Synthesis and Application of Chiral 2-(2-Pyridyl)4-carbomethoxy-1,3-thiazolidine

Chinese Journal of Applied Chemistry ›› 1998, Vol. 0 ›› Issue (4): 89-91.

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Synthesis and Application of Chiral 2-(2-Pyridyl)4-carbomethoxy-1,3-thiazolidine

Yao Jinshui¹, Wu Yumin¹, Li Hong², He Binglin²

1. Department of Chemical Engineering, Shandong Institute of Light Industry, Ji'nan 250100;
2. The State Key Laboratory of Functirnial Polymeric Materials for Adsorption and Separation, lnstitute of Polymer Chemistry, Nankai University, Tianjin

Received:1997-10-27 Revised:1998-04-15 Published:1998-08-10 Online:1998-08-10

Abstract

Abstract: The title ligand(A) was synthesized through condensation of 2-pyridine aldehydeand L-methyl cysteine hydrochloride.The isomers of (A) were separated by column chromatography.The in-situ prepared catalyst from (A) with [Rh(COD)CI]₂(COD:cyclooctadiene) has been used to catalyze the asymmetric hydrosilylation of acetophenone.The resultsshowed that only the configuration of C₄, but not that of C₂ affected the optical yield andconfiguration of the products.

Key words: pyridyl-carbomethoxy-thiazolidine, ligand, asymmetric hydrosilylation

Yao Jinshui, Wu Yumin, Li Hong,He Binglin. Synthesis and Application of Chiral 2-(2-Pyridyl)4-carbomethoxy-1,3-thiazolidine[J]. Chinese Journal of Applied Chemistry, 1998, 0(4): 89-91.

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Synthesis and Application of Chiral 2-(2-Pyridyl)4-carbomethoxy-1,3-thiazolidine

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