Oxydation of Benzyl Alcohol Catalyzed by Chloridizing Metallic Porphyrin Immobilized in Ionic Liquid

doi:10.3724/SP.J.1095.2010.90396

Chinese Journal of Applied Chemistry ›› 2010, Vol. 27 ›› Issue (10): 1124-1128.DOI: 10.3724/SP.J.1095.2010.90396

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Oxydation of Benzyl Alcohol Catalyzed by Chloridizing Metallic Porphyrin Immobilized in Ionic Liquid

RONG Li-Xia1, HE Kai2, FANG Yan-Xiong1*, JI Hong-Bing3, ZHANG Kun1

(1.Faculty of Chemical Engineering and Light Industry,Guangdong
University of Technology,Guangzhou 510006;
2.Guangdong Maoming Huayue Group Co.,Ltd,Maoming;
3.College of Chemistry and Chemical Engineering,Sun Yat-sen University,Guangzhou)

Received:2009-06-11 Revised:2010-05-18 Published:2010-10-10 Online:2010-10-10

Abstract

Abstract:

The direct oxidation of benzyl alcohol to phenyl aldehyde was studied with chloridized metallic porphyrin(MnTPPCl)/ionic liquid(ILs)/oxidant catalysts. The effects of temperature, MnTPPCl, various oxidation agents and the role of axial ligands on the yield were examined. The results showed that the yield and the selectivity of phenyl aldehyde can be both more than 99% in half an hour under the novel catalytic system MnTPPCl/[Bmim]HSO4/K2S2O8. The catalytic system without any organic solvents can be reused for many times and get a good performance.

Key words: metallic porphyrin, ionic liquids, benzyl alcohol, catalytic oxidation

CLC Number:

O625

RONG Li-Xia1, HE Kai2, FANG Yan-Xiong1*, JI Hong-Bing3, ZHANG Kun1. Oxydation of Benzyl Alcohol Catalyzed by Chloridizing Metallic Porphyrin Immobilized in Ionic Liquid[J]. Chinese Journal of Applied Chemistry, 2010, 27(10): 1124-1128.

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Oxydation of Benzyl Alcohol Catalyzed by Chloridizing Metallic Porphyrin Immobilized in Ionic Liquid

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