Synthesis, Structure and Molecule Recognition Properties of a New Wave-Shaped Chain Cadmium Complex

doi:10.11944/j.issn.1000-0518.2017.09.170060

Chinese Journal of Applied Chemistry ›› 2017, Vol. 34 ›› Issue (9): 1093-1098.DOI: 10.11944/j.issn.1000-0518.2017.09.170060

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Synthesis, Structure and Molecule Recognition Properties of a New Wave-Shaped Chain Cadmium Complex

HUANG Qiuying^a^*(),LIN Xiaoyi^b,WANG Yong^a,ZHU Yongchao^c

^aDepartment of Chemical Engineering,He'nan Polytechnic Institute,Nanyang,He'nan 473009,China
^bNo.1 Middle School of Nanyang,Nanyang,He'nan 473000,China
^cCollege of Chemistry and Molecular Engineering,Zhengzhou University,Zhengzhou 450001,China

Received:2017-03-07 Accepted:2017-07-18 Published:2017-08-31 Online:2017-08-31
Contact: HUANG Qiuying
Supported by:
Supported by the National Natural Science Foundation of China(No.J1210060), Henan Science and Technology Project(No.172102210128)

Abstract

Abstract:

By the hydrothermal reaction of Cd(NO₃)₂·4H₂O with 2-(2-bromophenyl)-1H-imidazole-4,5-dicarboxylic acid(o-BrPhH₃IDC) and ammonium oxalate, a new wave-shaped chain complex {[Cd(o-BrPhH₂IDC)₂(H₂O)]·H₂O}_n(1) was synthesized and characterized through elemental analysis, Fourier transform infrared spectrometer, thermogravimetric and single crystal X-ray diffraction analysis. The results show that complex 1 crystallizes in the orthorhombic space group Pbca. Excited by the wavelength of 316 nm, complex 1 shows the maximum fluorescence emission peak around 356 nm. Further experiments show that acetonitrile significantly increases the fluorescence intensity of complex 1, and methanol and ethanol may decrease the fluorescence intensity. If complex 1 is treated with pyridine, the fluorescence emission peak of complex 1 disappears, which indicates selective recognition for pyridine.

Key words: Cd-complex, imidazole dicarboxylic acid, crystal structure, fluorescence properties, small molecule recognition

HUANG Qiuying, LIN Xiaoyi, WANG Yong, ZHU Yongchao. Synthesis, Structure and Molecule Recognition Properties of a New Wave-Shaped Chain Cadmium Complex[J]. Chinese Journal of Applied Chemistry, 2017, 34(9): 1093-1098.

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Synthesis, Structure and Molecule Recognition Properties of a New Wave-Shaped Chain Cadmium Complex

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