Catalytic Performance of Ce(Ⅲ)-barbitone Complex for Bis(p-nitrophenyl) Phosphate Hydrolysis

doi:10.11944/j.issn.1000-0518.2015.12.150250

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (12): 1410-1415.DOI: 10.11944/j.issn.1000-0518.2015.12.150250

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Catalytic Performance of Ce(Ⅲ)-barbitone Complex for Bis(p-nitrophenyl) Phosphate Hydrolysis

LIU Hongjun,ZHOU Tong,SHEN Yuhua,XIE Anjian()

School of Chemistry and Chemical Engineering,Anhui University,Hefei 230601,China

Received:2015-07-17 Accepted:2015-09-25 Published:2015-12-01 Online:2015-12-01
Contact: XIE Anjian
Supported by:
Supported by the National Natural Science Foundation of China(NSFC)(No.21171001, No.51372004)

Abstract

Abstract:

Hydrolysis of bis(p-nitrophenyl) phosphate(BNPP) catalyzed by Ce(Ⅲ)-barbitone complex was explored. The results indicate that the Ce(Ⅲ)-barbitone complex exhibits excellent catalytic activity for BNPP hydrolysis. The complex can increase the rate of the BNPP hydrolysis by a factor of 1.52×10⁸ times compared to that of the spontaneous hydrolysis. The effect of temperature and pH on the catalytic activity of Ce(Ⅲ)-barbitone complex for BNPP hydrolysis was also investigated. It is found that the optimal catalytic condition is at 25 ℃ and pH 8.50.

Key words: Ce(Ⅲ), barbitone sodium, Ce(Ⅲ)-barbitone complex, bis(p-nitrophenyl) phosphate hydrolysis, catalytic activity

LIU Hongjun, ZHOU Tong, SHEN Yuhua, XIE Anjian. Catalytic Performance of Ce(Ⅲ)-barbitone Complex for Bis(p-nitrophenyl) Phosphate Hydrolysis[J]. Chinese Journal of Applied Chemistry, 2015, 32(12): 1410-1415.

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Catalytic Performance of Ce(Ⅲ)-barbitone Complex for Bis(p-nitrophenyl) Phosphate Hydrolysis

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