Hydrolysis of Cellulose by Solid Carbon Sulfonic Acid Supported 1-Butyl-3-methylimidazolium Chloride

doi:10.11944/j.issn.1000-0518.2019.01.180049

Chinese Journal of Applied Chemistry ›› 2019, Vol. 36 ›› Issue (1): 58-64.DOI: 10.11944/j.issn.1000-0518.2019.01.180049

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Hydrolysis of Cellulose by Solid Carbon Sulfonic Acid Supported 1-Butyl-3-methylimidazolium Chloride

QU Haonan,BAO Chong,MA Wenjing,MA Yiming,ZHAO Peng,WANG Xinhai(),ZHOU Yanmei()

He'nan Joint International Research Laboratory of Environmental Pollution Control Materials,College of Chemistry and Chemical Engineering,He'nan University,Kaifeng,He'nan 475004,China

Received:2018-02-19 Accepted:2018-06-07 Published:2019-01-01 Online:2019-01-04
Contact: WANG Xinhai,ZHOU Yanmei
Supported by:
Supported by the National Natural Science Foundation of China(No.21576071, No.21776061)

Abstract

Abstract:

Cellulose is a renewable resource. Compounds obtained by the hydrolysis of cellulose are of great significance to ease the energy pressure. Herein, the hydrolysis of cellulose catalyzed by solid carbon sulfonic acid supported 1-butyl-3-methylimidazolium chloride is reported. The solid carbon sulfonic acid obtained from bamboo biomass by pre-carbonization at 700 ℃ and sulfonation at 150 ℃ was used as the matrix. Ionic liquid functionalized solid carbon sulfonic acid catalyst was obtained by loading 1-butyl-3-methylimidazolium chloride. The results show that the total reducing sugar yield under optimal conditions is increased by 15.2% relative to the total reducing sugar yield by exploiting solid carbon sulfonic acid. The catalyst still exhibits good performance after recycling.

Key words: solid carbon sulfonic acid, ionic liquids, hydrolysis of cellulose

QU Haonan, BAO Chong, MA Wenjing, MA Yiming, ZHAO Peng, WANG Xinhai, ZHOU Yanmei. Hydrolysis of Cellulose by Solid Carbon Sulfonic Acid Supported 1-Butyl-3-methylimidazolium Chloride[J]. Chinese Journal of Applied Chemistry, 2019, 36(1): 58-64.

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Hydrolysis of Cellulose by Solid Carbon Sulfonic Acid Supported 1-Butyl-3-methylimidazolium Chloride

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