Electrodeposited Zn-Ni-P-La Alloys Coating for Electrolytic Copper Foil

doi:10.11944/j.issn.1000-0518.2015.04.140266

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (4): 458-463.DOI: 10.11944/j.issn.1000-0518.2015.04.140266

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Electrodeposited Zn-Ni-P-La Alloys Coating for Electrolytic Copper Foil

TAN Yuhui^a, WANG Yan^a, ZHANG Meng^a, GAO Jixing^a, XU Qing^a, TANG Yunzhi^{a, *}, YANG Shaoping^{b, *}

^aSchool of Materials and Chemical Engineering,Jiangxi University of Science and Technology,Ganzhou,Jiangxi 341000,China
^bSchool of Mechanical & Material Engineering,Wuzhou University,Wuzhou,Guangxi 543002,China

Received:2014-07-28 Published:2015-04-10 Online:2015-04-10
Contact: Corresponding author:TANG Yunzhi, professor; Tel:0797-8312204; E-mail:tyxcn@163.com; Research interests:metal surface treatment
About author:Co-corresponding author:YANG Shaoping, associate professor; Tel:0797-8312204; E-mail:ysp1120@163.com; Research interests:electrochemistry
Supported by:
Supported by National Natural Science Foundation of China(No.21261009, No.2461010, No.21471070), Support Program of Jiangxi Provincial Science and Technology Department(No.20133BBE50020), Program of Jiangxi Provincial Education Department(No.GJJ13434)

Abstract

Abstract:

In order to alleviate the situation of the country's reliance on importing high-performance copper foil, the experiment was carried out by introducing metalloid (P) and rare earth(La) in the Zn-Ni alloy coating to obtain high corrosion resistance for the copper foil. The quality of the copper foil coating was characterized by the X-ray photoelectron spectrscopy (XPS), powder X-ray diffraction (XRD) and scanning electron microscope (SEM). Zn-Ni-P-La amorphous alloy coating with well-distributed and dense crystallization was achieved by optimizing the experimental process parameters. The unpassivated copper foil can keep color for one hour in a 180 degree oven and exhibits good antioxidation and anticorrosion abilities. It indicates that a proper amount of P and La in the coating plays an important role in improving the quality of the copper foil coating, which has a good industrial application prospect.

Key words: electrolytic copper foil, alloy electrodeposition, rare earth additive, amorphous

CLC Number:

O614.1

TAN Yuhuia, WANG Yana, ZHANG Menga, GAO Jixinga, XU Qinga, TANG Yunzhia, , YANG Shaopingb, . Electrodeposited Zn-Ni-P-La Alloys Coating for Electrolytic Copper Foil[J]. Chinese Journal of Applied Chemistry, 2015, 32(4): 458-463.

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Electrodeposited Zn-Ni-P-La Alloys Coating for Electrolytic Copper Foil

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