Poly(n-butyl methacrylate)/Polystyrene Blend Compatibilized by the Diels-Alder Reaction of Furan/Maleimide

doi:10.11944/j.issn.1000-0518.2019.04.180300

Chinese Journal of Applied Chemistry ›› 2019, Vol. 36 ›› Issue (4): 451-458.DOI: 10.11944/j.issn.1000-0518.2019.04.180300

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Poly(n-butyl methacrylate)/Polystyrene Blend Compatibilized by the Diels-Alder Reaction of Furan/Maleimide

YE Lin^a^b,ZHANG Shaofeng^a^b,MIN Jiakang^a^b,MA Li^a^*(),TANG Tao^a^*()

^aState Key Laboratory of Rare Earth Resource Utilization,Changchun Institute of Applied Chemistry,Chinese Acdemy of Sciences,Changchun 130022,China
^bUniversity of Chinese Academy of Sciences,Beijing 100049,China

Received:2018-09-10 Accepted:2018-09-29 Published:2019-04-01 Online:2019-04-02
Contact: MA Li,TANG Tao
Supported by:
Supported by the National Natural Science Foundation of China(No.51233005, No.51573179, No.21304089)

Abstract

Abstract:

The compatibilization of immiscible poly(n-butyl methacrylate)(PBMA)/polystyrene(PS) blends was realized by the reaction of furan and maleimide groups. The furan-functionalized poly(n-butyl methacrylate)(P(BMA-co-FMA)) and maleimide-functionalized polystyrene(MPS) was synthesized by copolymerization and post-polymerization modification, respectively. The Diels-Alder reaction of the functionalized polymers and their blend were confirmed by nuclear magnetic resonance spectroscopy(NMR). The reaction of furan and maleimide dramatically promoted the compatibility of two components, confirmed by a homogeneous microstructure evidenced by transmission electron microscopy(TEM) observation and by the presence of a single glass transition temperature in the (P(BMA-co-FMA)/MPS blends. The properties of the blend materials could be controlled conveniently by adjusting the reaction time, and the blends transformed from tough material to brittle material gradually as the reaction processed, which was confirmed by the three point bending test.

Key words: poly(butyl methacrylate, polystyrene, polymer blend, compatibilization, diels-Alder reaction, furan/maleimide

YE Lin, ZHANG Shaofeng, MIN Jiakang, MA Li, TANG Tao. Poly(n-butyl methacrylate)/Polystyrene Blend Compatibilized by the Diels-Alder Reaction of Furan/Maleimide[J]. Chinese Journal of Applied Chemistry, 2019, 36(4): 451-458.

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Poly(n-butyl methacrylate)/Polystyrene Blend Compatibilized by the Diels-Alder Reaction of Furan/Maleimide

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