Synthesis of 1-Cyano 2,3,5-tri-O-benzoyl-β-D-ribofuranose

Chinese Journal of Applied Chemistry ›› 1997, Vol. 0 ›› Issue (3): 115-116.

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Synthesis of 1-Cyano 2,3,5-tri-O-benzoyl-β-D-ribofuranose

Zhang Wanxuan, Lei Cenan, Huang Jinxia, Chen Jiawei

Department of Chemistry, Hubei University, Wuhan 430062

Received:1996-08-12 Revised:1997-03-05 Published:1997-06-10 Online:1997-06-10

Abstract

Abstract: Reacting guanosine with benzoyl chloride gave a mixture containing 2',3',5'-tribenzoyl guanosine. After distillation in vacuum the residual solid was acetylated directly and 1-O-acetyl-2,3,5-tri-O-benzoyl-β-D-ribofuranose(2)was obtained. Being reacted with Me 3SiCN,(2)led to the title compound(1). The method reported here is more convenient and cheaper with a considerably higher yield.

Key words: guanosine, cyano-tri-O-benzoyl-β-D-ribofuranose, synthesis, chloro trimethylsilane

Zhang Wanxuan, Lei Cenan, Huang Jinxia, Chen Jiawei. Synthesis of 1-Cyano 2,3,5-tri-O-benzoyl-β-D-ribofuranose[J]. Chinese Journal of Applied Chemistry, 1997, 0(3): 115-116.

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Synthesis of 1-Cyano 2,3,5-tri-O-benzoyl-β-D-ribofuranose

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