Synthesis and Hydrogenation Activity of Diiminodiphosphine Ruthenium Complex RuCl2P2N2

Chinese Journal of Applied Chemistry ›› 1997, Vol. 0 ›› Issue (3): 58-61.

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Synthesis and Hydrogenation Activity of Diiminodiphosphine Ruthenium Complex RuCl₂P₂N₂

Xu Pianpian¹, Gao Jingxing¹, Huang Peiqiang¹, Wang Huilin¹, Wang Wenguo², Cheng Shouzheng²

1. Department of Chemistry, State Key Laboratory of Physical Chemistry of Solid Surface, Institute of Physical Chemistry, Xiamen University, Xiamen 361005;
2. Department of Chemistry, Fujian Normal University, Fuzhou

Received:1996-11-06 Revised:1997-03-05 Published:1997-06-10 Online:1997-06-10

Abstract

Abstract: The trans form of the title complex was synthesized in high yield by interaction of equimole RuCl₂(Ph₃P)₄ or RuCl₂(DMSO)₄(DMSO=dimethylsulfoxide)with P₂N₂(i.e.= N,N'-bis[o-(diphenylphosphine benzylidene)]ethylene diamine)in refluxing toluene. The complex has been investigated as catalyst for selective hydrogenation of α,β-unsaturated acids and some functionalized olefins. The hydrogenation catalytic activity was observed as follows: styrene>acrylic acid>benzaldehyde>salicyl aldehyde>cyclohexanone>furfural>methylacrylic acidacetophenone. The effect of addition of NH₄PF₆ or AgNO₃ as promotor has also been studied.

Key words: diiminodiphosphine ligand, ruthenium complex, synthesis, hydrogenation, catalytic activity

Xu Pianpian, Gao Jingxing, Huang Peiqiang, Wang Huilin, Wang Wenguo, Cheng Shouzheng. Synthesis and Hydrogenation Activity of Diiminodiphosphine Ruthenium Complex RuCl₂P₂N₂[J]. Chinese Journal of Applied Chemistry, 1997, 0(3): 58-61.

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Synthesis and Hydrogenation Activity of Diiminodiphosphine Ruthenium Complex RuCl₂P₂N₂

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