Inhibition Behavior of 1-Phenylaminomethylbenzimidazole for Mild Steel in Hydrochloric Acid

doi:10.11944/j.issn.1000-0518.2015.04.140292

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (4): 464-471.DOI: 10.11944/j.issn.1000-0518.2015.04.140292

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Inhibition Behavior of 1-Phenylaminomethylbenzimidazole for Mild Steel in Hydrochloric Acid

SU Tiejun^{a, *}, LI Kehua^b, LUO Yunbai^c

^aCollege of Technology and Engineering
^bCollege of Chemistry and Environmental engineering, Yangtze University,Jingzhou,Hubei 434020,China
^cCollege of Chemistry and Molecular Sciences,Wuhan University,Wuhan 430072,China

Received:2014-08-25 Published:2015-04-10 Online:2015-04-10
Contact: Corresponding author:SU Tiejun, lecturer; Tel:0716-8067596; E-mail:sutj@qq.com; Research interests:oilfield chemistry and protection of metal corrosion
Supported by:
Supported by Yangtze University College of Technology and Engineering Innovation Foundation(13J0603)

Abstract

Abstract:

The inhibition effect and adsorption behavior of 1-phenylaminomethylbenzimidazole (PAB) for N80 steel in HCl solution were investigated by mass-loss test, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The inhibition efficiency increased with higher concentration of PAB and decreased with elevated temperature. Polarization curve reveals that PAB is a mix-type inhibitor. The adsorption between PAB and N80 steel surface is a spontaneous, exothermic and entropy increasing process fitting Langmuir isotherm. The relationship between the molecular structure of PAB and the inhibition efficiency was investigated using quantum chemical calculations.

Key words: corrosion inhibitor, mass loss, potentiodynamic polarization, impedance, quantum chemistry calculation

CLC Number:

O646
TG174.4

SU Tiejuna, , LI Kehuab, LUO Yunbaic. Inhibition Behavior of 1-Phenylaminomethylbenzimidazole for Mild Steel in Hydrochloric Acid[J]. Chinese Journal of Applied Chemistry, 2015, 32(4): 464-471.

References

[1] ZHAO Fulin. Oilfield Chemistry[M]. Dongying:Press of University of Petroleum,2000:177-178(in Chinese). 赵福麟. 油田化学[M]. 东营:石油大学出版社,2000:177-178.
[2] Abdallah M. Ethoxylated Fatty Alcohols as Corrosion Inhibitors for Dissolution of Zinc in Hydrochloric Acid[J]. Corros Sci ,2003,45:2705-2710.
[3] LI Kehua,WU Lanlan. Synthesis of XJ Mannich Base Inhibitor and Research of N80 Steel Corrosion Performance[J]. Oilfield Chem ,2013,30(3):434-437(in Chinese). 李克华,吴兰兰. 曼尼希碱缓蚀剂XJ合成及其对N80钢的缓蚀性能[J]. 油田化学, 2013,30(3):434-437.
[4] Ishtiaque Ahamad,Rajendra Prasad,Quraishi M A. Adsorption and Inhibitive Properties of Some New Mannich Bases of Isatin Derivatives on Corrosion of Mild Steel in Acidic Media[J]. Corros Sci ,2010,52:1472-1478.
[5] LI Jielan,LIANG Chenghao,HUANG Naibao, et al . Progress on Research of Benzimidazole Derivative as Corrosion Inhibitor[J]. Corros Sci Prot Tech ,2011,23(2):191-195(in Chinese). 李杰兰,梁成浩,黄乃宝,等. 苯并咪唑衍生物缓蚀剂研究进展[J]. 腐蚀科学与防护技术,2011,23(2):191-195.
[6] Popova A,Sokolova E,Raicheva S. AC and DC Study of the Temperature Effect on Mild Steel Corrosion in Acid media in the Presence of Benzimidazole Derivatives[J]. Corros Sci ,2003,45:33-58.
[7] HU Songqing,Hu Jianchun,YU Jinhua, et al . Studies on Corrosion Inhibition of Benzimidazole and Its Derivatives[J]. J Chinese Soc Corros Prot ,2010,30(5)354-357(in Chinese). 胡松青,胡建春,郁金华,等. 苯并咪唑及其衍生物定量构效关系研究[J]. 中国腐蚀与防护学报,2010,30(5):354-357.
[8] Wang X,Yang H,Wang F. An Investigation of Benzimidazole Derivative as Corrosion Inhibitor for Mild Steel in Different Concentration HCl Solutions[J]. Corros Sci ,2011,53:113-118.
[9] XU Xiujuan,CHEN Guangxu. Exchange Reaction between Acetophenone and Benzimidazole N -Mannich Base[J]. Acta Chim Sin ,1982,40(4):362-364(in Chinese). 徐秀娟,陈光旭. 苯并咪唑- N -Mannich碱与苯乙酮的交换反应[J]. 化学学报,1982,40(4):362-364.
[10] XIAO Jun,WU Yongren. The Preparation of N-Mannich Bases and Its Exchange Reaction with Arylketones[J]. J Beijing Nor Univ ,1996,32(3):367-370(in Chinese). 肖军,吴永仁. N -Mannich碱的制备及其与芳香酮的交换反应[J]. 北京师范大学学报,1996,32(3):367-370.
[11] CAO Chu'nan. Principles of Electrochemistry of Corrsion[M]. Beijin:Chemical Industry Press,2004:201-203(in Chinese). 曹楚南. 腐蚀电化学原理[M ]. 北京:化学工业出版社,2004:201-203.
[12] BEI Fengli,CHEN Haiqun,YANG Xujie, et al . Synthesis,Crystal Structure and Quantum Chemical Calculation of Benzimidazole Derivatives[J]. Chinese J Org Chem ,2004,24(3):300-305(in Chinese). 卑凤利,陈海群,杨绪杰,等. 苯并咪唑衍生物的合成-晶体结构及量子化学计算[J]. 有机化学,2004,24(3):300-305.
[13] WU Yinshun,ZHENG Jiashen. Electrochemical Protection and Application Technology of Corrosion Inhibitor[M]. Beijin:Chemical Industry Press,2006:496-497(in Chinese). 吴荫顺,郑家燊. 电化学保护和缓蚀剂应用技术[M]. 北京:化学工业出版社,2006:496-497.
[14] Zhang F,Tang Y M,Cao Z Y. Performance and Theoretical Study on Corrosion Inhibition of 2-(4-Pyridyl)-benzimidazole for Mild Steel in Hydrochloric Acid[J]. Corros Sci ,2012,61:1-9.
[15] CAO Chu'nan,ZHANG Jianqing. An Introduction to Electrochemical Impedance Spectroscopy[M]. Beijin:Science Press,2002:80-83(in Chinese). 曹楚南,张鉴清. 电化学阻抗谱导论[M]. 北京:科学出版社,2002:80-83.
[16] Wang X,Yang H,Wang F. An Investigation of Benzimidazole Derivative as Corrosion Inhibitor for Mild Steel in 1M HCl Solution[J]. Corros Sci ,2009,51(5):1836-1843.
[17] CAO Chu'nan. Principles of Electrochemistry of Corrsion[M]. Beijin:Chemical Industry Press,2004:211-214(in Chinese). 曹楚南. 腐蚀电化学原理[M ]. 北京:化学工业出版社,2004:211-214.
[18] HU Ying. Physical Chemistry[M]. Biejin:High Education Press,2007:51- 85(in Chinese). 胡英. 物理化学[ M]. 北京:高等教育出版社,2007:51- 85.
[19] Tang L,Mu G N,Liu G H, et al . The Effect of Neutral Red on the Corrosion Inhibition of Cold Rolled Steel in 1.0M Hydrochloric Acid[J]. Corros Sci ,2003,45:2251-2262.
[20] Ruth F V Villamil,Paola Corio,Silma M L Agostinho, et al . Effect of Sodium Dodecylsulfate on Copper Corrosion in Sulfuric Acid Media in the Absence and Presence of Benzotriazole[J] . J Electroanal Chem ,1999,472(2):112-119.
[21] Amar H,Benzakour J,Derja A. Piperidin-1-yl-phosphonic Acid and (4-Phosphono-piperazin-1-yl) Phosphonic Acid:A New Class of Iron Corrosion Inhibitors in Sodium Chloride 3% Media[J]. Appl Surf Sci ,2006,252(18):6162-6172.
[22] ZHANG Jun,ZHAO Weimin,GUO Wenyue, et al . Theoretical Evaluation of Corrosion Inhibition Performance of Benzimidazole Corrosion Inhibitios[J]. Acta Phys-Chim Sin ,2008,24(7):1239-1244(in Chinese). 张军,赵卫民,郭文跃,等. 苯并咪唑类缓蚀剂缓蚀性能的理论评价[J]. 物理化学学报,2008,24(7):1239-1244.

Inhibition Behavior of 1-Phenylaminomethylbenzimidazole for Mild Steel in Hydrochloric Acid

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