Sensitized Luminescence of Terbium(Ⅲ) in BaF2∶Tb3+ Nanoparticles by Salicylate

doi:10.11944/j.issn.1000-0518.2018.07.170295

Chinese Journal of Applied Chemistry ›› 2018, Vol. 35 ›› Issue (7): 812-817.DOI: 10.11944/j.issn.1000-0518.2018.07.170295

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Sensitized Luminescence of Terbium(Ⅲ) in BaF₂∶Tb³⁺Nanoparticles by Salicylate

Suwen LI(),Xuewei ZHANG,Yi JIANG,Jinying YUE,Cong GUAN

College of Science,Changchun Institute of Technology,Changchun 130012,China

Accepted:2017-12-01 Published:2018-07-06 Online:2018-07-06
Contact: Suwen LI
Supported by:
Supported by the National Natural Science Foundation of China(No.11304021), the Undergraduate Innovation and Entrepreneurship Training Program of Jilin Province(No.201611437001)

Abstract

Abstract:

Uniform BaF₂∶Tb³⁺ nanoparticles have been prepared by hydrothermal synthesis, and sodium salicylate(SS) sensitized BaF₂∶Tb³⁺(SS-BaF₂∶Tb³⁺) nanoparticles have been prepared by the ion exchange technique. Their structures, morphologies and photoluminescence properties were studied. A broad excitation band from 200 to 385 nm by monitoring ⁵D₄→⁷F₅ transition of Tb³⁺ at 547 nm in SS-BaF₂∶Tb³⁺ nanoparticles was detected. Under excitation of the π-π^* electron transition absorption of salicylate, enhanced green emission of Tb³⁺ ions in SS-BaF₂∶Tb³⁺ nanoparticles was observed due to the energy transfer from SS to Tb³⁺ ions by “antenna effect”. The photoluminescence lifetimes of Tb³⁺ ions in SS sensitized nanoparticles were found to be longer than those in un-sensitized nanoparticles.

Key words: sensitization, energy transfer, nanoparticles, photoluminescence properties

Suwen LI, Xuewei ZHANG, Yi JIANG, Jinying YUE, Cong GUAN. Sensitized Luminescence of Terbium(Ⅲ) in BaF₂∶Tb³⁺Nanoparticles by Salicylate[J]. Chinese Journal of Applied Chemistry, 2018, 35(7): 812-817.

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Sensitized Luminescence of Terbium(Ⅲ) in BaF₂∶Tb³⁺Nanoparticles by Salicylate

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