Solid and Solution Properties of Zinc(Ⅱ) and Cobalt(Ⅱ) with Ethylenediaminetriacetate

doi:10.11944/j.issn.1000-0518.2016.01.150208

Chinese Journal of Applied Chemistry ›› 2016, Vol. 33 ›› Issue (1): 70-75.DOI: 10.11944/j.issn.1000-0518.2016.01.150208

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Solid and Solution Properties of Zinc(Ⅱ) and Cobalt(Ⅱ) with Ethylenediaminetriacetate

WU Rui,YANG Yuchen,DONG Xin,ZHOU Zhaohui()

College of Chemistry and Chemical Engineering,State Key Laboratory of Physical Chemistry of Solid Surfaces,Xiamen University,Xiamen 361005,China

Received:2015-06-19 Accepted:2015-10-08 Published:2016-01-05 Online:2016-01-05
Contact: ZHOU Zhaohui
Supported by:
Supported by the Research Funds for the Central Universities (No.20720150041) and the Program for Innovative Research Team in Chinese Universities(No.IRT_14R31)

Abstract

Abstract:

Zinc and cobolt ethylenediaminetriacetates [M(H₂O)₆][M(ED3A)(H₂O)]₂·2H₂O[M=Zn(1), Co(2); H₃ED3A=ethylenediaminetriacetic acid, C₈H₁₄N₂O₆] were obtained on the hydrothermal conditions at 140 ℃ in a weak acidic solution. Complexes 1 and 2 were characterized by elemental analysis, IR, TG-DTG, solution ¹³C NMR spectroscopy, and X-ray analysis. ED3A coordinates with zinc or cobalt ions as a pentadentate ligand. The metal ions are arranged in octahedral coordination geometries [MN₂O₄] or [MO₆]. Comparisons of ¹³C NMR spectra demonstrate that the coordination of ED3A zinc complex is stable in weak acidic solution(pH 3~7), while ED3A cyclizes to form ketopiperazinediacetic acid(H₂kpda, C₈H₁₂N₂O₅) under acidic condition.

Key words: ethylenediaminetriacetic acid, ketopiperazinediacetic acid, equilibrium, zinc, cobalt, 13C NMR spectra

WU Rui, YANG Yuchen, DONG Xin, ZHOU Zhaohui. Solid and Solution Properties of Zinc(Ⅱ) and Cobalt(Ⅱ) with Ethylenediaminetriacetate[J]. Chinese Journal of Applied Chemistry, 2016, 33(1): 70-75.

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Solid and Solution Properties of Zinc(Ⅱ) and Cobalt(Ⅱ) with Ethylenediaminetriacetate

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