Catalytic Hydrogenation Activity of Zirconium Glycine-N,N-Dimethylphosphonate Palladium

Chinese Journal of Applied Chemistry ›› 1997, Vol. 0 ›› Issue (1): 74-76.

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Catalytic Hydrogenation Activity of Zirconium Glycine-N,N-Dimethylphosphonate Palladium

Fu Xiangkai, Ma Xuebing, Liu Changhua, He Youqiu

College of Chemistry and Chemical Engineering, Southwest China Normal University, Chongqing 630715

Received:1996-03-25 Revised:1996-06-19 Published:1997-02-10 Online:1997-02-10

Abstract

Abstract: A new type of supported complex catalysts, zirconium glycine-N,N-dimethylph osphonate palladium was prepared for the first time. The catalytic activity of title catalysts for hydrogenation of several substrates under atmospheric pressure was studied. The catalytic activity is greatly affected by the NCH₂CO₂H/Pd ratio, catalyst amount, reaction temperature, substrates and solvents. At 40℃ and under atmospheric pressure, the hydrogenation activity of the catalysts for various substituted olefins and nitrobenzene is very high and with high selectivity. The catalyst can be reused.

Key words: zirconium glycine-N, N-dimethylphosphonate, palladium catalyst, catalytic hydrogenation, catalytic activity

Fu Xiangkai, Ma Xuebing, Liu Changhua, He Youqiu. Catalytic Hydrogenation Activity of Zirconium Glycine-N,N-Dimethylphosphonate Palladium[J]. Chinese Journal of Applied Chemistry, 1997, 0(1): 74-76.

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Catalytic Hydrogenation Activity of Zirconium Glycine-N,N-Dimethylphosphonate Palladium

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