Research Progress of Non-Pt-Based Catalysts in Cathode Oxygen Reduction Reaction of Proton Exchange Membrane Fuel Cells

doi:10.19894/j.issn.1000-0518.230075

Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (8): 1077-1093.DOI: 10.19894/j.issn.1000-0518.230075

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Research Progress of Non-Pt-Based Catalysts in Cathode Oxygen Reduction Reaction of Proton Exchange Membrane Fuel Cells

Yi-Ning DONG¹^,², He LI¹^,², Xue GONG¹, Ce HAN¹, Ping SONG¹(), Wei-Lin XU¹^,²()

^1.State Key Laboratory of Electroanalytical Chemistry & Jilin Province Key Laboratory of Low Carbon Chemical Power，Changchun Institute of Applied Chemistry，Chinese Academy of Sciences，Changchun 130022，China
^2.School of Applied Chemistry and Engineering，University of Science and Technology of China，Hefei 230026，China

Received:2023-03-27 Accepted:2023-06-02 Published:2023-08-01 Online:2023-08-24
Contact: Ping SONG,Wei-Lin XU
About author:songping@ciac.ac.cn
weilinxu@ciac.ac.cn
Supported by:
the Key Research and Development Program Sponsored by the Ministry of Science and Technology （MOST）(2022YFA1203400);the National Natural Science Foundation of China(22072145)

Abstract

Abstract:

With the increasing demand for green and efficient energy storage devices， advanced technologies for clean energy conversion have attracted close attention from researchers. Fuel cells with environmental friendliness and high energy conversion efficiency are promising alternatives to traditional energy sources. However， Pt catalysts with high commercialization degrees in the industrial catalysis field have some problems， such as high cost， poor stability and weak anti-toxicity ability， which limits the further development of fuel cells. The development of non-Pt oxygen reduction reaction （ORR） catalysts with abundant reserves， low cost and excellent performance is an effective way to improve the efficiency of fuel cells. In this paper， based on the research results at home and abroad in recent years， various types of non-Pt system ORR catalysts， including non-precious metal and non-metal catalysts， are systematically introduced. The advantages， disadvantages and modification strategies of various catalysts are summarized， and challenges and prospects for the development of ORR electrocatalysts are put forward.

Key words: Proton exchange membrane fuel cell, Non-precious metal catalyst, Non-metal catalyst, Oxygen reduction reaction

CLC Number:

O646

Yi-Ning DONG, He LI, Xue GONG, Ce HAN, Ping SONG, Wei-Lin XU. Research Progress of Non-Pt-Based Catalysts in Cathode Oxygen Reduction Reaction of Proton Exchange Membrane Fuel Cells[J]. Chinese Journal of Applied Chemistry, 2023, 40(8): 1077-1093.

Figures/Tables 8

Fig.1 The ORR process for Wroblowa［6］. Copyright?1976， Elsevier

Fig.2 The schematic diagram for RRDE［11］. Copyright?2021， American Chemical Society

Fig.3 （A） Volcanic relationship between adsorption energy of oxygen intermediates and ORR activity［20］. Copyright?2004， American Chemical Society. （B） The model of the activity as a function of the adsorption energy of oxygen at a cell potential of 0.9 V. （A=kBTln （r））， where r is the rate per surface atom per second； Those shown in red are the measured activities relative to that of Pt. The activity of the experiment is A=kBTln （i/iPt）+Apt， where i/iPt is the current density relative to Pt， and APt is the theoretical value for the activity of Pt. It is assumed that the number of active sites per surface area is the same for Pt and all the alloys［18］. Copyright?2006 WILEY-VCH Verlag GmbH & Co. KGaA， Weinheim

Fig.4 （A） Linear sweep voltammetry （LSV） in rotating ring-disk electrode （RRDE） for different M-N-C catalysts at +1.2 V［31］； Copyright?2019 American Chemical Society. （B） Activity volcano correlation for the reduction of O2 in 0.1 mol/L NaOH on different molecular MN4 catalysts adsorbed on ordinary pyrolytic graphite （OPG）［32］.Copyright?2016 Wiley-VCH Verlag GmbH & Co. KGaA， Weinheim. （C-H） The relationship between gibbs free energy of *OH and the position of d-band［33］. Copyright? 2021 Elsevier B.V.

Fig.5 （A） Structural evolution of MnO［44］. Copyright?2020；（B） The schematic diagram of CoO nanosheet with oxygen defect［45］. Copyright?2021 Wiley-VCH GmbH

Fig.6 The scheme for the preparation of Co9S8@N，S-C and corresponding SEM image［55］. Copyright?2021 Wiley-VCH GmbH

Fig.7 ORR mechanism of 2e- process for Ni3（HITP）2［70］. Copyright?2017， American Chemical Society

Fig.8 （A） The structure model for N-doped carbon nanotube［78］；（B） The N，?F-codoping catalyst preparing by electrospinning［80］. Copyright@2020， Royal Society of Chemistry

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Research Progress of Non-Pt-Based Catalysts in Cathode Oxygen Reduction Reaction of Proton Exchange Membrane Fuel Cells

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