A New Approach for Prepareation of deuteroporphyrin and Its Metallo-Complexes

doi:10.3724/SP.J.1095.2011.00715

Chinese Journal of Applied Chemistry ›› 2011, Vol. 28 ›› Issue (11): 1263-1268.DOI: 10.3724/SP.J.1095.2011.00715

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A New Approach for Prepareation of deuteroporphyrin and Its Metallo-Complexes

DENG Quanzhi, HU Bingcheng^*, SUN Chengguo, XU Shichao, LIU Zuliang

(College of Chemical Engineering,Nanjing University of Science and Technology,Nanjing 210094)

Received:2010-12-01 Revised:2011-03-11 Published:2011-11-10 Online:2011-11-10

Abstract

Abstract:

A facile demetalation of deuterohemin(DP) has been developed in a mixed solvent of acetic anhydride and hydrobromic acid. The influences of reaction time, bath temperature and the molar ratio on the yields were also investigated. Under the optimal reaction conditions for the demetalation of DP, the yield of 96.3% is obtained at the temperature of 100 ℃ for 2 h with the molar ratio of DP, hydrobromic acid and acetic anhydride about 1∶6.3∶61.2. A series of metallodeuteroporphyrins was prepared and characterized by electrospray ionization tandem mass spectrometry(ESI-MS-MS), UV-Vis and IR. In addition, we also studied the effects of different solvents on the synthesis of metalloporphyrins, and the properties of metal cations on the shift of S and Q bands of porphyrin.

Key words: Deuteroporphyrin, Deuterohemin, Synthesis, Metallo-Deuteroporphyrin

CLC Number:

O621

DENG Quanzhi, HU Bingcheng*, SUN Chengguo, XU Shichao, LIU Zuliang. A New Approach for Prepareation of deuteroporphyrin and Its Metallo-Complexes[J]. Chinese Journal of Applied Chemistry, 2011, 28(11): 1263-1268.

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A New Approach for Prepareation of deuteroporphyrin and Its Metallo-Complexes

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