Chinese Journal of Applied Chemistry ›› 1997, Vol. 0 ›› Issue (2): 50-52.

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Syntheses and Spectra of Bulkier Substituted Titanocene Zirconocene Dichlorides

Cheng Lin1, Jian Xigao1, Chen Shoushan2, Qian Yanlong3   

  1. 1. Department of Polymer Science and Materials, College of Chemical Engieering, Dalian University of Science and Technology, Dalian 116012;
    2. Elemento Organic Chemistry Institute, Nankai University, Tianjin;
    3. Department of Chemistry, East China University of Science and Technology, Shanghai
  • Received:1996-06-26 Revised:1996-10-22 Published:1997-04-10 Online:1997-04-10

Abstract: Seven bulkier substitute titanocene and zirconocene dichlorides have been synthesized by addition reaction of 6,6-dialkylfulvenes with 1-lithiocyclohexene followed by treatment of the obtained bulkier substituted metallocene with MCl4(M=Ti, Zr). Their 1H NMR, EIMS and IR spectra have been discussed.

Key words: addition reaction, substituted cyclopentadienyl metal compound, spectra