Synthesizing and Bonding Bidentate Schiff Base Ligand on Side Chain of Polysulfone and Preliminary Exploration of Luminescence Property of Functionalized Polysulfone-Tb(Ⅲ) Complexes

doi:10.11944/j.issn.1000-0518.2016.01.150162

Chinese Journal of Applied Chemistry ›› 2016, Vol. 33 ›› Issue (1): 53-62.DOI: 10.11944/j.issn.1000-0518.2016.01.150162

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Synthesizing and Bonding Bidentate Schiff Base Ligand on Side Chain of Polysulfone and Preliminary Exploration of Luminescence Property of Functionalized Polysulfone-Tb(Ⅲ) Complexes

ZHANG Dandan,ZHA Xianyu,GAO Baojiao()

Department of Chemical Engineering,North University of China,Taiyuan 030051,China

Received:2015-05-11 Accepted:2015-10-08 Published:2016-01-05 Online:2016-01-05
Contact: GAO Baojiao
Supported by:
Supported by the Shanxi Province Science Foundation for Youths(No.2013021012-3)

Abstract

Abstract:

The esterification of chloromethylated polysulfone(CMPSF) with glyoxylic acid(GA) afforded aldehyde(AL) modified PSF-AL. Subsequent condensation of PSF-AL with 3-aminopyridine led to bidentate Schiff base ligand-functionalized PSF-AA. The chemical structure of PSF-AA was characterized by FTIR and ¹H NMR spectra. The binary polymer-rare earth complexes of PSF-(AA)₃-Tb(Ⅲ) and PSF-(AA)₃-Eu(Ⅲ) were prepared and their photoluminescence properties were preliminarily explored. Optimized esterification between CMPSF and GA were performed in N,N-dimethylacetamide at 75 ℃. The macromolecular PSF-AA does not exhibit sensitization towards Eu(Ⅲ) ion, whereas PSF-AA can strongly sensitize the fluorescence emission of Tb(Ⅲ) ion. The complex PSF-(AA)₃-Tb(Ⅲ) emits characteristic green fluorescence of Tb(Ⅲ) ion.

Key words: polysulfone, polymer-rare earth complex, bidentate schiff base ligand, sensitization, Tb(Ⅲ) ion

ZHANG Dandan, ZHA Xianyu, GAO Baojiao. Synthesizing and Bonding Bidentate Schiff Base Ligand on Side Chain of Polysulfone and Preliminary Exploration of Luminescence Property of Functionalized Polysulfone-Tb(Ⅲ) Complexes[J]. Chinese Journal of Applied Chemistry, 2016, 33(1): 53-62.

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Synthesizing and Bonding Bidentate Schiff Base Ligand on Side Chain of Polysulfone and Preliminary Exploration of Luminescence Property of Functionalized Polysulfone-Tb(Ⅲ) Complexes

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