Synthesis, Crystal Structure and Properties of Dinuclear Copper(Ⅱ) Complex {[Cu(Phen)(Nap)2]2·(EtOH)2·(H2O)2} (Phen=1,10-Phenanthroline; Nap=1-Naphthoic Acid; EtOH=Ethyl Alcohol)

doi:10.11944/j.issn.1000-0518.2016.08.150402

Chinese Journal of Applied Chemistry ›› 2016, Vol. 33 ›› Issue (8): 932-938.DOI: 10.11944/j.issn.1000-0518.2016.08.150402

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Synthesis, Crystal Structure and Properties of Dinuclear Copper(Ⅱ) Complex {[Cu(Phen)(Nap)₂]₂·(EtOH)₂·(H₂O)₂} (Phen=1,10-Phenanthroline; Nap=1-Naphthoic Acid; EtOH=Ethyl Alcohol)

ZHU Xiaoming,FENG Yonglan,ZHANG Fuxing,YU Jiangxi,JIANG Wujiu,OU Yaping,KUANG Daizhi()

Key Laboratory of Functional Organometallic Materials of Hengyang Normal University,College of Hu'nan Province,College of Chemistry and Material Science,Hengyang Normal University,Hengyang,Hu'nan 421008,China

Received:2015-11-16 Accepted:2016-02-25 Published:2016-07-21 Online:2016-07-21
Contact: KUANG Daizhi
Supported by:
Supported by Hu'nan Provincial Natural Science Foundation of China(No.13JJ3112), Scientific & Technological Projects of Hu'nan Province(No.2014NK3086, No.2014FJ3060), the Open Fund Project of Key Laboratory of Functional Organometallic Materials of Hengyang Normal University(No.13K105, No.14K014, No.13K01-05, No.GN14K01), Aid Programs for Science and Technology Innovative Research Team in Higher Educational Institutions of Hu'nan Province and the Key Discipline of Hu'nan Province. the Scientific Research Fund of Hunan Provincial Education Department of China(No.15C0199, No.15C0200, No.14C0171, No.14C0168), the Science Foundation of Hengyang Normal University of China(No.12C45)

Abstract

Abstract:

A new complex [Cu(Phen)(Nap)₂]₂·(EtOH)₂·(H₂O)₂(Phen=1,10-phenanthroline; Nap=1-naphthoic acid; EtOH=ethyl alcohol) was synthesized. The compound was characterized by elemental analysis, FTIR, TG-DTG, single crystal X-ray diffraction. The complex is dinuclear copper(Ⅱ) structure. The electrochemical and luminescent properties of the complex was studied by cyclic voltammetry and emission spectrum. The interactions of the complex with calf thymus DNA(ct-DNA) has been studied by UV and fluorescence spectroscopy. The results show that the copper(Ⅱ) complex shows irreversible redox process, and possesses a fluorescent emission band at 416 nm, and this copper(Ⅱ) complex binds to ct-DNA in groove binding and its intrinsic binding constant K_b is 4.68×10³ L/mol.

Key words: dinuclear copper(Ⅱ) complex, synthesis, crystal structure, DNA, electrochemical performance

ZHU Xiaoming, FENG Yonglan, ZHANG Fuxing, YU Jiangxi, JIANG Wujiu, OU Yaping, KUANG Daizhi. Synthesis, Crystal Structure and Properties of Dinuclear Copper(Ⅱ) Complex {[Cu(Phen)(Nap)₂]₂·(EtOH)₂·(H₂O)₂} (Phen=1,10-Phenanthroline; Nap=1-Naphthoic Acid; EtOH=Ethyl Alcohol)[J]. Chinese Journal of Applied Chemistry, 2016, 33(8): 932-938.

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Synthesis, Crystal Structure and Properties of Dinuclear Copper(Ⅱ) Complex {[Cu(Phen)(Nap)₂]₂·(EtOH)₂·(H₂O)₂} (Phen=1,10-Phenanthroline; Nap=1-Naphthoic Acid; EtOH=Ethyl Alcohol)

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