Synthesis, Characterization and Bioactivity of Bis-Schiff Base Complexes of Furoylpyrazolone

Chinese Journal of Applied Chemistry ›› 1997, Vol. 0 ›› Issue (6): 98-100.

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Synthesis, Characterization and Bioactivity of Bis-Schiff Base Complexes of Furoylpyrazolone

Li Jinzhou¹, Yu Wenjin¹, Du Xiaoyan²

1. Department of Chemistry, Harbin Normal University, Harbin 150080;
2. Institute of Public Health, Harbin Medical University, Harbin

Received:1997-06-16 Revised:1997-09-09 Published:1997-12-10 Online:1997-12-10

Abstract

Abstract: Five novel bis schiff base complexes M(PMαFP)₂en have been synthesized, where(HPMαFP)₂en=N,N-bis[(1-phenyl-3-methyl-5-oxo-4 pyrazolinyl)α-furylmethylidyne]ethylenediimine, M=Cu(Ⅱ), Ni(Ⅱ), Co(Ⅱ), Pd(Ⅱ), Pt(Ⅱ). They were characterized by elemental analysis, IR, UV-vis, ¹H NMR, ¹³C NMR, magnetic moment and molar conductance measurements. The results showed that the complexes are all of quadricoordinate square-planar geometry. The antibacterial experiment indicated that they have high antibacterial activities against S. aureus, B. subtillis, E. coli, E. carotovora and C. flaccumfaciens.

Key words: acylpyrazolone, bis-schiff base, complex, synthesis, bioactivity

Li Jinzhou, Yu Wenjin, Du Xiaoyan. Synthesis, Characterization and Bioactivity of Bis-Schiff Base Complexes of Furoylpyrazolone[J]. Chinese Journal of Applied Chemistry, 1997, 0(6): 98-100.

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Synthesis, Characterization and Bioactivity of Bis-Schiff Base Complexes of Furoylpyrazolone

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