropolymers: state of the art and applications[J]. ACS Appl Mater Interfaces, 2020, 12(1): 38-59. |
16 | HUO S, YANG S, WANG J, et al. A liquid phosphorus-containing imidazole derivative as flame-retardant curing agent for epoxy resin with enhanced thermal latency, mechanical, and flame-retardant performances[J]. J Hazard Mater, 2020, 386: 121984. |
17 | XU Y J, SHI X H, LU J H, et al. Novel phosphorus-containing imidazole as hardener for epoxy resin aiming at controllable latent curing behavior and flame retardancy[J]. Compos Part B-Eng, 2020, 184: 107673. |
18 | CHEN T, HONG J, PENG C, et al. Superhydrophobic and flame retardant cotton modified with DOPO and fluorine-silicon-containing crosslinked polymer[J]. Carbohyd Polym, 2019, 208: 14-21. |
19 | CHEN R, HU K, TANG H, et al. A novel flame retardant derived from DOPO and piperazine and its application in epoxy resin: flame retardance, thermal stability and pyrolysis behavior[J]. Polym Degrad Stabil, 2019, 166: 334-343. |
20 | SHI Y Q, FU T, XU Y J, et al. Novel phosphorus-containing halogen-free ionic liquid toward fire safety epoxy resin with well-balanced comprehensive performance[J]. Chem Eng J, 2018, 354: 208-219. |
21 | HOU S, WANG J, YANG S, et al. Synergistic effect between a novel triazine-based flame retardant and DOPO/HPCP on expoxy resin[J]. Polym Adv Technol, 2018, 29(11): 2774-2783. |
22 | 刘懿德, 陈嘉炼, 李红周, 等. 协效阻燃聚丙烯的阻燃性能[J]. 应用化学, 2019, 36(10): 1165-1171. |
LIU Y D, CHEN J L, LI H Z, et al. Flame retardant properties of synergistic flame retardant polypropylene[J]. Chin J Appl Chem, 2019, 36(10): 1165-1171. | |
23 | 杜以波, 何静, 李峰, 等. 水滑石及柱撑水滑石的制备和表征[J]. 北京化工大学学报, 1997, 24(3): 76-80. |
DU Y B, HE J, LI F, et al. Preparation and characterization of hydrotalcite and pillared hydrotalcite[J]. J Beijing Univ Chem Technol, 1997, 24(3): 76-80. | |
24 | CASTROVICI A, CAMINO G, DREVELLE C, et al. Ammonium polyphosphate-aluminum trihydroxide antagonism in fire retarded butadiene-styrene block copolymer[J]. Eur Polum J, 2005, 41(9): 2023-2033. |
25 | 张泽江, 梅秀娟, 冯良荣, 等. 三聚氰胺聚磷酸盐阻燃剂的合成与表征[J]. 应用化学, 2003, 20(11): 1035-1038. |
ZHANG Z J, MEI X J, FENG L R, et al. Preparation and characterization of melamine polyphosphate as a flame retardant[J]. Chin J Appl Chem, 2003, 20(11): 1035-1038. |
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