Synthesis of Sodium Tetracarbonylcobaltate Using Urushibara-Co/CH3OH/CoCl2/CO and Its Application in Carbonylation

Chinese Journal of Applied Chemistry ›› 1998, Vol. 0 ›› Issue (1): 116-118.

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Synthesis of Sodium Tetracarbonylcobaltate Using Urushibara-Co/CH₃OH/CoCl₂/CO and Its Application in Carbonylation

Li Guangxing, Liu Yong

Department of Chemistry, Huazhong University of Science and Technology, Wuhan 430074

Received:1997-07-10 Revised:1997-10-06 Published:1998-02-10 Online:1998-02-10

Abstract

Abstract: Sodium tetracarbonyl cobaltate was prepared by reaction of CO with CoCl₂ inCH₃OH, using Urushibara-Cobalt (U-Co) as activator and characterized by IR spectrometry-The optimum conditions were: Co(from U-Co)/CoCl₂=0.6; 30 ℃; 0.1 MPa of CO.Theconvertion of CoCl₂ in 3h of reaction was 96%.The convertion of benzyl chloride to pheny-lacetic acid using the Na[Co(CO)₄] as catalyst was about 90% at 50℃ and 0.1 MPa of CO.

Key words: sodium tetracarbonyl cobaltate, urushibara-cobalt, phenylacetic acid, synthesis

Li Guangxing, Liu Yong. Synthesis of Sodium Tetracarbonylcobaltate Using Urushibara-Co/CH₃OH/CoCl₂/CO and Its Application in Carbonylation[J]. Chinese Journal of Applied Chemistry, 1998, 0(1): 116-118.

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Synthesis of Sodium Tetracarbonylcobaltate Using Urushibara-Co/CH₃OH/CoCl₂/CO and Its Application in Carbonylation

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