Research Progress in Regulation Strategy of Transition Metal Phosphate Catalyst for Electrochemical Water Splitting

doi:10.19894/j.issn.1000-0518.230108

Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (8): 1094-1108.DOI: 10.19894/j.issn.1000-0518.230108

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Research Progress in Regulation Strategy of Transition Metal Phosphate Catalyst for Electrochemical Water Splitting

Ying-Hua GUO, Shun-Fa ZHOU, Jing LI, Wei-Wei CAI()

Hydrogen Energy Technology Innovation Center of Hubei Province，Faculty of Materials Science and Chemistry，China University of Geosciences，Wuhan 430074，China

Received:2023-04-17 Accepted:2023-07-07 Published:2023-08-01 Online:2023-08-24
Contact: Wei-Wei CAI
About author:caiww@cug.edu.cn
Supported by:
the National Natural Science Foundation of China(22179121)

Abstract

Abstract:

Transition metal phosphate has attracted the attention of researchers in the field of electrolytic water because of its advantages of safety， cleanliness， low cost and high efficiency. Phosphate groups in phosphate have unique atomic geometric structure， strong coordination and various orientations， which are beneficial to stabilize the middle valence state of transition metals and accelerate proton conduction rate. However， its poor conductivity and low porosity have prompted researchers to explore and design more efficient transition metal phosphate electrocatalysts. Although researchers have invested a lot of time and energy， there are still many problems to be solved in the efficient development and utilization of transition metal phosphate electrocatalysts. In this paper， combined with the latest research progress of transition metal phosphate electrocatalysts， the development and design strategies of phosphate by researchers in recent years are introduced from the aspects of morphology control， defect engineering and interface engineering. At the same time， the opportunities and challenges faced by this kind of catalyst in the future material field are discussed from the aspects of scientific research and practical application.

Key words: Phosphate, Electrolytic water, Catalyst, Regulation strategy

CLC Number:

O614

Ying-Hua GUO, Shun-Fa ZHOU, Jing LI, Wei-Wei CAI. Research Progress in Regulation Strategy of Transition Metal Phosphate Catalyst for Electrochemical Water Splitting[J]. Chinese Journal of Applied Chemistry, 2023, 40(8): 1094-1108.

Figures/Tables 6

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Catalyst	Electrolyte	Overpotential （η₁₀）/V	Tafel slope/（mV·dec^-1）	Ref.
Fe_0.72Co_0.42PO₄/Ni^*	1.0 mol/L KOH	77	80.7	［16］
δ-FeOOH NSs/NF	1.0 mol/L KOH	265	36	［24］
CoPO/NF^*	1.0 mol/L KOH	116	65.6	［46］
S-doped Co-Fe-Pi	1.0 mol/L KOH	273	40	［56］
Gly-NCP	1.0 mol/L KOH 1.0 mol/L KOH+0.5 mol/L NaCl	265 252	57 39	［57］
NiFeP/Pi	0.1 mol/L KOH	210	39	［58］
α-ZrP	0.1 mol/L KOH	450	53.4	［59］
HEPi	1.0 mol/L KOH	270	74	［60］
Ni₅P₄@ Ni²⁺^δ O _δ （OH）_2-_δ^*	1.0 mol/L KOH Seawater 0.5 mol/L H₂SO₄	87 144 66	69 108 33	［61］
Nd₂O₃∶NdPO₄^*	0.5 mol/L H₂SO₄	134	55.6	［62］
CoFeP/NF	1.0 mol/L KOH	253	36	［63］
CoFePi	1.0 mol/L KOH	225	34	［64］
（Fe _x Co _y ）P₂O₇@N-C	1.0 mol/L KOH	341	34.9	［65］
FMZP4^*	1.0 mol/L KOH	53	53.2	［66］
RuFeP-NCs/CNF^*	0.5 mol/L H₂SO₄ 1.0 mol/L KOH	65.8 16.0	50 90.24	［67］
NiCo-2.0	1.0 mol/L KOH	320	84	［68］
Co₇Fe₃-P/C	1.0 mol/L KOH	260	37.8	［69］
Ni-Co-TEP-600	1.0 mol/L KOH	310	68	［70］
CoPiNF-800	1.0 mol/L KOH	222 （η₁₀₀）	62	［71］
NiCoPO@NC/P-NF-e	1.0 mol/L KOH	221	87.8	［72］
FPO₃/NF	1.0 mol/L KOH	309	96.9	［73］
A-Ni₂P/Cu₃P	1.0 mol/L KOH	262	78.1	［74］
NiCoPi/Ni-P/NiCoPi	1.0 mol/L KOH	234	87	［75］
Ni∶Pi-Fe/NF	1.0 mol/L KOH	220	37	［76］
Co-Zn-P/NiFoam	1.0 mol/L KOH	307	56.6	［77］
NiFeO _x H _y /NF-0H	1.0 mol/L KOH	205 （η₅₀）	30	［78］
Ni₃Fe-LDHs@CoP _x /NF	1 mol/L phosphate buffer+0.5 mol/L NaCl	370	76	［79］
NiCoFe phosphate NSs/NF	1.0 mol/L KOH	240	58	［80］
Ni（PO₃）^2-CoP₄/CoMoO₄/NF^*	1.0 mol/L KOH	79 （η₁₀₀）	27.75	［81］
De-LCoFeP/rGO	0.1 mol/L KOH	270	57.5	［82］
NiMo-Fe-P	1.0 mol/L KOH	215.2	37.52	［83］

Catalyst	Electrolyte	Overpotential （η₁₀）/V	Tafel slope/（mV·dec^-1）	Ref.
Fe_0.72Co_0.42PO₄/Ni^*	1.0 mol/L KOH	77	80.7	［16］
δ-FeOOH NSs/NF	1.0 mol/L KOH	265	36	［24］
CoPO/NF^*	1.0 mol/L KOH	116	65.6	［46］
S-doped Co-Fe-Pi	1.0 mol/L KOH	273	40	［56］
Gly-NCP	1.0 mol/L KOH 1.0 mol/L KOH+0.5 mol/L NaCl	265 252	57 39	［57］
NiFeP/Pi	0.1 mol/L KOH	210	39	［58］
α-ZrP	0.1 mol/L KOH	450	53.4	［59］
HEPi	1.0 mol/L KOH	270	74	［60］
Ni₅P₄@ Ni²⁺^δ O _δ （OH）_2-_δ^*	1.0 mol/L KOH Seawater 0.5 mol/L H₂SO₄	87 144 66	69 108 33	［61］
Nd₂O₃∶NdPO₄^*	0.5 mol/L H₂SO₄	134	55.6	［62］
CoFeP/NF	1.0 mol/L KOH	253	36	［63］
CoFePi	1.0 mol/L KOH	225	34	［64］
（Fe _x Co _y ）P₂O₇@N-C	1.0 mol/L KOH	341	34.9	［65］
FMZP4^*	1.0 mol/L KOH	53	53.2	［66］
RuFeP-NCs/CNF^*	0.5 mol/L H₂SO₄ 1.0 mol/L KOH	65.8 16.0	50 90.24	［67］
NiCo-2.0	1.0 mol/L KOH	320	84	［68］
Co₇Fe₃-P/C	1.0 mol/L KOH	260	37.8	［69］
Ni-Co-TEP-600	1.0 mol/L KOH	310	68	［70］
CoPiNF-800	1.0 mol/L KOH	222 （η₁₀₀）	62	［71］
NiCoPO@NC/P-NF-e	1.0 mol/L KOH	221	87.8	［72］
FPO₃/NF	1.0 mol/L KOH	309	96.9	［73］
A-Ni₂P/Cu₃P	1.0 mol/L KOH	262	78.1	［74］
NiCoPi/Ni-P/NiCoPi	1.0 mol/L KOH	234	87	［75］
Ni∶Pi-Fe/NF	1.0 mol/L KOH	220	37	［76］
Co-Zn-P/NiFoam	1.0 mol/L KOH	307	56.6	［77］
NiFeO _x H _y /NF-0H	1.0 mol/L KOH	205 （η₅₀）	30	［78］
Ni₃Fe-LDHs@CoP _x /NF	1 mol/L phosphate buffer+0.5 mol/L NaCl	370	76	［79］
NiCoFe phosphate NSs/NF	1.0 mol/L KOH	240	58	［80］
Ni（PO₃）^2-CoP₄/CoMoO₄/NF^*	1.0 mol/L KOH	79 （η₁₀₀）	27.75	［81］
De-LCoFeP/rGO	0.1 mol/L KOH	270	57.5	［82］
NiMo-Fe-P	1.0 mol/L KOH	215.2	37.52	［83］

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Research Progress in Regulation Strategy of Transition Metal Phosphate Catalyst for Electrochemical Water Splitting

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